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公开(公告)号：US20080319147A1
公开(公告)日：2008-12-25
申请号：US12099940
申请日：2008-04-09
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或 两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。
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Patent Agency Ranking
公开(公告)号：US07217675B2
公开(公告)日：2007-05-15
申请号：US10802514
申请日：2004-03-17
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: B01J31/143 , B01J31/1616 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07F1/005 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/02 , C08F4/7042 , C08F4/7081
Abstract: This invention relates to transition metal catalyst compounds represented by the formula: LMX2 wherein M is a Group 7 to 11 metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by least three or four nitrogen atoms, and at least one terminal nitrogen atom is part of a pyridinyl ring, a different terminal nitrogen atom is substituted with one C3–C50 hydrocarbyl, and one hydrogen atom or two hydrocarbyls; wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to at least three different carbon atoms or two different carbon atoms, and one hydrogen atom; X is independently a monoanionic ligand or both X are joined together to form a bidentate dianionic ligand.
Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：其中M是7-11族金属; L是三齿或四齿中性带电的配体，其通过至少三个或四个氮原子与M键合，并且至少一个末端氮原子是吡啶基环的一部分，不同的末端氮原子被一个C 3 一个或多个烃基，一个氢原子或两个烃基; 其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合至至少三个不同的碳原子或两个不同的碳原子，一个 氢原子; X独立地是单阴离子配体，或者两者X连接在一起以形成二齿二离子配体。
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公开(公告)号：US08058372B2
公开(公告)日：2011-11-15
申请号：US12099940
申请日：2008-04-09
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX2或（LMX2）2，其中每个M独立地是7-11族金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C 3 -C 50烃基，并且中心氮原子键合到三个不同的碳原子或 两个不同的碳原子和一个氢原子; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。
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公开(公告)号：US07820582B2
公开(公告)日：2010-10-26
申请号：US11712881
申请日：2007-03-01
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: B01J31/143 , B01J31/1616 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2531/14 , C07C2531/22 , C07F1/005 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/02 , C08F4/7042 , C08F4/7081
Abstract: This invention relates to catalyst compounds, catalysts systems and methods to oligomerize or polymerize monomers where the catalyst compound and the catalyst system comprise compounds of formula: LMX2 or (LMX2)2 wherein: M is a Group 7, 8, 9, 10 or 11 transition metal; L is a tridentate or tetradentate neutrally charged ligand that is bonded to M by at least three nitrogen atoms; at least one of the nitrogen atoms is a central non-pyridinal nitrogen atom and is not bonded to its adjacent atoms by a multibond; at least two of the nitrogen atoms are terminal nitrogen atoms; at least one terminal nitrogen atom is part of a pyridinyl ring; at least one other terminal nitrogen atom is substituted with at least one C3-C50 hydrocarbyl or halobydrocarbyl; the central nitrogen atom is bonded to at least two different carbon atoms; and each X is an anionic monodentate ligand.
Abstract translation: 本发明涉及催化剂化合物，催化剂体系和使单体低聚或聚合的方法，其中催化剂化合物和催化剂体系包含式：LMX2或（LMX2）2的化合物，其中：M为第7,8,9,10或11族 过渡金属; L是三齿或四齿中性带电的配体，其通过至少三个氮原子与M键合; 氮原子中的至少一个是中心非吡啶基氮原子，并且不通过多键与其相邻原子键合; 至少两个氮原子是末端氮原子; 至少一个末端氮原子是吡啶环的一部分; 至少一个其它末端氮原子被至少一个C 3 -C 50烃基或卤代烃基取代; 中心氮原子与至少两个不同的碳原子键合; 并且每个X是阴离子单齿配体。
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公开(公告)号：US07371803B2
公开(公告)日：2008-05-13
申请号：US11602897
申请日：2006-11-21
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3-C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3-C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）键合到M上 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。
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公开(公告)号：US07189791B2
公开(公告)日：2007-03-13
申请号：US10855585
申请日：2004-05-27
Applicant: Gregory Adam Solan , Christopher James Davies
Inventor： Gregory Adam Solan , Christopher James Davies
CPC classification number: C07C2/32 , B01J31/143 , B01J31/146 , B01J31/1805 , B01J31/1815 , B01J2231/122 , B01J2231/20 , B01J2531/0258 , B01J2531/16 , B01J2531/72 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2531/26 , C07F13/005 , C07F15/025 , C07F15/045 , C07F15/065 , C08F10/00 , C08F110/02 , C07C11/02 , C08F2500/02 , C08F4/60089 , C08F4/7042 , C08F4/50 , C08F4/7081
Abstract: This invention relates to a transition metal catalyst compound represented by the formula: LMX2 or (LMX2)2 wherein each M is independently a Group 7 to 11 metal, preferably a Group 7, 8, 9, or 10 metal; each L is, independently, a tridentate or tetradentate neutrally charged ligand that is bonded to M by three or four nitrogen atoms, (where at least one of the nitrogen atoms is a central nitrogen atom and at least two of the nitrogen atoms are terminal nitrogen atoms), and at least two terminal nitrogen atoms are substituted with one C3–C50 hydrocarbyl and one hydrogen atom or two hydrocarbyls wherein at least one hydrocarbyl is a C3–C50 hydrocarbyl, and the central nitrogen atom is bonded to three different carbon atoms or two different carbon atoms and one hydrogen atom; X is independently a monoanionic ligand, or two X may join together to form a bidentate dianionic ligand.
Abstract translation: 本发明涉及由下式表示的过渡金属催化剂化合物：LMX 2或（LMX 2）2 N，其中每个M独立地为基团 7至11个金属，优选第7,8,9或10族金属; 每个L独立地是三齿或四齿中性带电的配体，其通过三个或四个氮原子（其中至少一个氮原子是中心氮原子，并且至少两个氮原子是末端氮）与M键合 原子），并且至少两个末端氮原子被一个C 3 -C 50烃基和一个氢原子或两个烃基取代，其中至少一个烃基是C < 并且中心氮原子键合到三个不同的碳原子或两个不同的碳原子和一个氢原子上; X独立地是单阴离子配体，或两个X可以连接在一起以形成二齿二离子配体。
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