摘要:
Byproducts of the oxidation of cycloalkanes, which react with primary and secondary amines, are condensed with polyvalent aliphatic amines. The condensation products are inexpensive and are suitable as epoxide resin hardners. The condensation products generally contain in chemically bound form about 50 percent or more of said byproducts. Resins hardened with the hardeners of the present invention surprisingly show increased impact strength.
摘要:
A continuous process for the purification of caprolactam characterized in that raw caprolactam is subjected to a solvent distillation followed by a distillation under reduced pressure in the presence of sodium hydroxide and then to a melt crystallization, in which: A. The residue from the alkaline distillation is taken up in water, the aqueous solution extracted with benzene or toluene and the lactam solution fed to the main product stream through the solvent distillation; B. The residue from the melt crystallization is extracted in the crystalline state with an aliphatic or cycloaliphatic hydrocarbon with 5-10 carbon atoms and the purified residue is fed back into the alkaline distillation of the main produce stream; and C. The aliphatic or cycloaliphatic hydrocarbon is regenerated and used again for the extraction of the residue from the meltcrystallization.
摘要:
A PHENOL WHICH IS UNSUBSTITUTED AT THE POSITION PARA TO THE HYDROXY GROUP OR UNSUBSTITUTED AT AT LEAST ONE OF THE POSITIONS ORTHO TO THE HYDROXY GROUP IS DISSOLVED IN A SOLVENT, IN THE ABSENCE OF HYDROGEN SULFIDE AND CATALYSTS, AND WHILE COOLING TO A TEMPERATURE BELOW 30* C. IS REACTED WITH DISULFUR DICHLORIDE. THE SOLVENT IS AN ACID AMIDE WHOSE NITROGEN ATOMS ARE COMPLETELY ALKYLATED. POLYTHIOBISPHENOLS ARE OBTAINED IN HIGH YIELD.
摘要:
POLYMERIC COMPOUNDS OF THE FORMULA -X1-AR1-(Y1-AR1)N1-X2-(AR2-Y2)N2-AR2WHEREIN X1 AND X2 ARE INDEPENDENTLY EITHER OXYGEN OR SULPHUR, AR1 AND AR2 ARE THE SAME OR DIFFERENT AROMATIC RADICALS,N1 AND N2 ARE INDEPENDENTLY OF ONE ANOTHER THE NUMBERS 0-2, AND Y1 AND Y2 ARE INDEPENDENTLY OF ONE ANOTHER A SIMPLE BOND OR A DIVALENT RADICALS, PARTICULARLY ONE OF THE SERIES -O-, -CONH-, -S-, -SO2-, -CO-, -CH2-, -C(CH3)2-, -N=N-, IN WHICH EACH AR IS ATTACHED TO ADJCENT RING MEMBER BY TWO CARBON ATOMS WHICH ARE NOT ADJACENT ONE ANOTHER, AND IS CHARACTERIZED IN THAT AT LEAST ONE COMPOUND OF THE FORMULA: H-X1-AR1-(Y1-AR1)N1-X2-H IS TREATED WITH AT LEAST ONE COMPOUND OF THE FORMULLA: HAL-(AR2-Y2)N2-AR2-HAL IN WHICH HAL REPRESENTS HALOGEN, PARTICULARLY CHLORINE OR BROMINE, AND X1, X2 AND AR1, AR2, N1, N2, Y1 AND Y2 HAVE THE SIGNIFICANCE STATED IN FORMULA I, IN THE PRESENCE OF THE QUANTITY NECESSARY FOR NEUTRALIZATION OF HYDROGEN-HALIDE IN PARTICULAR 1-20% BY WEIGHT EXCESS CALCULATED ON THE STARTING MATERIAL OF AN INORGANIC OR ORGANIC BASE AS ACID ACCEPTOR, IN A SOLVENT OF THE FORMULA: A-N
摘要:
A PROCESS CHARACTERIZED IN THAT RAW CAPROLACTAM IS SUBJECTED, IN EITHER SEQUENCE, TO A CRYSTAL EXTRACTION WITH AN ALIPHATIC OR CYCLOALIPHATIC HYDROCARBON HAVING 5-10 CARBON ATOMS AND TO DISTILLATION UNDER REDUCED PRESSURE.
摘要:
TRANSESTERIFICATION OF ALKYL ESTERS OF A DICARBOXYLIC ACID AND A DIOL AIDED BY A METAL SALT CATALYST WHEREIN THE REACTION MEDIUM IS PASSED THROUGH AN ELONGATED REACTION ZONE IN PLUG-LIKE FLOW (LITTLE BACK-MIXING OF THE REACTION MEDIUM), WHEREIN SOME OF THE TRANSESTERIFICATION PRODUCT IS MAINTAINED PRESENT AT THE INLET END OF THE REACTION ZONE. THEREBY INACTIVATION OF THE CATALYST IS PREVENTED.
摘要:
Method and apparatus for purifying organic substances which form crystals and melt without decomposition by use of centrifuge which includes heating of the discharge channels above the melting point of the substance to prevent crust formation.
摘要:
PROCESS FOR REMOVING METAL IMPURITITEDSUCH AS IRON FORM 55-85% BY WEIGHT SULPHURIC ACID. THE SULPHURIC ACID IS TREATED WITH A MOLAR EXCESS OF A HALIDE TO FORM A COMPLEX WITH THE IMPURITY. THE ACID IS THEN PASSED THROUGH AN ANION EXCHANGER TO PURIFY AND REMOVE THE IMPURITIES FROM THE ACID.