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公开(公告)号:US20180094097A1
公开(公告)日:2018-04-05
申请号:US15565952
申请日:2016-04-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Tao Gong
IPC: C08G59/22 , C08G59/32 , C08G75/04 , C08L81/02 , C08L81/04 , C08L63/00 , C08G59/40 , C08G59/56 , C08G59/66 , C08G59/68
CPC classification number: C08G59/4021 , C08G59/22 , C08G59/32 , C08G59/56 , C08G59/66 , C08G59/686 , C08G75/02 , C08G75/04 , C08L63/00 , C08L81/02 , C08L81/04
Abstract: A method of making a polymer network. The method includes providing a composition including a polythiol having more than one thiol group and a polyepoxide having more than one epoxide group, applying a solution including a photolatent base catalyst to a surface of the composition, and subsequently exposing the composition to light. Upon exposure to light, the photolatent base catalyst photochemically generates a first amine and at least partially cures at least the surface of the composition to form the polymer network.
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公开(公告)号:US10768528B2
公开(公告)日:2020-09-08
申请号:US15745737
申请日:2016-09-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Dennis E. Vogel , Ann R. Fornof , Andrew R. Davis , Babu N. Gaddam
IPC: G03F7/20 , C08J3/28 , C08F220/18 , C09J133/08 , C09J7/38 , C08F2/28 , C08F230/00 , C08J5/18 , C09J143/00
Abstract: A pattern article comprising a copolymer having polymerized units derived from a cleavable crosslinking monomer, to which a pattern is imparted by the release of incipient acid from a thermal acid generator or photoacid generator. The selective release of the acid provides a pattern of high crosslink density and low crosslink density as result of the incipient acid cleaving a portion of the crosslinks.
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公开(公告)号:US10526440B2
公开(公告)日:2020-01-07
申请号:US15565952
申请日:2016-04-29
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Tao Gong
IPC: C08G59/22 , C08G59/40 , C08G59/66 , C08G59/32 , C08G59/56 , C08G59/68 , C08G75/02 , C08G75/04 , C08L81/02 , C08L63/00 , C08L81/04
Abstract: A method of making a polymer network. The method includes providing a composition including a polythiol having more than one thiol group and a polyepoxide having more than one epoxide group, applying a solution including a photolatent base catalyst to a surface of the composition, and subsequently exposing the composition to light. Upon exposure to light, the photolatent base catalyst photochemically generates a first amine and at least partially cures at least the surface of the composition to form the polymer network.
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公开(公告)号:US11041049B2
公开(公告)日:2021-06-22
申请号:US16308697
申请日:2017-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Brian S. Lam , Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Michael D. Swan
IPC: C08G75/04 , C09J181/02 , C08G75/045 , C09K3/10 , C08G75/12 , C08L81/02 , C08G75/32 , C07D277/82 , B64C3/34 , B64C1/12 , B64C1/14
Abstract: A dual curable thiol-ene composition comprising a polythiol, an unsaturated compound, a photoinitiator, an organic hydroperoxide (thermal initiator) and optionally a nitrogen-containing base, such as e.g. an N-heterocyclic compound (together with the organic hydroperoxide a redox initiator system). A cross-linked polymer prepared therefrom. A method of making such a polymer. A cured sealant comprising such a polymer. The sealant is preferably for use in aerospace.
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公开(公告)号:US20190144610A1
公开(公告)日:2019-05-16
申请号:US16308697
申请日:2017-06-27
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: William H. Moser , Erik M. Townsend , Brian S. Lam , Jonathan D. Zook , Susan E. DeMoss , Sheng Ye , Andrew R. Davis , Michael D. Swan
IPC: C08G75/045 , C09K3/10 , C09J181/02
Abstract: A dual curable thiol-ene composition comprising a polythiol, an unsaturated compound, a photoinitiator, an organic hydroperoxide (thermal initiator) and optionally a nitrogen-containing base, such as e.g. an N-heterocyclic compound (together with the organic hydroperoxide a redox initiator system). A cross-linked polymer prepared therefrom. A method of making such a polymer. A cured sealant comprising such a polymer. The sealant is preferably for use in aerospace.
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公开(公告)号:US20180231891A1
公开(公告)日:2018-08-16
申请号:US15745737
申请日:2016-09-15
Applicant: 3M INNOVATIVE PROPERTIES COMPANY
Inventor: Jason D. Clapper , Dennis E. Vogel , Ann R. Fornof , Andrew R. Davis , Babu N. Gaddam
IPC: G03F7/20 , C09J133/08 , C08F220/18 , C08F230/00 , C09J143/00 , C08J5/18 , C08J3/28 , C09J7/38
Abstract: A pattern article comprising a copolymer having polymerized units derived from a cleavable crosslinking monomer, to which a pattern is imparted by the release of incipient acid from a thermal acid generator or photoacid generator. The selective release of the acid provides a pattern of high crosslink density and low crosslink density as result of the incipient acid cleaving a portion of the crosslinks.
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