FLUORINATED COPOLYMER HAVING SULFONYL PENDANT GROUPS AND METHOD OF MAKING AN IONOMER

    公开(公告)号:US20190027769A1

    公开(公告)日:2019-01-24

    申请号:US16082721

    申请日:2017-03-06

    Abstract: The copolymer includes divalent units represented by formula: (I), one or more independently selected fluorinated divalent units, and —SO2X end groups. In this formula, b is 2 to 8, c is 0 to 2, and e is 1 to 8. In each SO2X, X is independently F, —NZH, —NZSO2(CF2)1−6SO2X′, —NZ[SO2(CF2)aSO2NZ]1−10SO2X′, or —OZ, wherein Z is a hydrogen, an alkali-metal cation or a quaternary ammonium cation, X′ is independently —NZH or —OZ, and each a is independently 1 to 6. The copolymer has an —SO2X equivalent weight of up to 1000. The method includes copolymerizing components including fluorinated olefin and a compound represented by formula CF2═CF—CF2(O—CbF2b)c—O—(CeF2e)—SO2X′, wherein b, c, and e are as defined above. A method of making a membrane using the copolymer or ionomer is also provided. A polymer electrolyte membrane that includes the copolymer or the ionomer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.

    BRANCHED FLUOROTHERMOPLASTS AND METHOD OF MAKING THE SAME

    公开(公告)号:US20210189031A1

    公开(公告)日:2021-06-24

    申请号:US16756261

    申请日:2018-10-23

    Abstract: Described herein is a fluorothermoplast with long chain branching and a method of making such a polymer using a modifier of the formula: F2C═CF(CF2)a(O)RfH wherein a is 0 or 1 and Rf is a linear or branched fluorinated alkylene group comprising 1 to 5 carbon atoms and optionally comprising at least one ether linkage and optionally comprising 1 or 2 hydrogen atoms. This fluorothermoplast may be processed through polymer melt processes, such as blow molding, injection molding, film extrusion, and wire extrusion. Preferably, said polymer contains structural units derived from tetrafluoroethylene and a perfluorinated olefin or ether, and comprises chain branching.

    TETRAFLUOROETHYLENE POLYMER DISPERSIONS STABILIZED WITH ALIPHATIC NON-IONIC SURFACTANTS
    5.
    发明申请
    TETRAFLUOROETHYLENE POLYMER DISPERSIONS STABILIZED WITH ALIPHATIC NON-IONIC SURFACTANTS 审中-公开
    与非离子表面活性剂稳定的四氯氟乙烯聚合物分散体

    公开(公告)号:US20160347966A1

    公开(公告)日:2016-12-01

    申请号:US15115235

    申请日:2015-01-29

    Abstract: An aqueous dispersion comprising a tetrafluoroethylene core-shell polymer and at least one surfactant corresponding to the general formula R10-[CH2CH20]n[R20]m-R3 wherein R1 represents a linear or branched aliphatic hydrocarbon group having at least 8 carbon atoms, preferably 8 to 18 carbon atoms, R2 represents an alkylene having 3 carbon atoms, R3 represents hydrogen, a C1-C3 alkyl group, or a C1-C3 hydroxyalkyl group, n has a value of 0 to 40, m has a value of 0 to 40 and the sum of n+m is at least 2, wherein the dispersion is free of fluorinated emulsifiers or contains them in an amount of less than 50 ppm based on the weight of the dispersion and wherein the core-shell polymer contains an outer shell of tetrafluoroethylene homopolymer. Further provided are methods of making the dispersions, coating compositions comprising the dispersions and article coated by the coating composition.

    Abstract translation: 包含四氟乙烯核 - 壳聚合物和至少一种对应于通式R 10 - [CH 2 CH 2 O] n [R 20] m -R 3的表面活性剂的水分散体,其中R 1表示具有至少8个碳原子的直链或支链脂族烃基,优选 8至18个碳原子,R 2表示具有3个碳原子的亚烷基,R 3表示氢,C 1 -C 3烷基或C 1 -C 3羟烷基,n的值为0至40,m的值为0至 40,并且n + m的总和为至少2,其中所述分散体不含氟化乳化剂或基于分散体的重量以小于50ppm的量包含它们,并且其中所述核 - 壳聚合物包含外壳 的四氟乙烯均聚物。 还提供了制备分散体的方法,涂料组合物包含由涂料组合物涂覆的分散体和制品。

    PEROXIDE CURABLE FLUOROPOLYMERS OBTAINABLE BY POLYMERIZATION USING NON-FLUORINATED POLYHYDROXY EMULSIFIERS
    8.
    发明申请
    PEROXIDE CURABLE FLUOROPOLYMERS OBTAINABLE BY POLYMERIZATION USING NON-FLUORINATED POLYHYDROXY EMULSIFIERS 审中-公开
    过氧化物可固化的氟聚合物可通过使用非氟化聚羟基乳化剂聚合获得

    公开(公告)号:US20160272782A1

    公开(公告)日:2016-09-22

    申请号:US15033301

    申请日:2014-10-29

    Abstract: Described are methods of making a curable fluoropolymer having repeating units derived from vinylidenfluoride (VDF) and at least one perfluorinated monomer selected from hexafluoropropene (HFP), tetrafluoroethene (TFE), a perfluorovinyl ether (PAVE), a perfluoroallylether (PAAVE) or a combination thereof. The method includes polymerising the monomers in an aqueous medium in a radical reaction containing one or more reaction initiators, one or more chain transfer agent containing one or more halogens selected from iodine, bromine or a combination thereof and one or more non-fluorinated aliphatic polyhydroxy emulsifiers. The polymerization is carried out without adding a fluorinated emulsifier. Also provided are curable fluoropolymers obtainable by such methods and cured fluoropolymers obtainable by curing the curable fluoropolymers, and their applications.

    Abstract translation: 描述了制备具有衍生自偏氟乙烯(VDF)的重复单元和至少一种选自六氟丙烯(HFP),四氟乙烯(TFE),全氟乙烯基醚(PAVE),全氟烯烃(PAAVE)或组合物)的全氟化单体的可固化含氟聚合物的方法 其中。 该方法包括在包含一个或多个反应引发剂的自由基反应中在水性介质中聚合单体,一种或多种含有一种或多种选自碘,溴或其组合的卤素的链转移剂和一种或多种非氟化脂族多羟基 乳化剂。 在不加入氟化乳化剂的情况下进行聚合。 还提供了可通过这些方法获得的可固化含氟聚合物和通过固化可固化含氟聚合物获得的固化的氟聚合物及其应用。

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