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公开(公告)号：US20240002228A1
公开(公告)日：2024-01-04
申请号：US18254671
申请日：2021-12-14
发明人： Markus E. Hirschberg , Kalus Hintzer , Thomas W. Schoettle , Arne Thaler , Achim Schmidt-Rodenkirchen , Thorsten Gerdes , Konstantin Mierdel
IPC分类号： C01B7/19
摘要： Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.
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公开(公告)号：US20230056130A1
公开(公告)日：2023-02-23
申请号：US17782193
申请日：2020-12-18
发明人： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Klaus Hintzer , Matthew J. Lindell , Sean M. Smith , Arne Thaler , Michael A. Yandrasits
IPC分类号： H01M8/1039 , H01M8/1004 , H01M4/90 , H01M4/88
摘要： The copolymer includes divalent units represented by formula —[CF2—CF2]—, at least one divalent unit represented by formula (I): and at least one divalent unit independently represented by formula (II): A is —N(RFa)2 or a is non-aromatic, 5- to 8-membered, perfluorinated ring comprising one or two nitrogen atoms in the ring and optionally comprising at least one oxygen atom in the ring, each RFa is independently linear or branched perfluoroalkyl having 1 to 8 carbon atoms and optionally interrupted by at least one catenated O or N atom, each Y is independently —H or —F, with the proviso that one Y may be —CF3, h is 0, 1, or 2, each i is independently 2 to 8, and j is 0, 1, or 2. A catalyst ink and polymer electrolyte membrane including the copolymer are also provided.
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公开(公告)号：US20200303755A1
公开(公告)日：2020-09-24
申请号：US16646638
申请日：2018-09-14
发明人： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Steven J. Hamrock , Klaus Hintzer , Markus E. Hirschberg , Arne Thaler , Tilman C. Zipplies
IPC分类号： H01M8/1039 , C08F214/26 , H01M4/86 , H01M8/1004 , H01M8/1023
摘要： The copolymer includes divalent units represented by formula —[CF2-CF2]—, divalent units represented by formula: (I), and one or more divalent units independently represented by formula: (II) When Z is hydrogen, the copolymer has an alpha transition temperature of up to 100 ?C. The copolymer has an —SO3Z equivalent weight in a range from 300 to 1400, and a variation of the copolymer in which —SO3Z is replaced with —SO2F has a melt flow index of up to 80 grams per ten minutes measured at a temperature of 265° C. and at a support weight of 5 kg. A catalyst ink or polymer electrolyte membrane including the copolymer are also provided.
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公开(公告)号：US11492431B2
公开(公告)日：2022-11-08
申请号：US16645882
申请日：2018-09-14
发明人： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Steven J. Hamrock , Klaus Hintzer , Markus E. Hirschberg , Arne Thaler , Tilman C. Zipplies
IPC分类号： C08F214/26 , C08F8/12 , C08F214/18 , C08F8/44 , C08F216/14 , C08F2/10 , C08J5/22 , C09D11/52 , H01M8/1004 , H01M8/1039 , H01M4/86 , H01M8/1023 , H01M8/10
摘要： The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula; and one or more divalent units independently represented by formula: The copolymer has an —SO2X equivalent weight in a range from 300 to 2000. A polymer electrolyte membrane that includes the copolymer and a membrane electrode assembly that includes such a polymer electrolyte membrane are also provided.
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5.发明申请公开(公告)号：US20190110960A1
公开(公告)日：2019-04-18
申请号：US15533097
申请日：2015-12-03
发明人： Andreas R. Maurer , Peter Bissinger , Christoph Schulte , Arne Thaler , Joachim W. Zech , Johann Fetz , Peter U. Osswald , Johannes M. Leykauff
摘要： The present invention relates to a hardenable dental composition comprising (A) a curable component comprising curable moieties (AC), (B) a crosslinker component as component (B) capable of crosslinking said component (A), (C) a catalyst as component (C) capable of catalyzing a crosslinking reaction of component (A) and component (B), (D) polymeric particles as filler component (D), the polymeric particles having a maximum particle size of 150 μm or below and being composed of organic polymers, silicone elastomers or a combination or mixture thereof and preferably (E1) an inorganic filler component having a BET surface from 50 to 400 m2/g.The invention also relates to the use of a polymeric particulate filler component (D) for producing a hardenable dental composition, the hardenable dental composition being in particular useful as dental impression or dental retraction material or for dental impression or dental retraction purposes.
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公开(公告)号：US20240274848A1
公开(公告)日：2024-08-15
申请号：US18566288
申请日：2022-06-03
申请人： 3M Innovative Properties Company , Colorado School Of Mines , GM Global Technology Operations LLC
发明人： Michael A. Yandrasits , Matthew J. Lindell , Arne Thaler , Andrew M. Herring , ChulOong Kim , Mei-Chen Kuo , Craig S. Gittleman
IPC分类号： H01M8/1039 , C08F214/26 , C08J5/22 , H01M8/10 , H01M8/1023
CPC分类号： H01M8/1039 , C08F214/262 , C08J5/225 , H01M8/1023 , C08J2327/18 , H01M2008/1095 , H01M2300/0082
摘要： Fluorinated ionomers (i.e., ion conducting polymers) that include a fluorinated polymer backbone with covalently bound pendent groups that include heteropolyacid (HP A) groups, or salts thereof, and perfluorosulfonic acid (PF SA) groups, or salts thereof, as well as polymer electrolyte membranes, fuel cells, and methods.
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公开(公告)号：US11905178B2
公开(公告)日：2024-02-20
申请号：US18254671
申请日：2021-12-14
发明人： Markus E. Hirschberg , Klaus Hintzer , Thomas W. Schoettle , Arne Thaler , Achim Schmidt-Rodenkirchen , Thorsten Gerdes , Konstantin Mierdel
摘要： Methods of converting a variety of fluorinated materials into anhydrous hydrogen fluoride are described. The methods include thermally decomposing the fluorinated materials into a gaseous effluent comprising hydrogen fluoride and carbon dioxide. This gaseous effluent is then treated with carbon at a temperature of at least 830° C., converting the carbon dioxide to carbon monoxide (CO) and producing a gaseous product comprising the hydrogen fluoride, which can be condensed to generate anhydrous hydrogen fluoride. These methods can also be used to convert water contained in the gaseous effluent into hydrogen.
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公开(公告)号：US11377510B2
公开(公告)日：2022-07-05
申请号：US16646638
申请日：2018-09-14
发明人： Lisa P. Chen , Gregg D. Dahlke , Denis Duchesne , Steven J. Hamrock , Klaus Hintzer , Markus E. Hirschberg , Arne Thaler , Tilman C. Zipplies
IPC分类号： C08F214/26 , C08F2/10 , C08F8/12 , C08F214/18 , C08J5/22 , C08F8/44 , C09D11/52 , H01M8/10 , H01M4/86 , C08F216/14 , H01M8/1004 , H01M8/1039 , H01M8/1023
摘要： The copolymer includes divalent units represented by formula —[CF2—CF2]—, divalent units represented by formula: (I), and one or more divalent units independently represented by formula: (II) When Z is hydrogen, the copolymer has an alpha transition temperature of up to 100 ?C. The copolymer has an —SO3Z equivalent weight in a range from 300 to 1400, and a variation of the copolymer in which —SO3Z is replaced with —SO2F has a melt flow index of up to 80 grams per ten minutes measured at a temperature of 265° C. and at a support weight of 5 kg. A catalyst ink or polymer electrolyte membrane including the copolymer are also provided.
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公开(公告)号：US10093820B2
公开(公告)日：2018-10-09
申请号：US14891566
申请日：2014-05-16
IPC分类号： C08K5/07 , C11D3/37 , C09D127/18 , C08J3/03 , C08J3/05 , C08F6/16 , C08F6/20 , C08K5/06 , C08K5/41 , C08K5/42 , C08K5/521 , C09D105/00 , C08K5/053 , C08K5/1545
摘要： Provided are processes for upconcentrating fluoropolymer dispersions. Also provided are upconcentrated dispersions and substrates coated with such dispersions.
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公开(公告)号：US20180273663A1
公开(公告)日：2018-09-27
申请号：US15762267
申请日：2016-09-22
发明人： Gregg D. Dahlke , Denis Duchesne , Klaus Hintzer , Markus E. Hirschberg , Kai H. Lochhaas , Arne Thaler , Tilman C. Zipplies
IPC分类号： C08F214/26 , C08F8/22 , H01M8/1004 , H01M8/1039 , H01M4/86
CPC分类号： C08F214/262 , C08F8/22 , C09D127/18 , C09D127/24 , H01M4/8668 , H01M8/1004 , H01M8/1039 , H01M2008/1095 , H01M2300/0082 , Y02P70/56
摘要： A method of making a copolymer is disclosed. The method includes copolymerizing components including tetrafluoroethylene and a compound represented by formula CF2═CF—O—(CF2)a—SO2—X, wherein “a” is a number from 1 to 4, and X is —NZH, —NZ—SO2—(CF2)1-6—SO2X′, or —OZ, wherein Z is independently a hydrogen, an alkali metal cation, or a quaternary ammonium cation, and wherein X is independently —NZH or —OZ. The components include at least 60 mole % of tetrafluoroethylene based on the total amount of components. A copolymer prepared by the method is also provided. A method of making a membrane using the copolymer is also provided. The present disclosure also provides a polymer electrolyte membrane that includes a copolymer made by the method and a membrane electrode assembly that includes such a polymer electrolyte membrane.
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