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公开(公告)号:US20210301083A1
公开(公告)日:2021-09-30
申请号:US17335694
申请日:2021-06-01
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Motoshi AOYAMA , Kiyotaka TAKAO
IPC: C08G65/336 , C08G65/337 , C08G65/333 , C08G65/00 , C09D5/00 , C09D171/02
Abstract: Processes for producing a fluorinated ether compound are provided by which fluorinated ether compound capable of imparting excellent water/oil repellency, to a substrate surface or a hard coat layer can be easily produced in high yield. A process comprising reacting Rf(CF2)a—CF2OC(═O)Rf4 or Rf(CF2)a—C(═O)X1 with HN(—R1CH═CH2)2 to obtain Rf(CF2)a—C(═O)N(—R1CH2═CH2)2 and a process comprising obtaining the above product and reacting the product with HSiR2nL3−n to obtain Rf(CF2)a—C(═O)N(—R1CH2CH2SiR2nL3−n)2 wherein Rf is a linear polyfluoroalkyl group having at least two carbon atoms and at least one etheric oxygen atom between carbon atoms, Rf4 is a C1-30 perfluoroalkyl group or the like, X1 is a halogen atom, R1 is an alkylene group, a is an integer of from 1 to 5, R2 is a monovalent hydrocarbon group, L is a hydrolyzable group, and n is an integer of from 0 to 2.
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公开(公告)号:US20190218339A1
公开(公告)日:2019-07-18
申请号:US16282406
申请日:2019-02-22
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Motoshi AOYAMA , Kiyotaka TAKAO
IPC: C08G65/336 , C09D171/02 , C09D5/00
CPC classification number: C08G65/336 , C08G65/337 , C08G2150/00 , C09D5/00 , C09D171/02
Abstract: Processes for producing a fluorinated ether compound are provided by which fluorinated ether compound capable of imparting excellent water/oil repellency, to a substrate surface or a hard coat layer can be easily produced in high yield. A process comprising reacting Rf(CF2)a—CF2OC(═O)Rf4 or Rf(CF2)a—C(═O)X1 with HN(—R1CH═CH2)2 to obtain Rf(CF2)a—C(═O)N(—R1CH2═CH2)2 and a process comprising obtaining the above product and reacting the product with HSiR2nL3-n to obtain Rf(CF2)a—C(═O)N(—R1CH2CH2SiR2nL3-n)2 wherein Rf is a linear polyfluoroalkyl group having at least two carbon atoms and at least one etheric oxygen atom between carbon atoms, Rf4 is a C1-30 perfluoroalkyl group or the like, X1 is a halogen atom, R1 is an alkylene group, a is an integer of from 1 to 5, R2 is a monovalent hydrocarbon group, L is a hydrolyzable group, and n is an integer of from 0 to 2.
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公开(公告)号:US20210095160A1
公开(公告)日:2021-04-01
申请号:US17118665
申请日:2020-12-11
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Kiyotaka TAKAO , Kazue TODA , Kenji ISHIZEKI , Akira ISOBE
IPC: C09D201/04 , C09D171/00 , C09D201/10 , C08G65/329 , C08G65/336 , B32B33/00 , C08F259/08 , C08G65/00 , C07F7/18
Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
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公开(公告)号:US20200115589A1
公开(公告)日:2020-04-16
申请号:US16715155
申请日:2019-12-16
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Kiyotaka TAKAO , Kazue TODA , Kenji ISHIZEKI , Akira ISOBE
IPC: C09D201/04 , C09D201/10 , C08F259/08 , B32B33/00 , C09D171/00 , C07F7/18 , C08G65/329 , C08G65/00 , C08G65/336
Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1—O—(Rf1O)m1-Q1[C(O)N(R1)]p1—R11C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; ml is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
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公开(公告)号:US20240352278A1
公开(公告)日:2024-10-24
申请号:US18761449
申请日:2024-07-02
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Kiyotaka TAKAO , Kazue TODA , Kenji Ishizeki , Akira ISOBE
IPC: C09D201/04 , B32B33/00 , C07F7/18 , C08F259/08 , C08G65/00 , C08G65/329 , C08G65/336 , C09D171/00 , C09D201/10
CPC classification number: C09D201/04 , B32B33/00 , C07F7/1804 , C08F259/08 , C08G65/007 , C08G65/329 , C08G65/336 , C09D171/00 , C09D201/10 , B32B2307/7265 , B32B2307/746
Abstract: A fluorinated ether compound is represented by formula: [X23-n2R23n2Si—R22—]3C-R21—[N(R2)C(O)]p2—(Rf2O)m2-Q2-[C(O)N(R2)]p2—R21—C[—R22—SiR23-n2X23-n2]3. Rf2 is a fluoroalkylene group having no branched structure, Q2 is a fluoroalkylene group having no branched structure, R2 is a hydrogen atom or an alkyl group, R21 is a single bond, an alkylene group, an alkylene group comprising an etheric oxygen atom at its terminal on the side bonded to [X23-n2R23n2Si—R22—]3C, an alkylene group with at least two carbon atoms comprising an etheric oxygen atom between its carbon-carbon atoms, or an alkylene group with at least two carbon atoms comprising an etheric oxygen atom between its carbon-carbon atoms and at its terminal on the side bonded to [X23-n2R23n2Si—R22—]3C, R22 is an alkylene group, or the like, R23 is a hydrogen atom or a monovalent hydrocarbon group, and X2 is a hydrolyzable group.
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公开(公告)号:US20210348024A1
公开(公告)日:2021-11-11
申请号:US17443038
申请日:2021-07-20
Applicant: AGC Inc.
Inventor: Keigo MATSUURA , Taiki HOSHINO , Kiyotaka TAKAO , Makoto UNO , Eiichiro ANRAKU , Motoshi AOYAMA , Naoki KATSUKI , Yusuke TOMIYORI , Toyokazu ENTA , Hiromasa YAMAMOTO
IPC: C09D183/10 , C09D5/00 , C09D7/20
Abstract: To provide a composition with which a surface layer excellent in abrasion resistance and sliding resistance can be formed, and an article.
The composition of the present invention comprises a compound represented by the formula (1) and a compound represented by the formula (2), wherein the ratio of the number of moles of the group represented by —CF3 in Rf1 in the formula (1) to the total of the number of moles of the group represented by —CF2— closest to Y1 in Rf2 in the formula (1), the number of moles of the group represented by —CF2— closest to Y2 in Rf3 in the formula (2) and the number of moles of the group represented by —CF2— closest to Y3 in Rf3 in the formula (2), is from 0.001 to 0.1: Rf1—(OX1)m1—O—Rf2—Y1—[Si(R1)n1L13-n1]g1 (1) [L23-n2(R2)n2Si]g2—Y2—Rf3—(OX2)m2—O—Rf4—Y3—[Si(R3)n3L33-n3]g3 (2)-
公开(公告)号:US20210047540A1
公开(公告)日:2021-02-18
申请号:US17038304
申请日:2020-09-30
Applicant: AGC Inc.
Inventor: Taiki HOSHINO , Kiyotaka TAKAO , Kazue TODA , Kenji ISHIZEKI , Akira ISOBE
IPC: C09D201/04 , C08G65/336 , C08G65/00 , C08G65/329 , C07F7/18 , C09D171/00 , B32B33/00 , C08F259/08 , C09D201/10
Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.
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