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公开(公告)号：US20110105784A1
公开(公告)日：2011-05-05
申请号：US12009556
申请日：2008-01-18
IPC分类号： C07C69/52 , C07C51/145 , C07C5/333
CPC分类号： C07C51/252 , B01J35/0006 , C07C67/39 , C10G57/00 , C07C57/04 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared cumulatively from corresponding alkanes utilizing using a multi-staged catalyst system and a multi-stage process which comprises steam cracking of alkanes to corresponding alkenes at flame temperatures and at short contact times in combination with one or more oxidation catalysts for catalytically converting the corresponding alkenes to further corresponding oxygenated products using short contact time reactor conditions.
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2.发明授权Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products 失效多级催化剂体系和将烷烃转化为烯烃及其相应的氧化产物的方法公开(公告)号：US08049036B2
公开(公告)日：2011-11-01
申请号：US12009556
申请日：2008-01-18
IPC分类号： C07C53/00
CPC分类号： C07C51/252 , B01J35/0006 , C07C67/39 , C10G57/00 , C07C57/04 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared cumulatively from corresponding alkanes utilizing using a multi-staged catalyst system and a multi-stage process which comprises steam cracking of alkanes to corresponding alkenes at flame temperatures and at short contact times in combination with one or more oxidation catalysts for catalytically converting the corresponding alkenes to further corresponding oxygenated products using short contact time reactor conditions.
摘要翻译： 烯烃，不饱和饱和羧酸，饱和羧酸及其较高的类似物是使用多阶段催化剂体系和多阶段方法，从相应的烷烃累加制备的，该方法包括在火焰温度和短时间接触下将烷烃蒸汽裂解成相应的烯烃 时间与一种或多种氧化催化剂组合，用于使用短接触时间反应器条件将相应的烯烃催化转化为进一步相应的氧化产物。
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3.发明授权Multi-staged catalyst systems and process for converting alkanes to alkenes and to their corresponding oxygenated products 失效多级催化剂体系和将烷烃转化为烯烃及其相应的氧化产物的方法公开(公告)号：US07361622B2
公开(公告)日：2008-04-22
申请号：US11269434
申请日：2005-11-08
IPC分类号： B01J31/00
CPC分类号： C07C51/252 , B01J35/0006 , C07C67/39 , C10G57/00 , C07C57/04 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared cumulatively from corresponding alkanes utilizing using a multi-staged catalyst system and a multi-stage process which comprises steam cracking of alkanes to corresponding alkenes at flame temperatures and at short contact times in combination with one or more oxidation catalysts for catalytically converting the corresponding alkenes to further corresponding oxygenated products using short contact time reactor conditions.
摘要翻译： 烯烃，不饱和饱和羧酸，饱和羧酸及其较高的类似物是使用多阶段催化剂体系和多阶段方法，从相应的烷烃累加制备的，该方法包括在火焰温度和短时间接触下将烷烃蒸汽裂解成相应的烯烃 时间与一种或多种氧化催化剂组合，用于使用短接触时间反应器条件将相应的烯烃催化转化为进一步相应的氧化产物。
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4.发明授权公开(公告)号：US07026502B2
公开(公告)日：2006-04-11
申请号：US10681420
申请日：2003-10-07
申请人： Abraham Benderly , Anne Mae Gaffney
发明人： Abraham Benderly , Anne Mae Gaffney
CPC分类号： C07C51/215 , C07C67/39 , C07C57/04 , C07C69/54
摘要： Unsaturated carboxylic acids (and esters thereof) are prepared directly from alkanes (and alcohols) utilizing vapor phase oxidative esterification.
摘要翻译： 使用气相氧化酯化直接从烷烃（和醇）制备不饱和羧酸（及其酯）。
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5.发明授权公开(公告)号：US07906699B2
公开(公告)日：2011-03-15
申请号：US12221591
申请日：2008-08-05
IPC分类号： C07C5/02
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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6.发明申请公开(公告)号：US20090048411A1
公开(公告)日：2009-02-19
申请号：US12221591
申请日：2008-08-05
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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7.发明申请Catalytic process for producing ethylene and carbon monoxide mixtures from ethane 审中-公开从乙烷生产乙烯和一氧化碳混合物的催化方法公开(公告)号：US20090082530A1
公开(公告)日：2009-03-26
申请号：US12283955
申请日：2008-09-17
申请人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
发明人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
CPC分类号： C07C5/42 , B01J23/78 , B01J37/0201 , B01J37/03 , C07C45/75 , C07C67/343 , C07C67/38 , C07C2523/745 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising iron oxide supported on an inorganic material to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 600° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过使乙烷和氧源与包含负载在无机材料上的氧化铁的催化剂接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种通过以下步骤生产丙酸烷基酯的方法：（a）在至少600℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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8.发明申请公开(公告)号：US20070287841A1
公开(公告)日：2007-12-13
申请号：US11810654
申请日：2007-06-06
IPC分类号： C07C67/03
CPC分类号： B01J27/10 , B01J27/232 , B01J35/0006 , B01J37/04 , C07C67/03 , C07D233/32 , Y02P20/582 , C07C69/54
摘要： This invention utilizes a mixed salt transesterification catalyst in a transesterification process for the production of esters of alkyl(meth)acrylate monomers.
摘要翻译： 本发明在用于生产（甲基）丙烯酸烷基酯单体的酯的酯交换方法中利用混合盐酯交换催化剂。
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9.发明申请公开(公告)号：US20060004221A1
公开(公告)日：2006-01-05
申请号：US11214275
申请日：2005-08-29
申请人： Abraham Benderly , Anne Gaffney
发明人： Abraham Benderly , Anne Gaffney
IPC分类号： C07C67/05
CPC分类号： C07C51/215 , C07C67/39 , C07C57/04 , C07C69/54
摘要： Unsaturated carboxylic acids (and esters thereof) are prepared directly from alkanes (and alcohols) utilizing vapor phase oxidative esterification.
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10.发明申请公开(公告)号：US20110105708A1
公开(公告)日：2011-05-05
申请号：US12914396
申请日：2010-10-28
CPC分类号： C07C51/44 , C07C51/487 , C07C57/04
摘要： A method is provided herein for purifying (meth)acrylic acid to provide a purified (meth)acrylic acid product having a low aldehyde concentration and not more than 0.2 wt % water. One embodiment of the method includes distilling (meth)acrylic acid in the presence of an aldehyde treating compound. Another embodiment of the method includes also distilling crude (meth)acrylic acid in the presence of a reactive drying agent. (Meth)acrylic acid produced in this manner is especially suitable for use in specialty (meth)acrylic acid polymers, such as for example superabsorbent polymers, binders, and ethylene-(M)AA copolymers.
摘要翻译： 本文提供一种纯化（甲基）丙烯酸以提供具有低醛浓度和不超过0.2重量％水的纯化（甲基）丙烯酸产物的方法。 该方法的一个实施方案包括在醛处理化合物的存在下蒸馏（甲基）丙烯酸。 该方法的另一个实施方案还包括在反应性干燥剂存在下蒸馏粗（甲基）丙烯酸。 以这种方式生产的（甲基）丙烯酸特别适用于特种（甲基）丙烯酸聚合物，例如超吸收聚合物，粘合剂和乙烯 - （M）AA共聚物。
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