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1.发明申请Catalytic process for producing ethylene and carbon monoxide mixtures from ethane 审中-公开从乙烷生产乙烯和一氧化碳混合物的催化方法公开(公告)号：US20090082530A1
公开(公告)日：2009-03-26
申请号：US12283955
申请日：2008-09-17
申请人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
发明人： Rajiv Manohar Banavali , Abraham Benderly , Scott Han , Daniel Joseph Martenak , Jose Antonio Trejo
CPC分类号： C07C5/42 , B01J23/78 , B01J37/0201 , B01J37/03 , C07C45/75 , C07C67/343 , C07C67/38 , C07C2523/745 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source with a catalyst comprising iron oxide supported on an inorganic material to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 600° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过使乙烷和氧源与包含负载在无机材料上的氧化铁的催化剂接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种通过以下步骤生产丙酸烷基酯的方法：（a）在至少600℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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公开(公告)号：US20080015375A1
公开(公告)日：2008-01-17
申请号：US11827490
申请日：2007-07-12
IPC分类号： C11C3/04
摘要： A method for transesterification of triglycerides, especially those containing free fatty acids, with methanol. The method uses a catalyst derived from an acidic ion exchange resin. The catalyst is contacted with a reaction mixture containing a triglyceride and methanol under conditions suitable for transesterification.
摘要翻译： 甘油三酸酯，特别是含有游离脂肪酸的甘油三酯与甲醇的酯交换的方法。 该方法使用由酸性离子交换树脂衍生的催化剂。 在适于酯交换反应条件下，将催化剂与含有甘油三酯和甲醇的反应混合物接触。
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公开(公告)号：US07582784B2
公开(公告)日：2009-09-01
申请号：US11827490
申请日：2007-07-12
IPC分类号： C11B1/00
摘要： A method for transesterification of triglycerides, especially those containing free fatty acids, with methanol. The method uses a catalyst derived from an acidic ion exchange resin. The catalyst is contacted with a reaction mixture containing a triglyceride and methanol under conditions suitable for transesterification.
摘要翻译： 甘油三酸酯，特别是含有游离脂肪酸的甘油三酯与甲醇的酯交换的方法。 该方法使用由酸性离子交换树脂衍生的催化剂。 在适于酯交换反应条件下，将催化剂与含有甘油三酯和甲醇的反应混合物接触。
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4.发明授权公开(公告)号：US07906699B2
公开(公告)日：2011-03-15
申请号：US12221591
申请日：2008-08-05
IPC分类号： C07C5/02
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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5.发明申请Supported catalyst for conversion of propane to propene and its use in a process for that conversion 审中-公开用于将丙烷转化成丙烯的载体催化剂及其在该转化过程中的用途公开(公告)号：US20090182186A1
公开(公告)日：2009-07-16
申请号：US12319765
申请日：2009-01-12
申请人： Abraham Benderly , Wolfgang Ruettinger , Scott Han
发明人： Abraham Benderly , Wolfgang Ruettinger , Scott Han
IPC分类号： C07C5/32
CPC分类号： B01J23/685 , B01J21/08 , B01J23/26 , B01J35/1019 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J35/1066 , B01J37/0201 , C07C5/3332 , C07C5/42 , C07C2521/06 , C07C2521/08 , C07C2523/06 , C07C2523/10 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/50 , Y02P20/52 , C07C11/06
摘要： A process for the conversion of propane to propene is disclosed wherein a silica chromium catalyst composition is contacted with a propane feed stream and a carbon dioxide. The silica chromium catalyst composition is further disclosed wherein the composition, optionally, includes a promoter component.
摘要翻译： 公开了一种将丙烷转化为丙烯的方法，其中将二氧化硅铬催化剂组合物与丙烷进料流和二氧化碳接触。 进一步公开了二氧化硅铬催化剂组合物，其中组合物任选地包含促进剂组分。
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6.发明申请Catalyst systems for converting alkanes to alkenes and to their corresponding oxygenated products 审中-公开将烷烃转化为烯烃及其相应的氧化产物的催化剂体系公开(公告)号：US20050131255A1
公开(公告)日：2005-06-16
申请号：US10987367
申请日：2004-11-12
申请人： Abraham Benderly , Nitin Chadda , Anne Gaffney , Scott Han , Dominique Le , Mark Silvano
发明人： Abraham Benderly , Nitin Chadda , Anne Gaffney , Scott Han , Dominique Le , Mark Silvano
IPC分类号： B01J23/887 , B01J23/00 , B01J23/38 , B01J23/54 , B01J23/62 , B01J23/648 , B01J23/652 , B01J23/76 , B01J27/057 , B01J27/14 , B01J35/00 , B01J35/04 , B01J37/00 , B01J37/02 , B01J37/08 , C07B61/00 , C07C5/327 , C07C5/333 , C07C5/48 , C07C11/06 , C07C51/16 , C07C51/215 , C07C53/122 , C07C57/05 , C07C67/39
CPC分类号： B01J35/0006 , B01J23/002 , B01J23/54 , B01J23/62 , B01J23/6484 , B01J23/6525 , B01J27/0576 , B01J35/04 , B01J37/0036 , B01J37/0215 , B01J2523/00 , C07C5/3335 , C07C5/3337 , C07C51/215 , C07C67/39 , C07C2521/04 , C07C2523/62 , C07C2523/648 , C07C11/02 , C07C57/04 , B01J2523/31 , B01J2523/56 , B01J2523/828 , B01J2523/55 , B01J2523/64 , B01J2523/68 , B01J2523/824 , B01J2523/33 , C07C69/54
摘要： Alkenes, unsaturated saturated carboxylic acids, saturated carboxylic acids and their higher analogues are prepared directly from corresponding alkanes utilizing using a mixed bed catalyst at flame temperatures in a short contact time reactor.
摘要翻译： 烯烃，不饱和饱和羧酸，饱和羧酸及其较高的类似物，可以在短时间接触时间反应器中，在火焰温度下使用混合床催化剂直接从相应的烷烃制备。
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7.发明申请公开(公告)号：US20090048411A1
公开(公告)日：2009-02-19
申请号：US12221591
申请日：2008-08-05
CPC分类号： C07C67/343 , C07C5/42 , C07C5/48 , C07C45/50 , C07C45/75 , C07C67/38 , C07C2523/64 , Y02P20/142 , Y02P20/52 , C07C11/04 , C07C47/22 , C07C69/54 , C07C69/24 , C07C47/02
摘要： A method for producing a mixture of ethylene and carbon monoxide by contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene and carbon monoxide. A method for producing an alkyl propionate by steps of: (a) contacting ethane and an oxygen source at a temperature of at least 500° C. to produce ethylene; (b) contacting an alcohol, ethylene and carbon monoxide with an ethylene carbonylation catalyst to produce the alkyl propionate; and (c) separating the alkyl propionate from byproducts and starting materials. The method further comprises condensing the alkyl propionate with formaldehyde to produce an alkyl methacrylate.
摘要翻译： 通过在至少500℃的温度下使乙烷和氧源接触以产生乙烯和一氧化碳来生产乙烯和一氧化碳的混合物的方法。 一种制备丙酸烷基酯的方法，其步骤为：（a）在至少500℃的温度下使乙烷和氧源接触以产生乙烯; （b）使乙醇，乙烯和一氧化碳与乙烯羰基化催化剂接触以产生丙酸烷基酯; 和（c）将丙酸烷基酯与副产物和原料分离。 该方法还包括将丙酸烷基酯与甲醛缩合以产生甲基丙烯酸烷基酯。
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公开(公告)号：US20050239643A1
公开(公告)日：2005-10-27
申请号：US11112225
申请日：2005-04-22
申请人： Abraham Benderly , Anne Gaffney , Scott Han , Stephen Maroldo
发明人： Abraham Benderly , Anne Gaffney , Scott Han , Stephen Maroldo
IPC分类号： B01J23/00 , B01J23/20 , B01J23/22 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/652 , B01J23/887 , B01J27/057 , B01J35/04 , B01J37/02 , B01J37/34 , C07B61/00 , C07C51/215 , C07C51/25 , C07C57/055
CPC分类号： B01J23/002 , B01J23/20 , B01J23/28 , B01J23/30 , B01J23/34 , B01J23/6525 , B01J23/8877 , B01J27/0576 , B01J35/04 , B01J37/0238 , B01J37/347 , B01J2523/00 , C07C51/215 , C07C51/252 , B01J2523/55 , B01J2523/57 , B01J2523/64 , B01J2523/68 , B01J2523/56 , B01J2523/53 , B01J2523/69 , B01J2523/33 , B01J2523/821 , B01J2523/31 , B01J2523/47 , B01J2523/824 , B01J2523/72 , B01J2523/845 , C07C57/04
摘要： Structured catalysts useful for oxidizing alkanes, alkenes and combinations of alkanes and alkenes are described. The structure catalysts comprise one or more mixed metal oxide catalysts having a three dimensional structure that is self-supporting and that facilitates movement of gas phase reactants and products and one or more mixed metal oxide catalysts deposited on a three dimensional form of continuous unitary structures having openings that facilitates movement of gas phase reactants and products.
摘要翻译： 描述了可用于氧化烷烃，烯烃以及烷烃和烯烃组合的结构化催化剂。 结构催化剂包括一种或多种具有自支撑的三维结构的混合金属氧化物催化剂，并且促进气相反应物和产物的移动，以及沉积在三维形式的连续单一结构上的一种或多种混合金属氧化物催化剂，其具有 有助于气相反应物和产物运动的开口。
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9.发明申请公开(公告)号：US20070287841A1
公开(公告)日：2007-12-13
申请号：US11810654
申请日：2007-06-06
IPC分类号： C07C67/03
CPC分类号： B01J27/10 , B01J27/232 , B01J35/0006 , B01J37/04 , C07C67/03 , C07D233/32 , Y02P20/582 , C07C69/54
摘要： This invention utilizes a mixed salt transesterification catalyst in a transesterification process for the production of esters of alkyl(meth)acrylate monomers.
摘要翻译： 本发明在用于生产（甲基）丙烯酸烷基酯单体的酯的酯交换方法中利用混合盐酯交换催化剂。
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10.发明授权公开(公告)号：US07026502B2
公开(公告)日：2006-04-11
申请号：US10681420
申请日：2003-10-07
申请人： Abraham Benderly , Anne Mae Gaffney
发明人： Abraham Benderly , Anne Mae Gaffney
CPC分类号： C07C51/215 , C07C67/39 , C07C57/04 , C07C69/54
摘要： Unsaturated carboxylic acids (and esters thereof) are prepared directly from alkanes (and alcohols) utilizing vapor phase oxidative esterification.
摘要翻译： 使用气相氧化酯化直接从烷烃（和醇）制备不饱和羧酸（及其酯）。
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