公开(公告)号：US08796481B2

公开(公告)日：2014-08-05

申请号：US13728350

申请日：2012-12-27

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Tiziana Chiodo

IPC: C07F15/00 ,  C07F9/02

CPC classification number: C07F9/6571 ,  C07F9/65744 ,  C07F9/65746

Abstract: The present invention relates to a crystalline non-solvated form of 6,6′-[[3,3′,5,5′-tetrakis(1,1-dimethylethyl)-[1,1′-biphenyl]-2,2′-diyl]bis(oxy)]bis-dibenzo[d,f][1,3,2]-dioxaphosphepine (compound I) and toluene-solvates and acetone-solvates thereof.

Abstract translation: 本发明涉及6,6' - [[3,3'，5,5'-四（1,1-二甲基乙基） - [1,1'-联苯] -2,2]的结晶非溶剂化形式 （氧基）]双 - 二苯并[d，f] [1,3,2] - 二氧杂磷杂环戊烯（化合物I）和甲苯 - 溶剂合物及其丙酮 - 溶剂合物。

公开(公告)号：US20130225849A1

公开(公告)日：2013-08-29

申请号：US13731725

申请日：2012-12-31

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Franz Niklaus Windlin ,  Walid Al-Akhdar

IPC: C07F9/02

CPC classification number: C07F9/025 ,  C07F9/65746

Abstract: The present invention relates to a method of purifying organic diphosphite compounds.

Abstract translation: 本发明涉及一种纯化有机二亚磷酸酯化合物的方法。

公开(公告)号：US20130172596A1

公开(公告)日：2013-07-04

申请号：US13731847

申请日：2012-12-31

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Franz Niklaus Windlin ,  Alexander Tishkov

IPC: C07F9/6571

CPC classification number: C07F9/6571 ,  C07F9/65744 ,  C07F9/65746

Abstract: The present invention relates to a process for preparing 6-chlorodibenzo[d,f][1,3,2]dioxaphosphepin (I) which comprises reacting 2,2′-dihydroxybiphenyl with PCl3 in the presence of a catalytic amount of an acid salt of a nitrogen base, wherein the reaction is carried out in the absence of external organic solvents.

Abstract translation: 本发明涉及一种制备6-氯二苯并[d，f] [1,3,2]二氧杂磷杂环己烷（I）的方法，该方法包括在催化量的酸盐存在下使2,2'-二羟基联苯与PCl 3反应 的氮碱，其中反应在不存在外部有机溶剂的情况下进行。

公开(公告)号：US09969864B2

公开(公告)日：2018-05-15

申请号：US14903645

申请日：2014-07-03

Applicant: BASF SE

Inventor： Wolfgang Peter ,  Adalbert Braig ,  Ulrich Berens ,  Kai-Uwe Schöning ,  Markus Grob ,  Cinzia Tartarini ,  Tania Weyland

IPC: C08K5/3435 ,  C07D211/46 ,  C09D123/06 ,  C09D123/12 ,  C09D127/06 ,  C09D133/12 ,  C09D155/02 ,  C09D167/06 ,  C09D169/00 ,  C09D175/04 ,  C08K5/00 ,  C08K5/34

CPC classification number: C08K5/3435 ,  C07D211/46 ,  C08K5/005 ,  C09D123/06 ,  C09D123/12 ,  C09D127/06 ,  C09D133/12 ,  C09D155/02 ,  C09D167/06 ,  C09D169/00 ,  C09D175/04

Abstract: The present invention relates to symmetric diesters of hydroxyalkyl-4-hydroxy-tetraalkylpiperidine compounds and their use as light stabilizers. They are compatible with and soluble in coating formulations of different polarity.

公开(公告)号：US08841474B2

公开(公告)日：2014-09-23

申请号：US13731847

申请日：2012-12-31

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Franz Niklaus Windlin ,  Alexander Tishkov

IPC: C07F9/6571 ,  C07F9/6574

CPC classification number: C07F9/6571 ,  C07F9/65744 ,  C07F9/65746

Abstract: The present invention relates to a process for preparing 6-chlorodibenzo[d,f][1,3,2]dioxaphosphepin (I) which comprises reacting 2,2′-dihydroxybiphenyl with PCl3 in the presence of a catalytic amount of an acid salt of a nitrogen base, wherein the reaction is carried out in the absence of external organic solvents.

Abstract translation: 本发明涉及一种制备6-氯二苯并[d，f] [1,3,2]二氧杂磷杂环己烷（I）的方法，该方法包括在催化量的酸盐存在下使2,2'-二羟基联苯与PCl 3反应 的氮碱，其中反应在不存在外部有机溶剂的情况下进行。

公开(公告)号：US10370767B2

公开(公告)日：2019-08-06

申请号：US15503459

申请日：2015-08-12

Applicant: BASF SE

Inventor： Nicola Christiane Aust ,  Ulrich Griesbach ,  Ralf Pelzer ,  Thomas Haag ,  Ulrich Berens ,  Jörg Botzem

IPC: C25B3/10

Abstract: Alcohols are prepared by electrochemical reductive coupling of an aromatic vinyl compound and a carbonyl compound in a process which comprises electrolyzing an electrolyte solution in an electrochemical cell, the electrolyte solution comprising the aromatic vinyl compound, the carbonyl compound and a non-aqueous protic solvent, such as methanol, wherein the electrolyte solution is in contact with a carbon-based cathode. Styrene is reacted with acetone to prepare 2-methyl-4-phenyl-2-butanol.

公开(公告)号：US20150191581A1

公开(公告)日：2015-07-09

申请号：US14410979

申请日：2013-07-09

Applicant: BASF SE ,  ROBERT BOSCH GMBH

Inventor： Kai-Uwe Schoening ,  Cinzia Tartarini ,  Walid Al-Akhdar ,  Ulrich Berens ,  Bruno Rotzinger ,  Alexander Dichtl

IPC: C08K5/1535 ,  C08K5/5393 ,  C08K5/17 ,  C08K5/52 ,  C07D307/83 ,  C08K5/05

CPC classification number: C08K5/1535 ,  C07D307/83 ,  C08K5/05 ,  C08K5/17 ,  C08K5/52 ,  C08K5/5393

Abstract: The invention relates to a compound of the formula (I-1) wherein n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24 or 25, R1, R2, R3, R4, R5, R′1, R′2, R′3, R′4, and R′5 are each independently from each other H or C1-C8-alkyl. Compounds of the formula (I-1) or stabilizer mixtures containing compounds of the formula (I-1) are especially used for stabilization of polymers against degradation by oxidation, heat or light.

Abstract translation: 本发明涉及式（I-1）的化合物，其中n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17 ，18，19，20，21，22，23，24或25，R1，R2，R3，R4，R5，R'1，R'2，R'3，R'4和R'5各自独立地 彼此H或C 1 -C 8 - 烷基。 式（I-1）化合物或含有式（I-1）化合物的稳定剂混合物特别用于稳定聚合物以防止氧化，热或光降解。

公开(公告)号：US09328218B2

公开(公告)日：2016-05-03

申请号：US14410979

申请日：2013-07-09

Applicant: BASF SE

Inventor： Kai-Uwe Schoening ,  Cinzia Tartarini ,  Walid Al-Akhdar ,  Ulrich Berens ,  Bruno Rotzinger ,  Alexander Dichtl

IPC: C08K5/15 ,  A61L24/00 ,  C09K3/00 ,  C07D307/00 ,  C08K5/1535 ,  C07D307/83 ,  C08K5/05 ,  C08K5/17 ,  C08K5/52 ,  C08K5/5393

CPC classification number: C08K5/1535 ,  C07D307/83 ,  C08K5/05 ,  C08K5/17 ,  C08K5/52 ,  C08K5/5393

Abstract: The invention relates to a compound of the formula (I-1) wherein n is 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24 or 25, R1, R2, R3, R4, R5, R′1, R′2, R′3, R′4 and R′5 are each independently from each other H or C1-C8-alkyl. Compounds of the formula (I-1) or stabilizer mixtures containing compounds of the formula (I-1) are especially used for stabilization of polymers against degradation by oxidation, heat or light.

Abstract translation: 本发明涉及式（I-1）的化合物，其中n为1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17 ，18,19,20,21,22,23,24或25，R1，R2，R3，R4，R5，R'1，R'2，R'3，R'4和R'5各自独立地为 彼此H或C 1 -C 8烷基。 式（I-1）化合物或含有式（I-1）化合物的稳定剂混合物特别用于稳定聚合物以防止氧化，热或光降解。

公开(公告)号：US09108988B2

公开(公告)日：2015-08-18

申请号：US13731725

申请日：2012-12-31

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Franz Niklaus Windlin ,  Walid Al-Akhdar

IPC: C07F9/547 ,  C07F9/02 ,  C07F9/6574

CPC classification number: C07F9/025 ,  C07F9/65746

Abstract: A method of purifying an organic diphosphite of general formula (I) The method comprises providing a crude organic diphosphite of general formula (I) that is at least partly dissolved in a first solvent (L1), wherein (L1) is selected from the group consisting of alkylbenzenes, aryl alkyl ethers, chlorobenzene, and mixtures thereof, and precipitating by admixing with a second solvent (L2) selected from the group consisting of linear C1-C4-alkanols, ethylene glycol di(C1-C4-alkyl) ethers, and mixtures thereof, and separating off the precipitated organic diphosphite from the solvents.

Abstract translation: 一种纯化通式（I）的有机二亚磷酸酯的方法该方法包括提供至少部分溶解在第一溶剂（L1）中的通式（I）的粗有机二亚磷酸酯，其中（L1）选自 由烷基苯，芳基烷基醚，氯苯及其混合物组成，并通过与选自直链C 1 -C 4 - 链烷醇，乙二醇二（C 1 -C 4 - 烷基）醚， 及其混合物，并从溶剂中分离析出的有机二亚磷酸酯。

公开(公告)号：US20130184478A1

公开(公告)日：2013-07-18

申请号：US13728350

申请日：2012-12-27

Applicant: BASF SE

Inventor： Ulrich Berens ,  Holger Ganz ,  Tiziana Chiodo

IPC: C07F9/6571

CPC classification number: C07F9/6571 ,  C07F9/65744 ,  C07F9/65746

Abstract: The present invention relates to a crystalline non-solvated form of 6,6′-[[3,3′,5,5′-tetrakis(1,1-dimethylethyl)-[1,1′-biphenyl]-2,2′-diyl]bis(oxy)]bis-dibenzo[d,f][1,3,2]-dioxaphosphepine (compound I) and toluene-solvates and acetone-solvates thereof.

Abstract translation: 本发明涉及6,6' - [[3,3'，5,5'-四（1,1-二甲基乙基） - [1,1'-联苯] -2,2]的结晶非溶剂化形式 （氧基）]双 - 二苯并[d，f] [1,3,2] - 二氧杂磷杂环戊烯（化合物I）和甲苯 - 溶剂合物及其丙酮 - 溶剂合物。