公开(公告)号：US20170205710A1

公开(公告)日：2017-07-20

申请号：US15480099

申请日：2017-04-05

Applicant: BASF SE

Inventor： Yuichi NISHIMAE ,  Hisatoshi KURA ,  Kazuhiko KUNIMOTO ,  Ryuhei YAMAGAMI ,  Keita TANAKA

IPC: G03F7/031 ,  G03F7/033 ,  G03F7/20 ,  G02B5/20 ,  G03F7/00 ,  C09D135/02 ,  C08F122/20 ,  C07D209/86 ,  G03F7/26

CPC classification number: G03F7/027 ,  C07D209/86 ,  C07D209/88 ,  C08F122/20 ,  C09D135/02 ,  G02B5/20 ,  G03F7/0007 ,  G03F7/031 ,  G03F7/033 ,  G03F7/20 ,  G03F7/2002 ,  G03F7/2037 ,  G03F7/26 ,  G03F7/30

Abstract: Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

公开(公告)号：US20200004148A1

公开(公告)日：2020-01-02

申请号：US16563984

申请日：2019-09-09

Applicant: BASF SE

Inventor： Yuichi NISHIMAE ,  Hisatoshi KURA ,  Kazuhiko KUNIMOTO ,  Ryuhei YAMAGAMI ,  Keita TANAKA

IPC: G03F7/027 ,  G03F7/00 ,  C07D209/88 ,  G03F7/031 ,  G03F7/20 ,  G03F7/30 ,  C07D209/86 ,  C08F122/20 ,  C09D135/02 ,  G02B5/20 ,  G03F7/033 ,  G03F7/26

Abstract: Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

公开(公告)号：US20200004147A1

公开(公告)日：2020-01-02

申请号：US16563982

申请日：2019-09-09

Applicant: BASF SE

Inventor： Yuichi NISHIMAE ,  Hisatoshi KURA ,  Kazuhiko KUNIMOTO ,  Ryuhei YAMAGAMI ,  Keita TANAKA

IPC: G03F7/027 ,  G03F7/00 ,  C07D209/88 ,  G03F7/031 ,  G03F7/20 ,  G03F7/30 ,  C07D209/86 ,  C08F122/20 ,  C09D135/02 ,  G02B5/20 ,  G03F7/033 ,  G03F7/26

Abstract: Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

公开(公告)号：US20200004146A1

公开(公告)日：2020-01-02

申请号：US16563980

申请日：2019-09-09

Applicant: BASF SE

Inventor： Yuichi NISHIMAE ,  Hisatoshi KURA ,  Kazuhiko KUNIMOTO ,  Ryuhei YAMAGAMI ,  Keita TANAKA

IPC: G03F7/027 ,  G03F7/00 ,  C07D209/88 ,  G03F7/031 ,  G03F7/20 ,  G03F7/30 ,  C07D209/86 ,  C08F122/20 ,  C09D135/02 ,  G02B5/20 ,  G03F7/033 ,  G03F7/26

Abstract: Oxime ester compounds of the formula I, II, III, IV or V wherein Z is for example Z1 for is NO2, unsubstituted or substituted C7-C20aroyl or unsubstituted or substituted C4-C20heteroaroyl; provided that at least one Z1 is other than NO2; Z2 is for example unsubstituted or substituted C7-C20aroyl; R1, R2, R3, R4, R5 and R6 for example are hydrogen, halogen, or unsubstituted or substituted C1-C20alkyl, unsubstituted or substituted C6-C20aryl, or unsubstituted or substituted C4-C20heteroaryl; R9, R10, R11, R12 and R13 for example are hydrogen, halogen, OR16, unsubstituted or substituted C1-C20alkyl; provided that R9 and R13 are neither hydrogen nor fluorine; R14 is for example unsubstituted or substituted C6-C20aryl or C3-C20heteroaryl Q is for example C6-C20arylene or C3-C20heteroarylene; Q1 is —C1-C20alkylene-CO—; Q2 is naphthoylene; Q3 is for example phenylene; L is for example O-alkylene-O—; R15 is for example hydrogen or C1-C20alkyl; R20 is for example hydrogen, or unsubstituted or substituted C1-C20alkyl; are effective photoinitiators.

公开(公告)号：US20160248021A1

公开(公告)日：2016-08-25

申请号：US14913817

申请日：2014-08-14

Applicant: BASF SE

Inventor： Sudhakar SUNDARRAJ ,  Christian EICKHOFF ,  Sheeja BAHULAYAN ,  Robert SEND ,  Yuichi NISHIMAE ,  Helmut REICHELT ,  Junichi TANABE ,  Peter ERK

IPC: H01L51/00 ,  H01L51/42

CPC classification number: H01L51/0068 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029 ,  C09K2211/1037 ,  C09K2211/104 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0046 ,  H01L51/0052 ,  H01L51/0053 ,  H01L51/0065 ,  H01L51/0067 ,  H01L51/0069 ,  H01L51/0071 ,  H01L51/0072 ,  H01L51/0074 ,  H01L51/424 ,  H05B33/10

Abstract: The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described herein, or the acceptor substance comprises or consists of one or more compounds of formula (I) described herein, or the donor substance comprises or consists of a first compound of formula (I) described herein and the acceptor substance comprises a second compound of formula (I) described herein with the proviso that the first and second compound are not the same, as well as to an organic solar cell comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described herein for use as donor substance or as acceptor substance in a photoactive material. Further, the present invention relates to the use of a compound of formula (III) as described herein in the synthesis of a compound of formula (I) as described herein.

Abstract translation: 本发明涉及包含施主物质和受体物质的光活性材料，其中施主物质包含一种或多种本文所述的式（I）化合物或由其组成，或受体物质包含或由一种或多种 本文所述的式（I）或供体物质包含本文所述的第一式（I）化合物或由其组成，并且受体物质包含本文所述的第二式（I）化合物，条件是第一和第二化合物为 不同的是，以及包含所述光活性材料的有机太阳能电池。 本发明还涉及一种光电转换装置，其包含两种或更多种包含所述光活性材料的有机太阳能电池或由本文所述的式（I）化合物用作供体物质或作为光活性材料中的受体物质的组合。 此外，本发明涉及本文所述的式（III）化合物在合成如本文所述的式（I）化合物中的用途。

公开(公告)号：US20160211464A1

公开(公告)日：2016-07-21

申请号：US14913860

申请日：2014-08-14

Applicant: BASF SE

Inventor： Junichi TANABE ,  Yuichi NISHIMAE ,  Christian EICKHOFF ,  Peter ERK ,  Ruediger SENS ,  Robert SEND ,  Sudhakar SUNDARRAJ

IPC: H01L51/00 ,  C07D513/22 ,  C07F7/08 ,  C07D498/04 ,  C07D498/22

CPC classification number: H01L51/0071 ,  C07D487/04 ,  C07D498/04 ,  C07D498/22 ,  C07D513/04 ,  C07D513/22 ,  C07D519/00 ,  C07F7/0816 ,  H01L51/0046 ,  H01L51/0067 ,  H01L51/0068 ,  H01L51/0072 ,  H01L51/0094 ,  H01L51/424 ,  H01L51/4253 ,  H01L51/4273 ,  H01L2251/308 ,  Y02E10/549

Abstract: The present invention relates to a photoactive material comprising a donor substance and an acceptor substance, wherein the donor substance comprises or consists of one or more compounds of formula (I) described below, or the acceptor substance comprises or consists of one or more compounds of formula (I) described below, or the donor substance comprises or consists of a first compound of formula (I) described below and the acceptor substance comprises a second compound of formula (I) described below with the proviso that the first and second compound are not the same, as well as to an organic solar cell or photodetector comprising said photoactive material. The present invention also relates to a photoelectric conversion device comprising or consisting of two or more organic solar cells comprising said photoactive material and to compounds of formula (I) as described below for use as donor substance or as acceptor substance in a photoactive material.

Abstract translation: 本发明涉及包含施主物质和受体物质的光活性物质，其中供体物质包含一种或多种下述式（I）化合物或由其组成，或受体物质包含或由一种或多种 或者供体物质包含下述式（I）的第一化合物或由其组成，受体物质包含下述第二化合物（I），条件是第一和第二化合物为 不同的是，以及包含所述光活性材料的有机太阳能电池或光电探测器。 本发明还涉及一种光电转换装置，其包含两种或更多种包含所述光活性材料的有机太阳能电池或由以下所述的式（I）化合物或用作光活性材料中的受体物质或作为受体物质的有机太阳能电池组成。