公开(公告)号：US20160280846A1

公开(公告)日：2016-09-29

申请号：US15032324

申请日：2014-12-02

Applicant: DOW GLOBAL TECHNOLOGIES LLC

Inventor： Krishnan Karunakaran ,  Marvin L. Dettloff ,  Nikhil K.E. Verghese ,  Ha Q. Pham

IPC: C08G59/50 ,  C08G59/42 ,  C08G59/24

CPC classification number: C08G59/50 ,  C08F283/065 ,  C08G59/245 ,  C08G59/4215 ,  C08J3/243 ,  C08J3/246 ,  C08J2363/02 ,  C08K5/14 ,  C08L51/08 ,  C08L63/00 ,  C08L83/00 ,  C08L51/00 ,  C08L71/00

Abstract: A dual cure system including at least two different and separate types of chemical reactions occurring as the process of the present invention proceeds including, for example, the following two reactions: (1) free radical polymerization of methacrylated or acrylated polyol; and (2) an epoxy-curing agent reaction. The dual cure system of the present invention advantageously provides a first cure reaction of methacrylated or acrylated polyol followed by a second epoxy-curing agent thermoset reaction to form a cured thermoset exhibiting an elongation property of greater than about 5%.

Abstract translation: 包括如本发明的方法发生的至少两种不同和分开的化学反应类型的双重固化体系包括例如以下两个反应：（1）甲基丙烯酸酯化或丙烯酸酯化的多元醇的自由基聚合; 和（2）环氧固化剂反应。 本发明的双重固化体系有利地提供了甲基丙烯酸酯化或丙烯酸酯化的多元醇的第一固化反应，然后进行第二次环氧固化剂热固化反应以形成展现出大于约5％的伸长率的固化的热固性材料。

公开(公告)号：US20150065613A1

公开(公告)日：2015-03-05

申请号：US14387555

申请日：2013-04-03

Applicant: Dow Global Technologies LLC ,  Dow MF Produktions GmbH & Co. OHG

Inventor： Bharati Balijepalli ,  Theofanis Theofanous ,  Bernd Hoevel ,  Nikhil E. Verghese ,  Ha Q. Pham

IPC: C09J163/00 ,  C08K7/14 ,  C08K3/36

CPC classification number: C09J163/00 ,  C08G59/50 ,  C08K3/36 ,  C08K7/14 ,  C08K2201/016 ,  C09J2463/00

Abstract: A curable epoxy adhesive composition including (a) at least one first epoxy resin; (b) at least one first diluent; (c) at least one first hardener; (d) at least a first hydrophilic filler that has a predetermined aspect ratio; (e) at least a second hydrophobic filler that is different from the first filler and that has a predetermined aspect ratio; and (f) at least a third filler that is different from the first and second fillers; wherein the third filler has a predetermined aspect ratio higher than the first filler and the second filer; and wherein the volume ratio of the third filler to the combination of the first filler and second filler is in the range of from 1:1 to 10:1 such as to minimize the thermal residual stresses of the cured product made from the curable composition.

Abstract translation: 一种可固化环氧粘合剂组合物，其包含（a）至少一种第一环氧树脂; （b）至少一种第一稀释剂; （c）至少一种第一硬化剂; （d）至少一种具有预定长宽比的第一亲水性填料; （e）至少第二疏水性填料，其与第一填料不同，并具有预定的纵横比; 和（f）至少一种不同于第一和第二填料的填料; 其中所述第三填料具有比所述第一填料和所述第二填料高的预定纵横比; 并且其中第三填料与第一填料和第二填料的组合的体积比在1:1至10:1的范围内，以使得由可固化组合物制成的固化产物的热残余应力最小化。

公开(公告)号：US20160289444A1

公开(公告)日：2016-10-06

申请号：US15181896

申请日：2016-06-14

Applicant: Dow Global Technologies LLC

Inventor： Kandathil Eapen Verghese ,  Ha Q. Pham ,  George Jacob ,  Marvin L. Dettioff

IPC: C08L63/00 ,  C08J3/20 ,  C08J3/24 ,  C08J3/00

CPC classification number: C08L63/00 ,  C08J3/005 ,  C08J3/203 ,  C08J3/24 ,  C08J2363/00 ,  C08J2471/02 ,  C08K3/36 ,  C08L71/02 ,  C08L2205/05 ,  C08L2666/22 ,  C08L2666/54 ,  C08L2666/08

Abstract: Curable compositions, cured compositions, and methods of forming the same, including an epoxy resin, a curing agent, an amphiphilic toughening agent, and an inorganic nanofiller, wherein the toughening agent forms a second phase having at least one dimension being on the nanometer scale.

Abstract translation: 可固化组合物，固化组合物及其形成方法，包括环氧树脂，固化剂，两亲增韧剂和无机纳米填料，其中增韧剂形成至少一个尺寸在纳米级的第二相 。

公开(公告)号：US20150141602A1

公开(公告)日：2015-05-21

申请号：US14399413

申请日：2013-04-16

Applicant: Dow Global Technologies LLC

Inventor： Marvin L. Dettloff ,  Richard J. Keaton ,  Ha Q. Pham ,  Nikhil E. Verghese

IPC: C08F32/08 ,  C07C7/00 ,  C07C7/148

CPC classification number: C08F32/08 ,  C07C7/005 ,  C07C7/1485 ,  C07C2603/68 ,  C08G61/08 ,  C08G2261/3325 ,  C08G2261/418 ,  C08K3/22 ,  C08L65/00 ,  C07C13/61

Abstract: A monomer treatment process including treating at least one metathesis polymerizable monomer composition having a purity of less than 95 weight percent of a dicyclopentadiene monomer with an alkali metal-containing additive prior to polymerizing the metathesis polymerizable monomer composition such that the treated polymerized monomer exhibits improved properties in metathesis reactions.

Abstract translation: 一种单体处理方法，包括在使可转移聚合单体组合物聚合之前，用含碱金属的添加剂处理具有小于95重量％的二环戊二烯单体的纯度的至少一种易位可聚合单体组合物，使得经处理的聚合单体表现出改进的性能 在复分解反应中。

公开(公告)号：US20130251931A1

公开(公告)日：2013-09-26

申请号：US13856757

申请日：2013-04-04

Applicant: Dow Global Technologies LLC

Inventor： Zeng Kun Liao ,  Fabio Aguirre Vargas ,  Ha Q. Pham ,  Gyongyi Gulyas

IPC: C09D163/00

CPC classification number: C09D163/00 ,  C08G59/1477 ,  Y10T428/1393 ,  Y10T428/31529

Abstract: Thermosetting epoxy-terminated oxazolidinone ring containing polymers which are obtainable by reacting at least one polyisocyanate compound with at least one hydroxy group containing epoxy resin and/or a combination of at least one epoxy resin and at least one di- or multifunctional nucleophilic compound that is capable of forming crosslinks between epoxy groups. The polymers have an onset glass transition temperature of at least about 45° C. and are capable of showing an onset glass transition temperature in the cured state at least about 160° C. Powder coating compositions comprising these polymers are also disclosed.

Abstract translation: 通过使至少一种多异氰酸酯化合物与至少一种含羟基的环氧树脂和/或至少一种环氧树脂和至少一种二官能或多官能的亲核化合物的组合使至少一种多异氰酸酯化合物与至少一种含羟基的环氧树脂反应而得到的热固性环氧基封端的恶唑烷酮环 能够在环氧基之间形成交联。 聚合物的起始玻璃化转变温度为至少约45℃，并且能够在至少约160℃的固化状态下显示起始玻璃化转变温度。还公开了包含这些聚合物的粉末涂料组合物。