摘要:
Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.
摘要:
Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.
摘要:
Organosilanolate powders having a low cation to silicon ratio provide superior hydrophobing ability. The powders may be prepared on an industrial scale by hydrolysis of a silane with a basic salt solution, adding an inert organic solvent, and removing gaseous or alcoholic hydrolysis products by evaporation or distillation, precipitating the organosilanolate as a fine powder.
摘要:
Organosilanolate powders having a low cation to silicon ratio provide superior hydrophobing ability. The powders may be prepared on an industrial scale by hydrolysis of a silane with a basic salt solution, adding an inert organic solvent, and removing gaseous or alcoholic hydrolysis products by evaporation or distillation, precipitating the organosilanolate as a fine powder.
摘要:
Organopolysiloxanes having aminoalkyl groups are prepared by (i) reacting (A) linear, cyclic or branched organopolysiloxanes with (B) aminoalkylsilanes which have an SiC-bonded, basic nitrogen-containing hydrocarbon radical and 2 or 3 hydrolyzable groups, or the partial or complete hydrolysis products thereof, optionally in the presence of (C) basic catalysts and/or (D) chain-terminating reagents, and (ii) optionally, after the reaction (i) neutralizing the optionally used basic catalysts (c), with the proviso that compounds (A), (B) and, when used, (D) are reacted continuously in a reaction space whose ratio of length to diameter is equal to or greater than four.
摘要:
The present invention relates to colored organopolysiloxanes comprising units of the formula R1a(RO)bAcR2dSiO(4-a-b-c-d)/2 (I), in which R can be identical or different and is hydrogen or a monovalent, unsubstituted or substituted hydrocarbon radical; R1 can be identical or different and is hydrogen or a monovalent, SiC-bonded, unsubstituted or substituted hydrocarbon radical; R2 can be identical or different and is a substituted monovalent hydrocarbon radical; A can be identical or different and is an organic dye radical free from sulfonic acid groups and sulfonate groups; a is 0, 1, 2 or 3; b is 0, 1, 2 or 3; d is 0, 1, 2 or 3; and c is 0, 1 or 2; with the proviso that the sum a+b+c+d is ≦3, the organopolysiloxane has at least one radical A per molecule, and in the units of the formula (I) where c is other than 0 when d is 0. The invention also relates to a process to the color organopolysiloxane.
摘要翻译:本发明涉及包含下式的单元的有色有机聚硅氧烷:式中:α-in-line-formula description =“In-line formula”end =“lead”→> R1a(RO)bAcR2dSiO(4-abcd)/ 2(I) 其中R可以相同或不同,为氢或一价,未取代或取代的烃基的“?”in-line-formula description =“In-line Formulas”end =“tail”? R 1可以相同或不同,为氢或一价,SiC键合的未取代或取代的烃基; R2可以相同或不同,并且是取代的单价烃基; A可以相同或不同,是不含磺酸基和磺酸基的有机染料基团; a是0,1,2或3; b为0,1,2或3; d为0,1,2或3; 且c为0,1或2; 条件是总和a + b + c + d为<= 3,有机聚硅氧烷每分子具有至少一个基团A,并且在式(I)的单元中,当d为0时,c不为0。 本发明还涉及彩色有机聚硅氧烷的方法。
摘要:
Organopolysiloxanes having aminoalkyl groups are prepared by(i) reacting(A) linear, cyclic or branched organopolysiloxanes with(B) aminoalkyl silanes having an SiC-bonded hydrocarbon radical comprising basic nitrogen and 2 or 3 hydrolyzable groups, or partial or full hydrolyzates thereof, in the presence of(C) basic catalysts and optionally(D) chain-terminating reagents, at a temperature of at least 60° C., then, after the reaction (i),(ii) deactivating the catalysts (C) and(iii) cooling the product to a temperature below 60° C. before, during or after the deactivation (ii) of the catalysts, with the proviso that the process is performed in at least two successive stirred tanks, the reaction (i) and the cooling (iii) proceeding separately in different stirred tanks.
摘要:
Silicone resin emulsions especially suitable for hydrophobing gypsum compositions together with H-siloxanes are prepared by hydrolysis and subsequent distillation to an alcohol content of less than 0.1 weight percent. Use of the emulsion with H-siloxanes provides plaster products such as plasterboard of increased hydrophobicity.
摘要:
Organopolysiloxanes having aminoalkyl groups are prepared by (i) reacting (A) linear, cyclic or branched organopolysiloxanes with (B) aminoalkylsilanes which have an SiC-bonded, basic nitrogen-containing hydrocarbon radical and 2 or 3 hydrolyzable groups, or the partial or complete hydrolysis products thereof, optionally in the presence of (C) basic catalysts and/or (D) chain-terminating reagents, and (ii) optionally, after the reaction (i) neutralizing the optionally used basic catalysts (c), with the proviso that compounds (A), (B) and, when used, (D) are reacted continuously in a reaction space whose ratio of length to diameter is equal to or greater than four.
摘要:
Organopolysiloxanes having aminoalkyl groups are prepared by (i) reacting (A) linear, cyclic or branched organopolysiloxanes with (B) aminoalkyl silanes having an SiC-bonded hydrocarbon radical comprising basic nitrogen and 2 or 3 hydrolyzable groups, or partial or full hydrolyzates thereof, in the presence of (C) basic catalysts and optionally (D) chain-terminating reagents, at a temperature of at least 60° C., then, after the reaction (i), (ii) deactivating the catalysts (C) and (iii) cooling the product to a temperature below 60° C. before, during or after the deactivation (ii) of the catalysts, with the proviso that the process is performed in at least two successive stirred tanks, the reaction (i) and the cooling (iii) proceeding separately in different stirred tanks.