Abstract:
Solid alkali metal salts of organosilanols and/or their hydrolysis/condensation products are prepared by hydrolysis of organosilanes in water and in the presence of a basic alkali metal salt. The products contain predominately methyl and ethyl organic groups, and C4 or higher hydrocarbon groups as well. The solid salts effectively hydrophobe building materials, while being easily mixed with water.
Abstract:
Trichlorosilane production is increased while simultaneously lowering environmental burden due to destruction and disposition of high boilers by feeding high boilers from trichlorosilane production or from polycrystalline silicon production into a fluidized bed for production of trichlorosilane from metallic silicon and hydrogen chloride.
Abstract:
The invention relates to a method for producing neopentasilanes of the general formula (1) Si(SiR3)4 (1), wherein silicon compounds of the general formula (2) R3Si— (SiR2—)xSiR3 (2), where R is selected from Cl, Br, and I, and x is a non-negative whole number up to 5, are converted in the presence of catalytically active compounds (K), wherein the separating of the tetrahalogen silane formed thereby takes place by distilling out in the presence of a compound (L) that is liquid at room temperature having a higher boiling point than the released tetrahalogen silane.
Abstract:
The invention relates to a method for hydrolyzing hydrolyzable solid metallic salts, wherein the metallic salts are reacted with aqueous saline solutions.
Abstract:
The invention relates to a method for hydrolyzing hydrolyzable solid metallic salts, the metallic salts being reacted with aqueous saline solutions.
Abstract:
The invention relates to organosilicon compounds with at least three silicon atoms, consisting of units of the formula (I) RaSi(NR1C═ONR22)k(NR3C═ONR4)t/2YmOn/2[(CR52)s]r/2, where Y represents units of the formula (II) —SiR63-p-q(NR1C═ONR22)p(NR3C═ONR4)q/2, where R, R1, R2, R3, R4, R5 and R6 independently of each other can be either identical or different and represent a hydrogen atom or possibly substituted monovalent hydrocarbon radicals with between 1 and 20 carbon atoms; and where a, k, t, n, m, r, s, p and q have the meaning assigned to them in claim 1, under the provision that the sum of p+q is ≦3, the sum of a+k+l+m+n+r equals 4, the sum of m+r equals 0 or 1, and the organosilicon compound of the invention contains at least one unit of formula (I) where t is not equal to 0.
Abstract:
Disclosed are organopolysiloxane preparations containing: A) units of the formula (I): (R.sup.1 O).sub.a SiHR.sup.2.sub.2-a O1/2, in which R.sup.1 and R.sup.2, which may be the same or different, are each, independently of each other, an optionally substituted monovalent hydrocarbon group and a is 1 or 2, B) siloxane units which can be cross-linked by irradiating and, optionally, C) siloxane units acting as photo-initiators. These preparations are useful for the production of coatings.
Abstract:
The invention provides a process for preparing carbamatoorganosilanes (S) of the general formula (7) in which a haloorganosilane (S1) of the general formula (8) is reacted with a metal cyanate (MOCN) and an alcohol (A) of the general formula (9) in the presence of at least one aprotic solvent (L), where R1, R3 and R4 are each an unsubstituted or halogen-substituted hydrocarbyl radical having 1-10 carbon atoms, R2 is a divalent unsubstituted or halogen-substituted hydrocarbyl radical which has 1-10 carbon atoms and may be interrupted by nonadjacent oxygen atoms, X is a halogen atom, and x is a value of 0, 1, 2 or 3, where the removal of the solid metal halides formed as by-products and of any solid metal cyanate residues still present is preceded by distillative removal of at least 50% of the solvent (L).
Abstract:
The invention relates to a method for producing silicon compounds (A) having hydrocarbon oxy-groups that have at least one unit of the general formula (1) HmSi(OR)n(OR′)oR″pX4-m-n-o-p (1) by conversion of silicon compounds (B) having at least one unit of the general formula (2) Hm+nSi(OR′)oR″pX4-m-n-o-p (2), having an alcohol of the general formula (3) ROH (3) in the presence of a catalyst (K) that is on a carrier material bonded metal selected from Ni, Pd, Pt, wherein per mol formed group OR, at maximum 1 liter of solvent is used and wherein R, R′, R″, X, m, n, o and p have the meanings listed in claim 1.
Abstract:
The invention relates to a method for hydrolyzing hydrolyzable metallic salts, the metallic salts being reacted with emulsions of a) water and b) an inert liquid.