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公开(公告)号：US08426547B2
公开(公告)日：2013-04-23
申请号：US12748458
申请日：2010-03-29
申请人： Fang-Hsien Su , Chi-Hung Liu , Chun-Hsiung Kao , An-Pang Tu , Kuen-Yuan Hwang
发明人： Fang-Hsien Su , Chi-Hung Liu , Chun-Hsiung Kao , An-Pang Tu , Kuen-Yuan Hwang
CPC分类号： C08G59/304 , C08G59/1488
摘要： A phosphorus-containing epoxy resin and a method for synthesizing the same are disclosed. The method includes the step of catalytically reacting compound (i) with compound (ii) to synthesize the phosphorus-containing epoxy resin having the structure of compound (I). R is methyl or phenyl, and n is the integer from 1 to 9.
摘要翻译： 公开了含磷环氧树脂及其合成方法。 该方法包括使化合物（i）与化合物（ⅱ）催化反应合成具有化合物（I）结构的含磷环氧树脂的步骤。 R为甲基或苯基，n为1至9的整数。
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公开(公告)号：US06900269B2
公开(公告)日：2005-05-31
申请号：US10412126
申请日：2003-04-11
申请人： Kuen-Yuan Hwang , An-Pang Tu , Mong Liang , Chi-Yi Ju , Sheng-Yen Wu , Chun-Hsiung Kao , Fang-Shian Su
发明人： Kuen-Yuan Hwang , An-Pang Tu , Mong Liang , Chi-Yi Ju , Sheng-Yen Wu , Chun-Hsiung Kao , Fang-Shian Su
IPC分类号： C09K21/14 , C08G59/30 , C08G59/40 , C08G59/50 , C08K3/00 , C08L63/00 , C08L63/02 , C08L71/12 , C09D11/00 , C09J7/00 , C09J163/00 , C09J171/10 , H05K1/03
CPC分类号： C08G59/5046 , C08G59/304 , C08L63/00 , C08L71/12 , H05K1/0326 , C08L2666/22
摘要： Disclosed is a halogen-free resin composition comprising: (A) one or more phosphorus-containing epoxy resins; (B) a hardener; (C) a hardening accelerator; (D) a polyphenylene oxide resin; and (E) a filling material, wherein the hardener of component B has the structure represented by the following formula (I): wherein each symbol is as defined above. The halogen-free resin composition of the present invention without adding halogen has excellent heat resistance and flame retardant property, and excellent dielectric property. The halogen-free resin composition of the present invention is particularly useful in the application of bonding sheets, composite materials, laminated plates, printed circuit boards, copper foil adhesives, inks used for build-up process, semiconductor packaging materials and the like.
摘要翻译： 公开了一种无卤树脂组合物，其包含：（A）一种或多种含磷环氧树脂; （B）硬化剂; （C）硬化促进剂; （D）聚苯醚树脂; 和（E）填充材料，其中组分B的硬化剂具有由下式（I）表示的结构：其中每个符号如上所定义。 不添加卤素的本发明的无卤树脂组合物具有优异的耐热性和阻燃性，并且具有优异的介电性能。 本发明的无卤素树脂组合物特别适用于粘合片，复合材料，层压板，印刷电路板，铜箔粘合剂，用于堆积工艺的油墨，半导体包装材料等的应用。
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公开(公告)号：US08222441B2
公开(公告)日：2012-07-17
申请号：US12385573
申请日：2009-04-13
申请人： Ching-Hsuan Lin , Tsung Li Lin , Chia Wei Chang , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
发明人： Ching-Hsuan Lin , Tsung Li Lin , Chia Wei Chang , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
CPC分类号： C07F9/657172 , C08K5/5313 , C09K21/12
摘要： A series of novel phosphorus-containing compounds having the following formula are disclosed: wherein R1-R12, A, B, D, X, and Y are as defined in the specification. A process for the preparation of the compound of formula (1), a curing agent, and a flame resistant epoxy resin and a preparation process thereof are also provided.
摘要翻译： 公开了一系列具有下式的新型含磷化合物：其中R1-R12，A，B，D，X和Y如说明书中所定义。 还提供了制备式（1）化合物，固化剂和阻燃环氧树脂的方法及其制备方法。
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公开(公告)号：US08134021B2
公开(公告)日：2012-03-13
申请号：US12502241
申请日：2009-07-14
申请人： Ching-Hsuan Lin , Chia-Wei Chang , Tsung-Li Lin , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
发明人： Ching-Hsuan Lin , Chia-Wei Chang , Tsung-Li Lin , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
IPC分类号： C07D413/10 , C07F9/28
CPC分类号： C07F9/657172
摘要： The Phosphorus-containing bisphenols and preparing method thereof are disclosed. A method for producing the phosphorus-containing bisphenol of the formula (1) includes reacting compounds respectively defined by a formula (a), (b), (c) and an acid catalyst to yield compounds of phosphorus-containing bisphenol.
摘要翻译： 公开了含磷双酚及其制备方法。 制备式（1）的含磷双酚的方法包括分别由式（a），（b），（c）和酸催化剂定义的化合物反应，得到含磷双酚的化合物。
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5.发明申请公开(公告)号：US20090258997A1
公开(公告)日：2009-10-15
申请号：US12385573
申请日：2009-04-13
申请人： Ching-Hsuan Lin , Tsung Li Lin , Chia Wei Chang , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
发明人： Ching-Hsuan Lin , Tsung Li Lin , Chia Wei Chang , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
CPC分类号： C07F9/657172 , C08K5/5313 , C09K21/12
摘要： A series of novel phosphorus-containing compounds having the following formula are disclosed: wherein R1-R12, A, B, D, X, and Y are as defined in the specification. A process for the preparation of the compound of formula (1), a curing agent, and a flame resistant epoxy resin and a preparation process thereof are also provided.
摘要翻译： 公开了一系列具有下式的新型含磷化合物：其中R1-R12，A，B，D，X和Y如说明书中所定义。 还提供了制备式（1）化合物，固化剂和阻燃环氧树脂的方法及其制备方法。
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公开(公告)号：US20090171120A1
公开(公告)日：2009-07-02
申请号：US12017067
申请日：2008-01-21
申请人： Ching-Hsuan Lin , Ya-Ru Taso , Chau-Wei Hsieh , Hao-Hsin Lee , Fang-Hsien Su , An-Pang Tu , Kuen-Yuan Hwang
发明人： Ching-Hsuan Lin , Ya-Ru Taso , Chau-Wei Hsieh , Hao-Hsin Lee , Fang-Hsien Su , An-Pang Tu , Kuen-Yuan Hwang
IPC分类号： C07F9/02
CPC分类号： C07F9/657172
摘要： The present invention provides phosphorus-based oxazine compounds and the preparation method thereof. The phosphorus-based oxazine compounds of the present invention can provide better fire-resistant characteristics, while the preparation method for the phosphorus-based oxazine compound of the present invention can offer high yields and/or high purity phosphorus-based oxazine compounds.
摘要翻译： 本发明提供磷基恶嗪化合物及其制备方法。 本发明的磷基恶嗪化合物可以提供更好的耐火特性，而本发明的磷系恶嗪化合物的制备方法可以提供高产率和/或高纯度的磷基恶嗪化合物。
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公开(公告)号：US08242266B2
公开(公告)日：2012-08-14
申请号：US13353330
申请日：2012-01-19
申请人： Ching-Hsuan Lin , Chia-Wei Chang , Tsung-Li Lin , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
发明人： Ching-Hsuan Lin , Chia-Wei Chang , Tsung-Li Lin , Kuen-Yuan Hwang , An-Pang Tu , Fang-Hsien Su
IPC分类号： C07D413/10
CPC分类号： C07F9/657172
摘要： The Phosphorus-containing bisphenols and preparing method thereof are disclosed. A method for producing the phosphorus-containing bisphenol of the formula (1) includes reacting compounds respectively defined by a formula (a), (b), (c) and an acid catalyst to yield compounds of phosphorus-containing bisphenol.
摘要翻译： 公开了含磷双酚及其制备方法。 制备式（1）的含磷双酚的方法包括分别由式（a），（b），（c）和酸催化剂定义的化合物反应，得到含磷双酚的化合物。
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公开(公告)号：US07566780B2
公开(公告)日：2009-07-28
申请号：US12017067
申请日：2008-01-21
申请人： Ching-Hsuan Lin , Ya-Ru Taso , Chau-Wei Hsieh , Hao-Hsin Lee , Fang-Hsien Su , An-Pang Tu , Kuen-Yuan Hwang
发明人： Ching-Hsuan Lin , Ya-Ru Taso , Chau-Wei Hsieh , Hao-Hsin Lee , Fang-Hsien Su , An-Pang Tu , Kuen-Yuan Hwang
IPC分类号： C07D413/02 , C07D413/14
CPC分类号： C07F9/657172
摘要： The present invention provides phosphorus-based oxazine compounds and the preparation method thereof. The phosphorus-based oxazine compounds of the present invention can provide better fire-resistant characteristics, while the preparation method for the phosphorus-based oxazine compound of the present invention can offer high yields and/or high purity phosphorus-based oxazine compounds.
摘要翻译： 本发明提供磷基恶嗪化合物及其制备方法。 本发明的磷基恶嗪化合物可以提供更好的耐火特性，而本发明的磷系恶嗪化合物的制备方法可以提供高产率和/或高纯度的磷基恶嗪化合物。
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公开(公告)号：US20080262127A1
公开(公告)日：2008-10-23
申请号：US12018099
申请日：2008-01-22
申请人： Kuen-Yuan Hwang , An-Pang Tu , Gai-Chi Chen , I-Cheng Hsu
发明人： Kuen-Yuan Hwang , An-Pang Tu , Gai-Chi Chen , I-Cheng Hsu
CPC分类号： C08G59/3218 , C08G59/621 , C08K3/013 , C08L63/00 , C08L2666/54
摘要： A flame resistant resin composition is provided, which includes: (A) at least an epoxy resin having a biphenylic unit or a naphthalenic unit; (B) phenolic resins used as a curing agent, the phenolic resins include at least a phenolic resin having a biphenylic moiety and a polyphenolic moiety, wherein the the at least a phenolic resin having a biphenylic moiety and a polyphenolic moiety is in an amount of 30 to 100 wt % of the total weight of the curing agents; (C) a curing-promoting agent; and (D) an inorganic filler material. The resin composition includes an epoxy resin having a biphenylic unit or a naphthalenic unit and the phenolic resin having a biphenylic moiety and a polyphenolic moiety as a curing agent, such that excellent flame resistance can be achieved without adding flame resistant agents. The resin composition also has a higher glass transition temperature to improve the water absorption issue after curing, and increases heat stability. Therefore, the resin composition is particularly useful in composite materials, forming materials or semiconductor packaging materials.
摘要翻译： 提供了一种阻燃树脂组合物，其包括：（A）至少一种具有联苯单元或萘单元的环氧树脂; （B）用作固化剂的酚醛树脂，酚醛树脂至少包括具有联苯部分和多酚部分的酚醛树脂，其中至少一种具有联苯部分和多酚部分的酚醛树脂的量为 30至100重量％的固化剂总重量; （C）固化促进剂; 和（D）无机填料。 树脂组合物包括具有联苯单元或萘单元的环氧树脂和具有联苯部分和多酚部分作为固化剂的酚醛树脂，使得可以在不添加阻燃剂的情况下实现优异的阻燃性。 树脂组合物还具有较高的玻璃化转变温度，以改善固化后的吸水问题，并且增加热稳定性。 因此，树脂组合物特别适用于复合材料，成型材料或半导体封装材料。
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公开(公告)号：US20080054234A1
公开(公告)日：2008-03-06
申请号：US11894890
申请日：2007-08-21
申请人： Kuen-Yuan Hwang , An-Pang Tu , Chih-Fu Chen , Gai-Chi Chen
发明人： Kuen-Yuan Hwang , An-Pang Tu , Chih-Fu Chen , Gai-Chi Chen
IPC分类号： C09K21/14
CPC分类号： C09K21/14 , C08G59/68 , C08L63/00 , C08L2666/16
摘要： A nonflammable resin composition comprises (A) at least an epoxy resin with biphenyl unit or naphthyl unit; (B) at least a phenolic resin used as a hardener, wherein the phenolic resin has a skeleton formed by phenyl rings bonding directly each other without interruption, and is in an amount of 30 to 100% by weight based on total hardeners; and (C) a curing catalyst. The said nonflammable resin has an excellent flame retardancy, a good heat resistance, and an improved moldability and reliability.
摘要翻译： 不燃性树脂组合物包含（A）至少一种具有联苯单元或萘基单元的环氧树脂; （B）至少一种用作固化剂的酚醛树脂，其中所述酚醛树脂具有由不间断地直接键合的苯环形成的骨架，并且相对于总硬化剂为30〜100重量％ 和（C）固化催化剂。 所述不燃性树脂具有优异的阻燃性，良好的耐热性，并提高了成型性和可靠性。
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