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    Weatherable, thermostable polymers having improved flow composition
    1.
    发明授权
    Weatherable, thermostable polymers having improved flow composition 有权
    具有改善流动组成的耐候性耐热聚合物

    公开(公告)号：US07605221B2

    公开(公告)日：2009-10-20

    申请号：US11426680

    申请日：2006-06-27

    Applicant: Gary C. Davis ,  Brian D. Mullen ,  Paul D. Sybert

    Inventor： Gary C. Davis ,  Brian D. Mullen ,  Paul D. Sybert

    IPC: C08G77/14

    CPC classification number: C08G64/186 ,  C08G63/64 ,  C08G63/6956 ,  C08G77/448 ,  C08L69/00 ,  C08L83/10 ,  C08L2666/02

    Abstract: A copolymer composition comprises a polysiloxane block of Formula XIX or XXII, having 4 to 50 siloxane units, and a polyarylate-polycarbonate block consisting essentially of 50 to 99 mol % arylate polyester units and 1 to 50 mol % aromatic carbonate units, wherein 1 to 30 mole percent of the aromatic carbonate units are resorcinol carbonates, and 0 to 35 mol % of the aromatic carbonate units are bisphenol carbonates; wherein the sum of mole percentages of arylate polyester units, and aromatic carbonate units is 100 mol %; the polysiloxane blocks connect to an arylate ester unit, and/or an aromatic carbonate unit; the siloxane units of the polysiloxane block are present at 0.2 to 10 wt % based on weight of the copolymer composition; and a molded article of 3.2±0.12 millimeters thickness and consisting of the copolymer composition has a percent transmittance greater than or equal to 70%, according to ASTM D1003-00.

    Abstract translation: 共聚物组合物包含具有4至50个硅氧烷单元的式XIX或XXII的聚硅氧烷嵌段和基本上由50至99mol％芳基化聚酯单元和1至50mol％芳族碳酸酯单元组成的聚芳酯 - 聚碳酸酯嵌段，其中1至 30摩尔％的芳族碳酸酯单元是间苯二酚碳酸酯，0-35摩尔％的芳族碳酸酯单元是双酚碳酸酯; 其中芳基化聚酯单元和芳族碳酸酯单元的摩尔百分比之和为100摩尔％。 聚硅氧烷嵌段连接到芳基酯单元和/或芳族碳酸酯单元; 聚硅氧烷嵌段的硅氧烷单元以基于共聚物组合物的重量计为0.2-10重量％存在; 并且根据ASTM D1003-00，由共聚物组合物组成的3.2±0.12毫米厚的模制品具有百分比透射率大于或等于70％。

    Hydroxyarylestersiloxanes
    3.
    发明授权
    Hydroxyarylestersiloxanes 失效
    羟基芳基酯硅氧烷

    公开(公告)号：US5243009A

    公开(公告)日：1993-09-07

    申请号：US851704

    申请日：1992-03-16

    Applicant: Jonathan D. Rich ,  Philip J. McDermott ,  Gary C. Davis ,  Peter P. Policastro ,  Karen A. Regh ,  Pamela K. Hernandez ,  Thomas L. Guggenheim

    Inventor： Jonathan D. Rich ,  Philip J. McDermott ,  Gary C. Davis ,  Peter P. Policastro ,  Karen A. Regh ,  Pamela K. Hernandez ,  Thomas L. Guggenheim

    IPC: C08G64/18 ,  C08G77/448

    CPC classification number: C08G77/448 ,  C08G64/186

    Abstract: Silicone-polycarbonate block copolymers are provided resulting from the reaction of certain siloxy aromatic imide siloxanes or hydroxyaromatic ester siloxanes which are made by effecting reaction between an organosiloxane having terminal aromatic anhydride groups or aromatic haloacyl groups which are each attached to silicon by silicon arylene linkages with an appropriate bishydroxyarylene compounds or hydroxyarylene amino compound. The aforementioned hydroxyaromatic imide siloxanes or hydroxyaromatic ester siloxanes are then phosgenated with a dihydric phenol or an aromatic bischloroformate. The silicone-polycarbonate block copolymers have been found to be flame retardant and useful as dielectric films and membranes, and as flame retardants in aromatic polycarbonates.

    Abstract translation: 提供的硅氧烷 - 聚碳酸酯嵌段共聚物是由某些甲硅烷氧基芳族酰亚胺硅氧烷或羟基芳族酯硅氧烷的反应产生的，这些硅氧烷或羟基芳族酯硅氧烷是通过使具有末端芳族酸酐基团的有机硅氧烷或芳族卤代酰基与硅烷基链接在硅上的反应制得的， 合适的双羟基亚芳基化合物或羟基亚芳基氨基化合物。 然后将上述羟基芳族酰亚胺硅氧烷或羟基芳族酯硅氧烷用二元酚或芳族双氯甲酸酯进行光气化。 已经发现硅氧烷 - 聚碳酸酯嵌段共聚物是阻燃剂并且可用作介电膜和膜，并且作为芳族聚碳酸酯中的阻燃剂。

    POLYCARBONATE-POLY(ALKYLENE OXIDE) COPOLYMER COMPOSITIONS AND ARTICLES FORMED THEREFROM
    7.
    发明申请
    POLYCARBONATE-POLY(ALKYLENE OXIDE) COPOLYMER COMPOSITIONS AND ARTICLES FORMED THEREFROM 有权
    聚碳酸酯 - 聚（亚烷基氧化物）共聚物组合物及其形成的制品

    公开(公告)号：US20080312373A1

    公开(公告)日：2008-12-18

    申请号：US11763927

    申请日：2007-06-15

    Applicant: Gary C. Davis ,  Dibakar Dhara ,  Sarah Elizabeth Genovese ,  Katherine Glasgow ,  Jennifer Kubel ,  Gautam Madan ,  Patrick J. McCloskey ,  William D. Richards

    Inventor： Gary C. Davis ,  Dibakar Dhara ,  Sarah Elizabeth Genovese ,  Katherine Glasgow ,  Jennifer Kubel ,  Gautam Madan ,  Patrick J. McCloskey ,  William D. Richards

    IPC: C08G64/04 ,  C08G63/02 ,  C08G75/20

    CPC classification number: C08G64/183 ,  C08G65/40 ,  C08G2650/58 ,  C08L71/02 ,  C08L2205/05

    Abstract: Disclosed herein is a polycarbonate copolymer comprising A) a structure derived from a dihydroxy alkylene oxide compound selected from the group consisting of formula (1a) and formula (1b): H-(E-X)l—OH   (1a) H-(E-X-E)l-OH   (1b) wherein E and X are different and each and independently are selected from the group consisting of formula (2a) and formula (2b): —(OCH2CH2)m—   (2a) —(OCHRCH2)n—   (2b) wherein R is a C1-8 alkyl group; l, m, and n are integers greater than or equal to 1; and wherein the weight average molecular weight of the total amount of the structures corresponding to formula (2b) in the copolymer is between 100 and 2,000 g/mol; and B) a structure derived from a dihydroxy aromatic compound, wherein the weight percentages are based on the total weight of the structures of A) and B).

    Abstract translation: 本文公开了一种聚碳酸酯共聚物，其包含A）衍生自选自式（1a）和式（1b）的二羟基氧化烯化合物的结构：<？在线式描述=“在线配方”末端 =“lead”→H（EX）1-OH（1a）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In 线型公式“end =”lead“？> H-（EXE）1-OH（1b）<？in-line-formula description =”In-line Formulas“end =”tail“？>其中E和X不同 并且各自独立地选自式（2a）和式（2b）：<？in-line-formula description =“In-line formula”end =“lead”→>（OCH 2 CH 2）m-（ 2a）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line formula”end =“lead”？> - （OCHRCH2） n-（2b）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R是C1-8烷基; l，m和n是大于或等于1的整数; 并且其中共聚物中对应于式（2b）的结构的总量的重均分子量为100至2,000g / mol; 和B）衍生自二羟基芳族化合物的结构，其中所述重量百分比基于A）和B）的结构的总重量。

    Method for preparation of block copolysiloxanecarbonates
    8.
    发明授权
    Method for preparation of block copolysiloxanecarbonates 失效
    嵌段共聚硅氧烷碳酸酯的制备方法

    公开(公告)号：US5504177A

    公开(公告)日：1996-04-02

    申请号：US397456

    申请日：1995-03-02

    Applicant: Joseph A. King, Jr. ,  Patrick J. McCloskey ,  Gary C. Davis

    Inventor： Joseph A. King, Jr. ,  Patrick J. McCloskey ,  Gary C. Davis

    IPC: C08G64/32 ,  C08G64/00 ,  C08G64/18 ,  C08G64/30 ,  C08G77/42 ,  C08G77/448 ,  C08G77/08

    CPC classification number: C08G64/186 ,  C08G77/448

    Abstract: Copolysiloxanecarbonates are prepared in the melt by the reaction of a diaryl carbonate such as diphenyl carbonate with a mixture of a dihydroxyaromatic compound and a carbonate-terminated polydiorganosiloxane, the latter typically prepared by reaction of a diaryl carbonate or aryl chloroformate with a hydroxyorgano-terminated polydiorganosiloxane. By this method, incorporation of silicone units in the copolysiloxanecarbonate is maximized.

    Abstract translation: 通过碳酸二芳基酯与二羟基芳族化合物和碳酸酯封端的聚二有机硅氧烷的混合物的反应在熔融物中制备共聚硅氧烷碳酸酯，后者通常通过碳酸二芳基酯或氯甲酸芳基酯与羟基有机基封端的聚二有机硅氧烷 。 通过这种方法，将聚硅氧烷碳酸酯中的硅氧烷单元的引入最大化。

    Contrast enhancement layer compositions, alkylnitrones, and use
    10.
    发明授权
    Contrast enhancement layer compositions, alkylnitrones, and use 失效
    对比增强层组合物，烷基硝基酮和使用

    公开(公告)号：US5106723A

    公开(公告)日：1992-04-21

    申请号：US638694

    申请日：1991-01-08

    Applicant: Paul R. West ,  Gary C. Davis ,  Karen A. Regh

    Inventor： Paul R. West ,  Gary C. Davis ,  Karen A. Regh

    IPC: G03F7/09

    CPC classification number: G03F7/091 ,  Y10S430/129

    Abstract: Contrast enhancement compositions are provided which can be used to make contrast enhancement layer photoresist composites. The composites can be used to make patterned photoresists under mid-UV light and utilize photobleachable alkylnitrones.

    Abstract translation: 提供对比增强组合物，其可用于制造对比增强层光致抗蚀剂复合材料。 该复合材料可用于在UV光照射下制造图案化的光致抗蚀剂，并利用可光漂白的烷基硝基。

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