NON-INVASIVE ANALYTE SENSING SYSTEM AND METHOD
    1.
    发明申请
    NON-INVASIVE ANALYTE SENSING SYSTEM AND METHOD 有权
    非入侵分析仪感测系统及方法

    公开(公告)号:US20130281806A1

    公开(公告)日:2013-10-24

    申请号:US13823903

    申请日:2011-09-30

    IPC分类号: A61B5/1455

    摘要: A non-invasive gas analyte sensing and monitoring system and method is provided that is particularly applicable to transcutaneous monitoring of arterial blood gases in a mammal. The system and method relies on diffusion of the analyte to be measured into a diffusion chamber and remote sensing of the analyte in the diffusion chamber using optical chemical sensors and associated optoelectronics.

    摘要翻译: 提供一种非侵入性气体分析物感测和监测系统和方法,其特别适用于哺乳动物的动脉血气的经皮监测。 该系统和方法依赖于待测量分析物扩散到扩散室中,并使用光学化学传感器和相关联的光电子学来远程检测扩散室中的分析物。

    Hydrogenation of oxo aldehydes to oxo alcohols in the presence of a nickel-molybdenum catalyst
    4.
    发明申请
    Hydrogenation of oxo aldehydes to oxo alcohols in the presence of a nickel-molybdenum catalyst 失效
    在镍 - 钼催化剂存在下,将羰基醛氢化成羰基合成醇

    公开(公告)号:US20050065384A1

    公开(公告)日:2005-03-24

    申请号:US10938252

    申请日:2004-09-10

    IPC分类号: C07C29/141 C07C29/14

    CPC分类号: C07C29/141 C07C31/125

    摘要: A reduced or partially reduced nickel-molybdenum catalyst prepared by a process having the steps of 1) reacting nickel carbonate and molybdenum oxide precursors to form nickel molybdate and 2) treating the nickel molybdate under reducing conditions to form the reduced or partially reduced nickel-molybdenum catalyst. There is also a process for making the catalyst. There is also a process for using the catalyst in the hydrogenation of an oxo aldehyde, thereby forming an oxo alcohol of high selectivity. There is also a process for forming an oxo alcohol from the hydroformylation/hydrogenation of an olefinic feedstream. There is also a process for forming an oxo alcohol by contacting formates, dimers, trimers, and organic acids with hydrogen in the presence of a reduced or partially reduced nickel-molybdenum catalyst. The foregoing processes are also useful with a catalyst having the general formula YxZ wherein Y is nickel and/or cobalt and Z is molybdenum and/or tungsten; and wherein x ranges between about 0.25 to about 4.0. There are also reduced or partially reduced catalysts of the general formula NixMo or YxZ wherein x ranges between about 0.25 to about 4.0 and wherein oxide precursors of the catalysts are substantially free of ammonium groups.

    摘要翻译: 通过具有以下步骤的方法制备的还原或部分还原的镍 - 钼催化剂:具有以下步骤:1)使碳酸镍和氧化钼前体反应形成钼酸镍,和2)在还原条件下处理钼酸镍以形成还原或部分还原的镍 - 钼 催化剂。 还有一种制备催化剂的方法。 还有一种使用催化剂加氢羰基醛的方法,从而形成高选择性的羰基合成醇。 还有从烯烃进料流的加氢甲酰化/氢化形成羰基合成醇的方法。 还有一种通过在还原或部分还原的镍 - 钼催化剂存在下使甲酸盐,二聚体,三聚体和有机酸与氢接触来形成羰基合成醇的方法。 上述方法对于具有通式Y x Z的催化剂也是有用的,其中Y是镍和/或钴,Z是钼和/或钨; 并且其中x在约0.25至约4.0之间。 还有还原或部分还原的通式为NixMo或YxZ的催化剂,其中x为约0.25至约4.0,并且其中催化剂的氧化物前体基本上不含铵基团。