Process for the preparation of aryl-1,1,2,2-tetrafluoroethyl ethers
    2.
    发明授权
    Process for the preparation of aryl-1,1,2,2-tetrafluoroethyl ethers 失效
    芳基-1,1,2,2-四氟乙醚的制备方法

    公开(公告)号:US3926989A

    公开(公告)日:1975-12-16

    申请号:US15260071

    申请日:1971-06-14

    Applicant: HOECHST AG

    CPC classification number: C07C47/575 C07C45/71

    Abstract: Phenols react with tetrafluoroethylene at normal or reduced pressure when using about 0.05 to about 0.5 mole of an alkali metal hydroxide per each equivalent of phenolic hydroxy group as a catalyst and a water-miscible polar inert solvent to yield aryl-1,1,2,2-tetrafluoroethyl ethers. The products are useful as intermediates in the synthesis of dyestuffs and plant-protecting agents.

    Abstract translation: 当每当量酚羟基作为催化剂和与水混合的极性惰性溶剂使用约0.05至约0.5摩尔碱金属氢氧化物时,苯酚在正常或减压下与四氟乙烯反应,得到芳基-1,1,2, 2-四氟乙醚。 该产品可用作合成染料和植物保护剂的中间体。

    Process for the manufacture of stabilized polytetrafluoroethylene dispersions
    3.
    发明授权
    Process for the manufacture of stabilized polytetrafluoroethylene dispersions 失效
    制备稳定的聚偏氟乙烯分散体的方法

    公开(公告)号:US3707519A

    公开(公告)日:1972-12-26

    申请号:US3707519D

    申请日:1971-02-08

    Applicant: HOECHST AG

    Inventor: HAHN HELMUT

    CPC classification number: C08F14/26 C08F2/16

    Abstract: THE PRESENT INVENTION RELATES TO AQUEOUS DISPERSIONS OF POLYTETRAFLUOROETHYLENE WHICH ARE STABILIZED BY MEANS OF TERPENE HYDROCARBONS. THE STABILIZED DISPERSIONS ARE OBTAINED BY POLYMERIZING TETRAFLUOROETHYLENE IN THE PRESENCE OF 2 TO 25 P.P.M., CALCULATED ON THE TOTAL REACTION MIXTURE, OF TERPENE HYDROCARBONS. THE DISPERSIONS MAY CONTAIN UP TO 25% BY WEIGHT OF COLLOIDAL POLYTETRAFLUOROETHYLENE.

    Fluorinated polymers having bisurethano side chains
    4.
    发明授权
    Fluorinated polymers having bisurethano side chains 失效
    具有双硫腙侧链的氟化聚合物

    公开(公告)号:US3681426A

    公开(公告)日:1972-08-01

    申请号:US3681426D

    申请日:1969-08-15

    Applicant: HOECHST AG

    CPC classification number: C08G18/8087 C08G18/6212 D06M15/576

    Abstract: Polymers of the formula

    IN WHICH Rf is perfluoroalkyl of six to 12 carbon atoms, n is an integer of 1 to 4, m is 0 or 1 and x is a number of about 10 to about 300, are useful as water- and oil-repellent agents for fibrous materials, especially materials consisting of or containing cotton or wool. The agents are used in aqueous dispersions or solutions in organic solvents.

    Abstract translation: 其中R f为6至12个碳原子的全氟烷基,n为1至4的整数,m为0或1,x为约10至约300的数,可用作水和油 - 用于纤维材料的排斥剂,特别是由棉或羊毛组成或含有的材料。 这些试剂用于有机溶剂中的水性分散体或溶液中。

    Process for the preparation of trifluoroacetyl fluoride
    6.
    发明授权
    Process for the preparation of trifluoroacetyl fluoride 失效
    制备三氟甲基氟化物的方法

    公开(公告)号:US3689545A

    公开(公告)日:1972-09-05

    申请号:US3689545D

    申请日:1969-02-17

    Applicant: HOECHST AG

    CPC classification number: C07C51/58 C07C53/48

    Abstract: Trifluoroacetyl fluoride is prepared by pyrolyzing the reaction products of tetrafluoroethane and sulfur trioxide, namely 3,3,4,4-tetrafluoro-2,2-dioxo-1,2-oxathietane, 4,4,5,5tetrafluoro-2-oxo-1,3,2-dioxathiolane and 2-sulfofluoridodifluoroacetyl fluoride, in the presence of aluminum oxide or charcoal, as catalyst at a temperature of 50* to 240* C. The sulfur dioxide set free as a byproduct can be recycled after reoxidation to sulfur trioxide.

    Abstract translation: 通过热解四氟乙烷和三氧化硫的反应产物即3,3,4,4-四氟-2,2-二氧代-1,2-氧硫杂环己烷,4,4,5,5-四氟-2- 氧化-1,3,2-二氧硫杂环戊烷和2-磺基氟 - 二氟乙酰氟在氧化铝或木炭的存在下,作为催化剂,在50至240℃的温度下。作为副产物游离的二氧化硫可以循环使用 再氧化成三氧化硫后。

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