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公开(公告)号：US3629196A
公开(公告)日：1971-12-21
申请号：US3629196D
申请日：1969-08-21
Applicant: HOECHST AG
Inventor： HAHN HELMUT , REBSDAT SIEGFRIED , RUCHLAK KASIMIR , SCHUIERER ERICH
IPC: C08G77/26 , D06M15/657 , C08F11/04
CPC classification number: C08G77/26 , D06M15/657
Abstract: POLYCONDENSATES OF THE FORMULA
-(SI(-R)(-(CH2)3-OOC-NH-((CH3-)PHENYLENE)-NH-COO-(CH2)N-
RF)-O)Z-
IN WHICH R1 IS PERFLUOROALKYL OF 6 TO 12 CARBON ATOMS, R IS A GROUP OF THE FORMULA -O- OR LOWER ALKYL, N IS AN INTEGER OF 1 TO 4 AND Z IS A NUMBER OF FROM ABOUT 10 TO ABOUT 100, ARE USEFUL AS OLEO- AND HYDROPHOBIC AGENTS FOR TEXTILE MATERIALS, ESPECIALLY FOR WOOL AND COTTON.-
公开(公告)号：US3926989A
公开(公告)日：1975-12-16
申请号：US15260071
申请日：1971-06-14
Applicant: HOECHST AG
Inventor： REBSDAT SIEGFRIED , HAHN HELMUT
IPC: C07C45/71 , C07C47/575 , C07C41/06
CPC classification number: C07C47/575 , C07C45/71
Abstract: Phenols react with tetrafluoroethylene at normal or reduced pressure when using about 0.05 to about 0.5 mole of an alkali metal hydroxide per each equivalent of phenolic hydroxy group as a catalyst and a water-miscible polar inert solvent to yield aryl-1,1,2,2-tetrafluoroethyl ethers. The products are useful as intermediates in the synthesis of dyestuffs and plant-protecting agents.
Abstract translation: 当每当量酚羟基作为催化剂和与水混合的极性惰性溶剂使用约0.05至约0.5摩尔碱金属氢氧化物时，苯酚在正常或减压下与四氟乙烯反应，得到芳基-1,1,2， 2-四氟乙醚。 该产品可用作合成染料和植物保护剂的中间体。
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3.发明授权
公开(公告)号：US3707519A
公开(公告)日：1972-12-26
申请号：US3707519D
申请日：1971-02-08
Applicant: HOECHST AG
Inventor： HAHN HELMUT
Abstract: THE PRESENT INVENTION RELATES TO AQUEOUS DISPERSIONS OF POLYTETRAFLUOROETHYLENE WHICH ARE STABILIZED BY MEANS OF TERPENE HYDROCARBONS. THE STABILIZED DISPERSIONS ARE OBTAINED BY POLYMERIZING TETRAFLUOROETHYLENE IN THE PRESENCE OF 2 TO 25 P.P.M., CALCULATED ON THE TOTAL REACTION MIXTURE, OF TERPENE HYDROCARBONS. THE DISPERSIONS MAY CONTAIN UP TO 25% BY WEIGHT OF COLLOIDAL POLYTETRAFLUOROETHYLENE.
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公开(公告)号：US3681426A
公开(公告)日：1972-08-01
申请号：US3681426D
申请日：1969-08-15
Applicant: HOECHST AG
Inventor： HAHN HELMUT , REBSDAT SIEGFRIED , RUCHLAK KASIMIR , SCHUIERER ERICH
IPC: C08G18/62 , C08G18/80 , D06M15/576 , C07C125/06
CPC classification number: C08G18/8087 , C08G18/6212 , D06M15/576
Abstract: Polymers of the formula
IN WHICH Rf is perfluoroalkyl of six to 12 carbon atoms, n is an integer of 1 to 4, m is 0 or 1 and x is a number of about 10 to about 300, are useful as water- and oil-repellent agents for fibrous materials, especially materials consisting of or containing cotton or wool. The agents are used in aqueous dispersions or solutions in organic solvents.Abstract translation: 其中R f为6至12个碳原子的全氟烷基，n为1至4的整数，m为0或1，x为约10至约300的数，可用作水和油 - 用于纤维材料的排斥剂，特别是由棉或羊毛组成或含有的材料。 这些试剂用于有机溶剂中的水性分散体或溶液中。
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Patent Agency Ranking
公开(公告)号：US3654210A
公开(公告)日：1972-04-04
申请号：US3654210D
申请日：1969-07-28
Applicant: HOECHST AG
Inventor： KUHLS JURGEN , HAHN HELMUT , STEININGER ALFRED
IPC: C08F2/22 , C08F259/08 , C08F45/24
CPC classification number: C08F259/08 , Y10T428/2982 , C08F214/26
Abstract: THE PRESENT INVENTION RELATES TO AQUEOUS DISPERSIONS OF POLYMERS ON THE BASIS OF POLYTETRAFLUOROETHYLENE. THE POLYMERIC PARTICLES HAVE AN AVERAGE DIAMETER OF 0.2 TO 0.5U AND CONSIST OF A CORE MADE FROM 90-99% BY WEIGHT OF TETRAFLUROETHYLENE AND 1-10% BY WEIGHT OF CERTAIN HALOGEN CONTAINING COMONOMERS AND A SHELL OF TETRAFLUOROETHYLENE HOMOPOLYMER. THIS POLYMERIC MATERIAL HAS IMPROVED PROPERTIES FOR PASTE EXTRUSION PROCESSES.
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公开(公告)号：US3689545A
公开(公告)日：1972-09-05
申请号：US3689545D
申请日：1969-02-17
Applicant: HOECHST AG
Inventor： HAHN HELMUT , REBSDAT SIEGFRIED
IPC: C07C51/58
Abstract: Trifluoroacetyl fluoride is prepared by pyrolyzing the reaction products of tetrafluoroethane and sulfur trioxide, namely 3,3,4,4-tetrafluoro-2,2-dioxo-1,2-oxathietane, 4,4,5,5tetrafluoro-2-oxo-1,3,2-dioxathiolane and 2-sulfofluoridodifluoroacetyl fluoride, in the presence of aluminum oxide or charcoal, as catalyst at a temperature of 50* to 240* C. The sulfur dioxide set free as a byproduct can be recycled after reoxidation to sulfur trioxide.
Abstract translation: 通过热解四氟乙烷和三氧化硫的反应产物即3,3,4,4-四氟-2,2-二氧代-1,2-氧硫杂环己烷，4,4,5,5-四氟-2- 氧化-1,3,2-二氧硫杂环戊烷和2-磺基氟 - 二氟乙酰氟在氧化铝或木炭的存在下，作为催化剂，在50至240℃的温度下。作为副产物游离的二氧化硫可以循环使用 再氧化成三氧化硫后。
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7.发明授权Fluorine containing poly-n-vinyl carboxylic acid amides,processes for their preparation and their use as textile finishing agents 失效含有聚-N-乙酰羧酸的氟化物，其制备方法及其作为纺织成品代理
公开(公告)号：US3586643A
公开(公告)日：1971-06-22
申请号：US3586643D
申请日：1969-06-25
Applicant: HOECHST AG
Inventor： HAHN HELMUT , MULLER KLAUS-DIETER , REBSDAT SIEGFRIED , SCHUIERER ERICH
IPC: C09K3/18 , C08F26/00 , C08F26/02 , C08G61/00 , D06M15/21 , D06M15/277 , F27B21/06 , G07B13/04 , C08G33/02
Abstract: POLYMERS CONTAINING RECURRING UNITS OF THE FORMULA
-CH(-NH-CO-C(-X)(-Y)-RF)-CH2-
IN WHICH RF IS PERFLUOROALKYL OF 3 TO 10 CARBON ATOMS, AND X AND Y ARE FLUORINE AND/OR HYDROGEN, ARE USEFUL AS AGENTS FOR RENDERING FIBROUS MATERIALS WATER AND OIL REPELLANT. THE LOWER OLIGOMERS ARE SOLUBLE IN LOW VOLATILE FLUORINATED HYDROCARBONS. THE POLYMERS ARE SOLUBLE IN ACETONE AND CAPABLE OF FORMING AQUEOUS DISPERSIONS.-
8.发明授权Process for the preparation of 2-(1'-h-halogenoalkyl)-delta**2-oxazolines 失效制备2-（1'-H-卤代甲基） - 乙醇胺的方法** 2-氧杂环丁烷
公开(公告)号：US3564004A
公开(公告)日：1971-02-16
申请号：US3564004D
申请日：1969-06-30
Applicant: HOECHST AG
Inventor： SCHERER OTTO , SODEN BAD , HAHN HELMUT , HARTWIMMER ROBERT , REBSDAT SIEGFRIED , SCHUIERER ERICH
IPC: C07D263/10 , C07D85/36
CPC classification number: C07D263/10
Abstract: 2-(1''-H-HALOGENOALKYL)-$2-OXAZOLINES ARE OBTAINED BY REACTING 1,1-DIFLUOROETHYLENES WITH ETHANOLAMINE. THE PRODUCTS ARE USEFUL AS MONOMERS OR COMONOMERS FOR THE PREPARATION OF POLY-N-VINYL CARBOXYLIC ACID AMIDES, CAPABLE OF RENDERING FIBROUS MATERIALS WATER- AND OILREPELLENT.
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公开(公告)号：US3427276A
公开(公告)日：1969-02-11
申请号：US3427276D
申请日：1966-11-07
Applicant: HOECHST AG
Inventor： HAHN HELMUT , BEERMANN CLAUS
CPC classification number: C08J3/09
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