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    Recording solution for vaporization type heat transfer recording
    1.
    发明授权
    Recording solution for vaporization type heat transfer recording 失效
    记录蒸发式热转印记录液

    公开(公告)号：US5989324A

    公开(公告)日：1999-11-23

    申请号：US951505

    申请日：1997-10-16

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Miyuki Kuromiya

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Miyuki Kuromiya

    IPC分类号： B41J2/01 ,  B41J2/32 ,  B41M5/26 ,  C09D11/00

    CPC分类号： C09D11/32 ,  C09D11/037

    摘要： The present invention provides a recording solution for vaporization type heat transfer recording which produces no precipitate in a recording operation and thus no problem of burning in a vaporization portion.The recording solution for vaporization type heat transfer recording in which the recording solution is vaporized to be transferred to a recording material contains a dye, a solvent having a melting point of 0.degree. C. or less, and a compatibilier for increasing the solubility of the dye in the solvent. Particularly, when the temperature at which the weight loss by vaporization is 10% in thermogravimetric analysis at a rate of temperature rise of 20 C./min., is defined as the vaporization start temperature, the different between the vaporization start temperatures of any desired two of the dye, the solvent and the compatibilizer is set to 100.degree. C. or less.

    摘要翻译： 本发明提供一种用于蒸发型热转印记录的记录溶液，其在记录操作中不产生沉淀物，因此不会在蒸发部分中产生燃烧问题。 记录液蒸发转移到记录材料中的蒸发型传热记录记录液含有染料，熔点为0℃以下的溶剂和增溶剂的溶解度的增容剂 在溶剂中染色。 特别是，当以20℃/分钟的升温速率将热蒸发重量减少10％的温度定义为蒸发开始温度时，任何所需的蒸发开始温度之间的差异 将两种染料，溶剂和增容剂设定为100℃以下。

    Recording method and recording solution
    3.
    发明授权
    Recording method and recording solution 失效
    记录方法和记录方案

    公开(公告)号：US5781210A

    公开(公告)日：1998-07-14

    申请号：US602384

    申请日：1996-02-16

    申请人： Hideki Hirano ,  Hiroyuki Shiota ,  Shuji Sato ,  Kenji Shinozaki

    发明人： Hideki Hirano ,  Hiroyuki Shiota ,  Shuji Sato ,  Kenji Shinozaki

    IPC分类号： B41J2/01 ,  B41J2/015 ,  B41J2/14 ,  B41J2/32 ,  B41J2/475 ,  B41J2/48 ,  B41M5/382 ,  C09D11/00 ,  C09D11/328

    CPC分类号： C09D11/36 ,  B41J2/14104 ,  B41M5/0023

    摘要： A recording method of ink jet system which employs a recording solution composed of a dye which vaporizes more than 90 wt % upon heating at a temperature above 300.degree. C., leaving residues in an amount less than 10 wt %, and a solvent having a boiling point higher than 150.degree. C. which dissolves or disperses the dye more than 5 wt % at a temperature below 50.degree. C., the recording solution being heated at the time of recording by the recording solution heating unit which has a porous structure formed thereon which is composed of fine parts whose dimension in the plane direction is 0.2-3 .mu.m and whose dimension in the direction perpendicular to the plane direction is 2-15 .mu.m. This recording method makes use of the advantage of both the thermal transfer system and the ink jet system. Thus, it realizes a high resolution and a gradation within a picture element, produces high-quality images promptly, permits the printer to be made small and light, involves no waste materials, permits printing on plain paper, and needs a less amount of power and running cost.

    摘要翻译： 一种喷墨系统的记录方法，其采用由在高于300℃的温度下加热而蒸发大于90重量％的染料组成的记录溶液，留下少于10重量％的残留物和具有 沸点高于150℃，在低于50℃的温度下溶解或分散染料超过5重量％，记录溶液在记录溶液加热单元被记录时加热，该记录溶液加热单元形成有多孔结构 由平面方向尺寸为0.2-3μm，垂直于平面方向的尺寸为2-15μm的细小部分构成。 该记录方法利用了热转印系统和喷墨系统的优点。 因此，它实现了图像元素内的高分辨率和渐变，迅速产生高质量的图像，使打印机变得小而轻，不涉及废料，允许在普通纸上打印，并且需要较少的功率 并运行成本。

    Thermal transfer recording material and thermal transfer recording method using same
    6.
    发明授权
    Thermal transfer recording material and thermal transfer recording method using same 失效
    热转印记录材料和热转印记录方法使用相同

    公开(公告)号：US5935901A

    公开(公告)日：1999-08-10

    申请号：US614135

    申请日：1996-03-11

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida ,  Miyuki Kuromiya

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida ,  Miyuki Kuromiya

    IPC分类号： B41M5/035 ,  B41M5/382 ,  B41M5/385 ,  B41M5/38

    CPC分类号： B41M5/38207 ,  B41M5/3852 ,  Y10S428/913 ,  Y10S428/914

    摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation by heating, and then transferred to a recording medium disposed in an opposed relation to the transfer section, comprising:a dye represented by the general formula (I): ##STR1## where R.sup.1 and R.sup.2 are individually a substituted or unsubstituted alkyl or alkenyl group, or a cycloalkyl group, and when both R.sup.1 and R.sup.2 are unsubstituted alkyl groups, at least one of R.sup.1 and R.sup.2 is a branched alkyl group.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，通过加热进行状态变换，然后转印到设置的记录介质上 与所述转移部分相对，包括：由通式（I）表示的染料：其中R 1和R 2各自为取代或未取代的烷基或烯基或环烷基，并且当R 1和R 2均未被取代时 烷基，R 1和R 2中的至少一个是支链烷基。

    Recording device
    7.
    发明授权
    Recording device 失效
    录音设备

    公开(公告)号：US5847732A

    公开(公告)日：1998-12-08

    申请号：US524571

    申请日：1995-09-07

    申请人： Kenji Shinozaki ,  Hideki Hirano

    发明人： Kenji Shinozaki ,  Hideki Hirano

    IPC分类号： B41J2/01 ,  B41J2/005 ,  B41J2/32 ,  B41M5/26 ,  B41M5/382 ,  B41M5/46

    CPC分类号： B41J2/005

    摘要： During the recording where a liquid dye 22 supplied through a dye passage 27 is supplied to a vaporizing means 17 due to the capillarity of many small columns 21 within a vessel formed by coupling of a glass base 14 and a Teflon protection plate 290, the liquid dye in the vaporizing means is vaporized by irradiation of the laser beam L and the vaporized dye is transmitted to a photographic paper 50 passing a vaporization hole (aperture) 23 for the purpose of recording. The protection plate 290 has a critical surface tension against the liquid dye which is smaller than a surface tension of the liquid dye. Since the critical surface tension of the protection plate 290 is set smaller than a surface tension of the liquid dye, wettability of the liquid dye against the internal wall surface of the vaporizing hole 23 is low and the liquid dye left unvaporized at the vaporizing hole 17 at the time of recording is never deposited on the internal wall surface of the vaporizing hole. Therefore, the vaporizing hole is always kept clear, transfer of the vaporized dye 32 to the photographic paper is never prevented due to deposition of dye to the vapotizing hole and thereby excellent recording quality can always be guaranteed.

    摘要翻译： 在通过染料通道27供应的液体染料22由于通过玻璃基底14和特氟龙保护板290的联接而形成的容器内的许多小柱21的毛细管力而被供应到蒸发装置17的记录期间，液体 蒸发装置中的染料通过照射激光束L而蒸发，并且蒸发的染料被传送到通过蒸发孔（孔）23的照相纸50以进行记录。 保护板290对液体染料具有小于液体染料的表面张力的临界表面张力。 由于保护板290的临界表面张力小于液体染料的表面张力，所以液体染料相对于蒸发孔23的内壁表面的润湿性低，并且液体染料在蒸发孔17处未蒸发 在记录时不会沉积在蒸发孔的内壁表面上。 因此，蒸发孔始终保持清晰，由于染料沉积到蒸发孔中，蒸发的染料32不能防止转印到相纸上，从而可以始终保证良好的记录质量。

    Thermal transfer recording material and thermal transfer recording method using same
    8.
    发明授权
    Thermal transfer recording material and thermal transfer recording method using same 失效
    热转印记录材料和热转印记录方法使用相同

    公开(公告)号：US5618337A

    公开(公告)日：1997-04-08

    申请号：US614136

    申请日：1996-03-11

    申请人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    发明人： Kenji Shinozaki ,  Hideki Hirano ,  Yukichi Murata ,  Mio Ishida

    IPC分类号： B41M5/385 ,  B41J2/05 ,  B41M5/388 ,  B41M5/39 ,  C09D11/02

    CPC分类号： B41M5/3854

    摘要： A thermal transfer recording material for use in a recording apparatus in which the thermal transfer recording material is introduced into a transfer section having a porous structure by an effect of capillarity, subjected to a state transformation such as vaporization or droplet formation by heating, and then transferred to a recording medium disposed opposed to the transfer section, comprising:a dye having a melting point of 115.degree. C. or lower and represented by the general formula (I): ##STR1## where A is a substituted or unsubstituted p-phenylene group, R.sup.1 and R.sup.2 are individually a hydrogen atom, a substituted or unsubstituted alkyl or alkenyl group, a cycloalkyl group or a substituted or unsubstituted phenyl group; and R.sup.1 may constitute a heterocyclic group composed of a five- or six-member ring in combination with said p-phenylene group A and a nitrogen atom adjacent to the p-phenytene group A, or another heterocyclic group composed of a five- or six-member ring in combination with R.sup.2 and the nitrogen atom adjacent to the p-phenylene group A.

    摘要翻译： 一种用于记录装置的热转印记录材料，其中将热转印记录材料通过毛细管作用引入到具有多孔结构的转印部分中，经受诸如通过加热蒸发或液滴形成的状态转变，然后 转移到与转印部分相对设置的记录介质中，包括：熔点为115℃或更低并由通式（I）表示的染料：其中A是取代或未取代的 对亚苯基，R1和R2分别为氢原子，取代或未取代的烷基或链烯基，环烷基或取代或未取代的苯基; 并且R 1可以构成由与所述对亚苯基A和毗邻对苯基A相邻的氮原子组合的五元或六元环的杂环基或由五或六元组成的另一杂环基 - 与R2和与对亚苯基A相邻的氮原子的组合环。

    Method for regenerating a thermosensitive transfer recording medium and thermosensitive transfer recording apparatus
    10.
    发明授权
    Method for regenerating a thermosensitive transfer recording medium and thermosensitive transfer recording apparatus 失效
    热敏转印记录介质的再生方法和热敏转印记录装置

    公开(公告)号：US5371059A

    公开(公告)日：1994-12-06

    申请号：US100996

    申请日：1993-08-03

    申请人： Hideki Hirano ,  Kenji Shinozaki ,  Mari Seki

    发明人： Hideki Hirano ,  Kenji Shinozaki ,  Mari Seki

    IPC分类号： B41J31/00 ,  B41F31/16 ,  B41J31/16 ,  B41M5/382 ,  B41M5/035 ,  B41M5/38

    CPC分类号： B41M5/38207 ,  B41J31/16 ,  Y10S428/913 ,  Y10S428/914

    摘要： A method and apparatus for regenerating a thermosensitive transfer recording medium 1 comprising a dye layer having a thermally diffusable dye at a concentration, wherein the medium 1 is superposed on a material 10 to be transferred and heated in an imagewise pattern to transfer the dye of the medium 1 to the material 10 to be transferred thereby forming an image. The apparatus comprises a dye supplier 4 containing a thermally diffusable dye at a concentration higher than that of the dye layer, and a heating means 7 for diffusing the dye from the supplier 4 toward the dye layer whereby the dye consumed during the transfer recording operations is supplemented from the supplier 4 to the dye layer. A thermosensitive transfer recording apparatus is also described along with a thermosensitive transfer recording medium and a dye supplier.

    摘要翻译： 用于再生热敏转印记录介质1的方法和装置包括具有浓度为可热扩散染料的染料层，其中介质1以成像图案转印和加热的材料10重叠，以转印 介质1到要转印的材料10，从而形成图像。 该装置包括含有浓度高于染料层的热扩散性染料的染料供给体4，以及用于将染料从供给体4向染料层扩散的加热装置7，由此在转印记录操作期间消耗的染料为 从供应商4补充到染料层。 热敏转印记录装置还与热敏转印记录介质和染料供应器一起描述。