Method for preparing nitrate ester

    公开(公告)号:US10703707B2

    公开(公告)日:2020-07-07

    申请号:US16413322

    申请日:2019-05-15

    Abstract: A method for preparing a nitrate ester is provided. The method includes providing a first solution including a compound (which has at least one hydroxyl group) and a carboxylic acid having 2-5 carbon atoms; providing a second solution including nitric acid, acetic anhydride, and acetic acid; and transferring the first solution and the second solution to a microreactor, obtaining a nitrate ester after a residence time. In particular, the ratio of the weight of nitric acid to the total volume of the acetic anhydride and acetic acid is 1:1 to 1:3.5. The ratio of the molar amount of nitric acid to the hydroxyl group equivalent of the compound is from 1:1 to 15:1.

    Liquid crystal compound with negative dielectric anisotropy, liquid crystal display, and optoelectronic device
    9.
    发明授权
    Liquid crystal compound with negative dielectric anisotropy, liquid crystal display, and optoelectronic device 有权
    具有负介电各向异性的液晶化合物,液晶显示器和光电器件

    公开(公告)号:US09163178B2

    公开(公告)日:2015-10-20

    申请号:US14190709

    申请日:2014-02-26

    CPC classification number: C09K19/20 C09K19/3098 C09K2019/0466

    Abstract: Disclosed is a liquid crystal compound with negative dielectric anisotropy, having a general formula as Formula 1. In Formula 1, each of L1, L2, L3, and L4, being same or different, is hydrogen, halogen, or cyano group. Each of R1 and R2, being same or different, is hydrogen, halogen, C1-12 alkyl group, C1-12 alkoxy group, C1-12 haloalkyl group, C2-12 alkenyl group, C2-12 ether group, or C2-12 alkynyl group. Each of A1 and A2, being same or different, is benzene, cyclohexane, or cyclohexene.Z1 is —CF2O—, or —OCF2—, and Z2 is —CF2O—, or —OCF2—.

    Abstract translation: 公开了具有负介电各向异性的液晶化合物,具有通式为式1.在式1中,L1,L2,L3和L4各自相同或不同,为氢,卤素或氰基。 R1和R2各自相同或不同,为氢,卤素,C1-12烷基,C1-12烷氧基,C1-12卤代烷基,C2-12烯基,C2-12醚基或C2-12 炔基。 A1和A2各自相同或不同,为苯,环己烷或环己烯。 Z1是-CF2O-或-OCF2-,Z2是-CF2O-或-OCF2-。

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