公开(公告)号：US20210163653A1

公开(公告)日：2021-06-03

申请号：US17267906

申请日：2019-08-27

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Ulrich JANSEN ,  Gisbert MICHELS

IPC: C08F285/00 ,  C08F6/00 ,  C08L51/00 ,  C08L55/02 ,  C08F212/08 ,  C08F220/44 ,  C08F2/22

Abstract: The present invention is directed to a process for the production of graft copolymer compositions which are based on acrylonitrile-styrene-acrylate (ASA) or acrylonitrile- butadiene-styrene (ABS) graft copolymers. The graft copolymers compositions are obtained by emulsion polymerization and afterwards precipitation, dewatering, drying and optionally cooling of the dried graft copolymer powder, wherein the graft copolymer B powder obtained is mixed with an aeration gas, preferably air and/or nitrogen, wherein the bulk density of the graft copolymer B powder is equal or less than 98.5% of the bulk density of the non-aerated graft copolymer B, during the whole aeration step. The graft copolymer powders show higher powder flowability and less tendency of caking during storage, for example in a silo.

公开(公告)号：US20170362422A1

公开(公告)日：2017-12-21

申请号：US15536749

申请日：2015-12-15

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Eike JAHNKE ,  Ricardo Daniel FAJARDO

IPC: C08L25/14 ,  C08L25/12 ,  G02B5/02

CPC classification number: C08L25/14 ,  C08L25/12 ,  C08L2205/025 ,  G02B5/0242 ,  C08L33/12

Abstract: The invention relates to a styrene copolymer composition comprising a) 60 to 99.9% by weight of styrene-based polymer matrix component A, b) 0.1 to 5% by weight of PMMA-based, cross-linked polymer bead as light diffuser component B, wherein the polymer beads have an average particle diameter from 0.5 to 20 μηη and a refractive index ranging from 1.34 to 1.55, and c) 0 to 39.9% by weight of further component C, different to A and B, wherein the sum of components A) to C) is 100% by weight and the composition exhibits a light transmittance greater than 80%, a haze greater than 90% and a Yellowness Index less than 4.5.

公开(公告)号：US20210261740A1

公开(公告)日：2021-08-26

申请号：US17251324

申请日：2019-06-11

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Christian RUTHARD

IPC: C08J3/00 ,  C08J3/20 ,  C08L51/00 ,  C08L25/12 ,  C08L83/04 ,  C08L83/10 ,  C08F220/18 ,  C08K3/013 ,  C08K5/00

Abstract: The present invention relates to a method of improving UV resistance of a vinylaro-maticmolding mass by means of compounding a thermoplastic polymer composition which comprises at least one graft copolymer with an organopolysiloxane compound and optionally further components.

公开(公告)号：US20200255605A1

公开(公告)日：2020-08-13

申请号：US16648690

申请日：2018-09-26

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Philipp DEITMERG ,  Eike JAHNKE ,  Tobias SCHULZ ,  Pierre JUAN ,  Norbert NIESSNER ,  Marko BLINZLER

IPC: C08J5/04 ,  B29C51/12 ,  B29C51/42 ,  B29C51/44 ,  B29C70/46

Abstract: The invention relates to the use of a fibre-reinforced composite (K) in a thermoforming process. Moreover, a process for thermoforming a fibre-reinforced composite (K) to a molded body (M) is disclosed, the process comprising at least the following steps: (i) Providing a fibre-reinforced composite (K) as described herein; (ii) Heating the fibre-reinforced composite (K) to a temperature (T3) at which the at least one substantially amorphous matrix polymer composition (B) is substantially softened; (iii) Thermoforming the fibre-reinforced composition (K) in a mold at a mold surface temperature (T4) in order to obtain a molded body (M); (iv) Releasing the molded body (M) from the mold; wherein the mold surface temperature (T4) is ≥50° C.

公开(公告)号：US20200165432A1

公开(公告)日：2020-05-28

申请号：US16632920

申请日：2018-07-25

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Norbert NIESSNER ,  Andrew CHUNG ,  Richard JOHNSON

IPC: C08L25/12 ,  C08J3/20 ,  C08J3/00

Abstract: Thermoplastic polymer compositions (P) comprising at least one styrene-based polymer composition (A) comprising at least one graft copolymer (A-1), at least one organopolysiloxane compound, and optionally at least one colorant, dye or pigment, and/or at least one further additive show improved properties with respect to residual gloss after abrasion combined with improved melt flow characteristics while heat resistance is not affected.

公开(公告)号：US20200024437A1

公开(公告)日：2020-01-23

申请号：US16495133

申请日：2018-03-14

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ

IPC: C08L25/14 ,  C08L25/12 ,  B29C45/00

Abstract: The invention relates to polymer blends of a styrene copolymer A selected from the group consisting of styrene acrylonitrile copolymers (SAN), styrene acrylonitrile maleic anhydride terpolymers (SMA), styrene acrylic copolymers, acrylonitrile butadiene styrene terpolymers (ABS), acrylonitrile butadiene styrene terpolymers with polyamide (ABS/PA), and acrylonitrile styrene acrylate terpolymers (ASA); and at least one copolymer B selected from the group consisting of styrene-butadiene block copolymers (SBC) and styrene-isoprene block copolymers (SIS); wherein the mold shrinkage of the polymer blend is reduced by at least 5% compared to the mold shrinkage of the pure styrene copolymer A.A process for the preparation of the polymer blends and the uses of the polymer blends in an injection molding process are described.

公开(公告)号：US20190211128A1

公开(公告)日：2019-07-11

申请号：US16325440

申请日：2017-08-09

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Norbert NIESSNER ,  Tobias SCHULZ ,  Oliver CARSTENSEN ,  Konrad KNOLL ,  Manfred DOERING ,  Frank SCHOENBERGER ,  Julien FAGE

IPC: C08F265/04 ,  C08L25/12 ,  C08L25/14 ,  C08L51/00 ,  C08F220/18 ,  C08F2/22 ,  C08F8/14 ,  C08F2/38

CPC classification number: C08F265/04 ,  C08F2/22 ,  C08F2/38 ,  C08F8/14 ,  C08F212/145 ,  C08F220/18 ,  C08F220/28 ,  C08F265/06 ,  C08F2810/30 ,  C08F2810/50 ,  C08L25/12 ,  C08L25/14 ,  C08L51/003 ,  C08L2201/10 ,  C08F212/08 ,  C08L51/04 ,  C08F2220/1825 ,  C08F2220/325 ,  C08F2220/1808

Abstract: The invention relates to graft copolymers—based on non-cross-linked acrylate soft phases from which styrenic monomers are grafted—with a defined micro-structure, having a high transparency, toughness and weather resistance (UV-stability), a process for their preparation and their use, and also to polymer blends comprising said graft copolymers and styrenic polymers, and shaped articles produced therefrom and their use.

公开(公告)号：US20210292460A1

公开(公告)日：2021-09-23

申请号：US17262026

申请日：2019-07-22

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Norbert NIESSNER ,  Christian RUTHARD ,  Hannes KERSCHBAUMER

IPC: C08F257/02 ,  C08K5/00

Abstract: Thermoplastic molding composition comprising a graft copolymer B with core-shell structure having a particle diameter dw of 280 to 450 nm, comprising a core B1 and three layers B2 to B4: B1: 6 to 19 wt.-% of a core B1 comprising crosslinked polystyrene; B2: 41 to 54 wt.-% of a first layer B2 of a crosslinked acrylate polymer; B3: 1 to 19 wt.-% of a second layer B3 of polystyrene; and B4: 21 to 39 wt.-% of a third layer B4 consisting of SAN copolymer.

公开(公告)号：US20210292459A1

公开(公告)日：2021-09-23

申请号：US17262018

申请日：2019-07-22

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Wolfgang FISCHER ,  Norbert NIESSNER ,  Christian RUTHARD ,  Hannes KERSCHBAUMER

IPC: C08F257/02 ,  C08L33/20

Abstract: Polyacrylate graft rubber copolymer B and an impact modified thermoplastic molding composition thereof, where the graft copolymer B is composed of: B1: 50 to 70 wt.-% crosslinked acrylate polymer graft base B1 B2: 30 to 50 wt.-% graft shell B2 comprising a first layer B21 of vinylaromatic monomers, and a second layer B22 of vinylaromatic monomers B21-1 and nitrile monomers B22-2; wherein the particle diameter dw of the graft base B1 is 255 to 290 nm; the fraction of B21 is 10 to 26 wt.-%; and the amount of B22-2, is 20 to 30 wt.-%.

公开(公告)号：US20210147668A1

公开(公告)日：2021-05-20

申请号：US16627448

申请日：2018-07-03

Applicant: INEOS STYROLUTION GROUP GMBH

Inventor： Tobias SCHULZ ,  Felix RATTAY

IPC: C08L25/12 ,  C08L51/00 ,  C08F220/18 ,  C08K3/22 ,  C08K5/3432

Abstract: Thermoplastic styrene copolymer resin composition comprising: (a1) at least one styrene-acrylonitrile copolymer component A1, (a2) at least one acrylonitrile styrene acrylate graft copolymer A2 as impact modifier, (a3) optionally at least one thermoplastic polymer A3 other than components A1 and A2, (b) at least one transition metal oxide pigment B, (cl) at least one hindered amine UV light stabilizer C1, (c2) optionally at least one UV absorber C2 different from Cl, (d) optionally further polymer additives D, other than components B, C1, C2, and E, and (e) optionally one metal scavenger component E, wherein at least 99.0 wt.-% of the transition metal oxide pigment B consist of transition metal atoms and oxygen atoms.