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7 条记录 (耗时 0.021 秒)

    Process for producing polybutene-1
    1.
    发明授权
    Process for producing polybutene-1 失效
    生产聚丁烯-1的方法

    公开(公告)号：US4398006A

    公开(公告)日：1983-08-09

    申请号：US279803

    申请日：1981-07-02

    申请人： Kazumi Tsubaki ,  Noriaki Koto ,  Toyohiko Abe

    发明人： Kazumi Tsubaki ,  Noriaki Koto ,  Toyohiko Abe

    IPC分类号： C08F4/00 ,  C08F4/60 ,  C08F4/64 ,  C08F110/04 ,  C08F10/08

    CPC分类号： C08F10/00

    摘要： Butene-1 is polymerized in the presence of a catalytic system comprising a solid catalytic component (A), a trialkylaluminum compound (B), an organic acid ester (C), and an organoaluminum compound (D) at a molar ratio of (D) to (B) ranging 0.1 to 10 wherein said solid catalytic component (A) is obtained by reacting a reaction product (a) of a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3) with at least one compound having the formulaR.sub.n.sup.2 M(.sup.(z) X.sub.z-n(R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1-(z-1) to obtain a reaction product (b) and further reacting said reaction product (b) with at least one titanium halide in the presence of an organic acid ester.

    摘要翻译： 丁烯-1在包含固体催化组分（A），三烷基铝化合物（B），有机酸酯（C）和有机铝化合物（D））的催化体系存在下以（D ）至（B）的范围为0.1至10，其中所述固体催化组分（A）通过使格利雅试剂的反应产物（a）与具有单元的链或环状氢聚硅氧烷（R1表示烷基，芳基 芳基，芳烷基，烷氧基或芳氧基; a为0,1或2; b为1,2或3并且a + b = 3）与至少一种具有式Rn2M（（z）Xz-n 表示C1〜C12烃部分; M表示Al或Si; z表示原子值3或4; X表示卤素原子; n表示0，1-（z-1），得到反应产物（b） 在有机酸酯的存在下使所述反应产物（b）与至少一种卤化钛反应。

    Process for producing copolymer of ethylene
    2.
    发明授权
    Process for producing copolymer of ethylene 失效
    制备乙烯共聚物的方法

    公开(公告)号：US4424321A

    公开(公告)日：1984-01-03

    申请号：US326926

    申请日：1981-12-02

    申请人： Kazumi Tsubaki ,  Noriaki Koto ,  Toyohiko Abe

    发明人： Kazumi Tsubaki ,  Noriaki Koto ,  Toyohiko Abe

    IPC分类号： C08F4/00 ,  C08F2/18 ,  C08F4/42 ,  C08F4/58 ,  C08F4/60 ,  C08F4/64 ,  C08F210/00 ,  C08F210/02 ,  C08F210/16 ,  C08F4/02

    CPC分类号： C08F210/02 ,  Y10S526/903

    摘要： A copolymer of ethylene and a C.sub.4 -C.sub.10 .alpha.-olefin at a content of 0.5 to 10 mol % is produced by forming a polymerization catalyst system by reacting a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit R.sup.1.sub.a H.sub.b SiO.sub.(4-a-b/2) (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3), to form a reaction product (a); reacting the reaction product (a) with at least one compound having the formula R.sup.2.sub.n M.sup.(z) X.sub.z-n (R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1 . . . (z-1) in the presence of an aromatic hydrocarbon solvent at lower than 85.degree. C. to form a reaction product (b); and reacting the reaction product (b) with at least one titanium halide in the presence of an organic acid ester (c) to obtain a solid catalytic component (A) and adding an organoaluminum compound (B) and then, polymerizing ethylene and a C.sub.4 -C.sub.10 .alpha.-olefin in the presence of a catalytic amount of the polymerization catalyst system in an inert hydrocarbon solvent or in a liquid form of the C.sub.4 -C.sub.10 .alpha.-olefin in which ethylene is dissolved.

    摘要翻译： 通过使Grignard试剂与具有单元R1aHbSiO（4-ab / 2）的链或环状聚硅氧烷反应形成聚合催化剂体系，制备乙烯与C 5 -C 10α-烯烃的含量为0.5-10摩尔％的共聚物 ）（R1表示烷基，芳基，芳烷基，烷氧基或芳氧基; a为0,1或2; b为1,2或3，a + b为3），形成反应产物（a）。 使反应产物（a）与至少一种具有式R2nM（z）Xz-n的化合物（R2表示C1至C12烃部分; M表示Al或Si; z表示原子值3或4; X表示 卤素原子; n为0,1 ...（z-1），在芳族烃溶剂存在下，低于85℃，形成反应产物（b）;使反应产物（b）与 至少一种卤化钛在有机酸酯（c）的存在下得到固体催化组分（A）并加入有机铝化合物（B），然后在乙烯和C 4 -C 10α-烯烃的存在下聚合乙烯和C 4 -C 10α-烯烃 催化量的聚合催化剂体系在惰性烃溶剂中或其中溶解有乙烯的C 4 -C 10α-烯烃的液体形式。

    Process for producing powdery isotactic polyolefin
    3.
    发明授权
    Process for producing powdery isotactic polyolefin 失效
    制备粉状全同立构聚烯烃的方法

    公开(公告)号：US4258167A

    公开(公告)日：1981-03-24

    申请号：US6380

    申请日：1979-01-25

    申请人： Kazumi Tsubaki ,  Noriaki Koto ,  Kouichi Maeda

    发明人： Kazumi Tsubaki ,  Noriaki Koto ,  Kouichi Maeda

    IPC分类号： C08F4/64 ,  C08F10/00 ,  C08F4/02 ,  C08F10/06

    CPC分类号： C08F10/00 ,  Y10S526/909

    摘要： A powdery isotactic polyolefin having high isotactic characteristic and high bulk density and a narrow size distribution is produced by forming a polymerization catalyst system by reacting a Grignard reagent with a chain or cyclic hydropolysiloxane having the unit ##EQU1## (R.sup.1 represents an alkyl, aryl, aralkyl, alkoxy or aryloxy group; a is 0, 1 or 2; b is 1, 2 or 3 and a+b.ltoreq.3) to form a reaction product (a); reacting the reaction product (a) with at least one compound having the formulaR.sup.2.sub.n M.sup.(z) X.sub.z-n(R.sup.2 represents a C.sub.1 to C.sub.12 hydrocarbon moiety; M represents Al or Si; z represents atomic value of 3 or 4; X represents a halogen atom; n is 0, 1 . . . (z-1)) in the presence of an aromatic hydrocarbon solvent at lower than 85.degree. C. to form a reaction product (b); and reacting the reaction product (b) with at least one titanium halide in the presence of an organic acid ester (c) to obtain a solid catalytic component (A) and adding an organoaluminum compound (B) if necessary with an organic acid ester (C); and then, polymerizing a C.sub.3 or C.sub.4 olefin in the presence of a catalytic amount of the polymerization catalyst system.

    摘要翻译： 通过使格利雅试剂与具有单元的链或环状聚硅氧烷（R 1表示烷基，芳基，环烷基，环烷基，环烷基，环烷基等）反应形成聚合催化剂体系，制备具有高全同立构特性和高堆积密度和窄尺寸分布的粉末状全同立构聚烯烃， 芳烷基，烷氧基或芳氧基; a为0,1或2; b为1,2或3，a + b为3），形成反应产物（a）。 使反应产物（a）与至少一种具有式R2nM（z）Xz-n的化合物（R2表示C1至C12烃部分; M表示Al或Si; z表示原子值3或4; X表示 卤素原子; n为0,1 ...（z-1）），在芳族烃溶剂存在下，低于85℃，形成反应产物（b）; 并在有机酸酯（c）的存在下使反应产物（b）与至少一种卤化钛反应得到固体催化组分（A），并且如果需要，用有机酸酯（B）加入有机铝化合物（B） C）; 然后在催化量的聚合催化剂体系存在下聚合C3或C4烯烃。

    Process for producing chlorobenzene sulfochloride
    4.
    发明授权
    Process for producing chlorobenzene sulfochloride 失效
    生产氯苯磺酰氯的方法

    公开(公告)号：US4666637A

    公开(公告)日：1987-05-19

    申请号：US788671

    申请日：1985-10-17

    申请人： Kazumi Tsubaki ,  Noriaki Koto ,  Kouichi Maeda

    发明人： Kazumi Tsubaki ,  Noriaki Koto ,  Kouichi Maeda

    IPC分类号： C07C309/86 ,  C07C67/00 ,  C07C301/00 ,  C07C303/08 ,  C07C143/40

    CPC分类号： C07C303/08

    摘要： A process for producing chlorobenzene sulfochloride comprises adding a reaction mixture of chlorobenzene and chlorosulfonic acid to water or diluted sulfuric acid to decompose excess chlorosulfonic acid; driving off hydrogen chloride thereby generated, from the system; bringing the sulfuric acid concentration in the sulfuric acid layer upon completion of the decomposition to be from 60 to 90%; and then separating chlorobenzene sulfochloride. The process is characterized in that the excess chlorosulfonic acid is decomposed at a temperature of from 40.degree. to 85.degree. C. and the chlorobenzene sulfochloride is separated in a liquid state at a temperature of from 60.degree. to 80.degree. C.

    摘要翻译： 制备氯苯磺酰氯的方法包括将氯苯和氯磺酸的反应混合物加入到水或稀硫酸中以分解过量的氯磺酸; 从系统中排出氯化氢，从而产生; 完成分解后使硫酸浓度达到60〜90％; 然后分离氯苯磺酰氯。 该方法的特征在于过量的氯磺酸在40℃至85℃的温度下分解，氯代苯磺酸盐在60至80℃的温度下以液态分离。

    Process for preparing polyphosphonate
    6.
    发明授权
    Process for preparing polyphosphonate 失效
    制备聚膦酸盐的方法

    公开(公告)号：US3946093A

    公开(公告)日：1976-03-23

    申请号：US536577

    申请日：1974-12-26

    申请人： Noriaki Koto ,  Keiichi Kondo ,  Naotake Okada

    发明人： Noriaki Koto ,  Keiichi Kondo ,  Naotake Okada

    IPC分类号： C08G79/00 ,  C07F9/38 ,  C07F9/40 ,  C08G79/02 ,  C08G79/04 ,  C08J9/28 ,  D06M13/02 ,  D06M13/244

    CPC分类号： C08G79/04

    摘要： An improvement is disclosed in a process for preparing a polyphosphonate which comprises polycondensing an aromatic diol having the formula (I) - (IV) ##SPC1##wherein Z represents chlorine or bromine atom or a lower alkyl group and m represents 0 or an integer of from 1 to 4 and n represents 0 or an integer of from 1 to 3; Y represents an alkylene group, cycloalkylene group, sulfonyl group, carbonyl group or oxygen atom; with a dihalide or arylphosphonic or thiophosphonic acid having the formula (V) ##SPC2##wherein A represents oxygen or sulfur atom; X represents chlorine or bromine atom; Z represents chlorine or bromine atom or a lower alkyl group; and 1 represents 0 or an integer of from 1 to 5, wherein the improvement comprises maintaining a solution of the polyphosphonate at a temperature such that solid polyphosphonate is produced after flashing; and then evaporating all or a part of the solvent from the solution by flashing whereby a porous solid polyphosphonate is formed.

    摘要翻译： 在制备聚膦酸酯的方法中公开了一种改进，其包括使具有式（I） - （IV）的芳族二醇缩聚，其中Z表示氯或溴原子或低级烷基，m表示0或1〜 4，n表示0或1〜3的整数， Y表示亚烷基，亚环烷基，磺酰基，羰基或氧原子; 具有式（Ⅴ）的二卤化物或芳基膦酸或硫代膦酸，其中A代表氧或硫原子; X表示氯或溴原子; Z表示氯或溴原子或低级烷基; 和1表示0或1至5的整数，其中改进包括将聚膦酸盐的溶液保持在使得在闪烁后产生固体聚膦酸盐的温度; 然后通过闪蒸从溶液中蒸发全部或一部分溶剂，由此形成多孔固体聚膦酸酯。