公开(公告)号：US20070155903A1

公开(公告)日：2007-07-05

申请号：US11660307

申请日：2005-08-29

申请人： Kazuyoshi Kaneko ,  Toshiyuki Hirose

发明人： Kazuyoshi Kaneko ,  Toshiyuki Hirose

IPC分类号： C08F8/00

CPC分类号： C08J3/005 ,  C08J2345/00 ,  C08J2365/00 ,  C08K5/14 ,  C08L45/00 ,  C08L65/00 ,  C08L2666/02

摘要： Provided is a method for producing a resin composition by melt-kneading a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C. and a flexible polymer (B) having a glass transition temperature of 0° C. or lower, wherein a part of the cyclic olefin polymer (A) is previously melt-kneaded with the flexible polymer (B) and a radical initiator (C) and then the remaining cyclic olefin polymer (A) is added thereto and melt-kneaded. The cyclic olefin polymer (A) is divided into two portions and added separately at two times, and accordingly, the mixture having a crosslinked structure may be diluted with the cyclic olefin polymer (A) not having a crosslinked structure, and the increase in the melt viscosity of the resin composition may be thereby prevented. A composition having good abrasion resistance and good melt shapability can be obtained.

摘要翻译： 提供一种通过熔融捏合玻璃化转变温度为60-200℃的环烯烃聚合物（A）和玻璃化转变温度为0℃的柔性聚合物（B）来制备树脂组合物的方法。 或更低，其中一部分环烯烃聚合物（A）预先与柔性聚合物（B）熔融捏合和自由基引发剂（C），然后向其中加入剩余的环状烯烃聚合物（A）并熔融捏合 。 环状烯烃聚合物（A）分成两部分，分两次加入，因此可以用不具有交联结构的环状烯烃聚合物（A）稀释交联结构的混合物， 因此可以防止树脂组合物的熔融粘度。 可以获得具有良好的耐磨性和良好的熔融成形性的组合物。

公开(公告)号：US08088865B2

公开(公告)日：2012-01-03

申请号：US11660307

申请日：2005-08-29

申请人： Kazuyoshi Kaneko ,  Toshiyuki Hirose

发明人： Kazuyoshi Kaneko ,  Toshiyuki Hirose

IPC分类号： C08F8/00 ,  C08L9/00 ,  C08L23/00 ,  C08L45/00

CPC分类号： C08J3/005 ,  C08J2345/00 ,  C08J2365/00 ,  C08K5/14 ,  C08L45/00 ,  C08L65/00 ,  C08L2666/02

摘要： Provided is a method for producing a resin composition by melt-kneading a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C. and a flexible polymer (B) having a glass transition temperature of 0° C. or lower, wherein a part of the cyclic olefin polymer (A) is previously melt-kneaded with the flexible polymer (B) and a radical initiator (C) and then the remaining cyclic olefin polymer (A) is added thereto and melt-kneaded. The cyclic olefin polymer (A) is divided into two portions and added separately at two times, and accordingly, the mixture having a crosslinked structure may be diluted with the cyclic olefin polymer (A) not having a crosslinked structure, and the increase in the melt viscosity of the resin composition may be thereby prevented. A composition having good abrasion resistance and good melt shapability can be obtained.

摘要翻译： 提供一种通过熔融捏合玻璃化转变温度为60-200℃的环烯烃聚合物（A）和玻璃化转变温度为0℃的柔性聚合物（B）来制备树脂组合物的方法。 或更低，其中一部分环烯烃聚合物（A）预先与柔性聚合物（B）熔融捏合和自由基引发剂（C），然后向其中加入剩余的环状烯烃聚合物（A）并熔融捏合 。 环状烯烃聚合物（A）分成两部分，分两次加入，因此可以用不具有交联结构的环状烯烃聚合物（A）稀释交联结构的混合物， 因此可以防止树脂组合物的熔融粘度。 可以获得具有良好的耐磨性和良好的熔融成形性的组合物。

公开(公告)号：US20110060096A1

公开(公告)日：2011-03-10

申请号：US12944334

申请日：2010-11-11

申请人： Kazuyoshi KANEKO ,  Toshiyuki Hirose ,  Hiroyasu Yamaoka ,  Kenichi Goto ,  Akira Hasegawa

发明人： Kazuyoshi KANEKO ,  Toshiyuki Hirose ,  Hiroyasu Yamaoka ,  Kenichi Goto ,  Akira Hasegawa

IPC分类号： C08L45/00

CPC分类号： H05K1/032 ,  C08L21/00 ,  C08L23/02 ,  C08L25/02 ,  C08L35/06 ,  C08L45/00 ,  C08L47/00 ,  C08L65/00 ,  H05K2201/0158 ,  C08L2666/02 ,  C08L2666/06 ,  C08L2666/04

摘要： A cyclic olefin resin composition which includes (A) 35 to 85 parts by weight of a cyclic olefin polymer having a glass transition temperature of 60 to 200° C., (B) 10 to 60 parts by weight of a flexible copolymer, prepared by polymerizing at least two monomers selected from the group consisting of an olefin compound, a diene compound and an aromatic vinyl hydrocarbon compound, and having a glass transition temperature of 0° C. or below, and (C) 5 to 55 parts by weight of a modified polyolefin. The cyclic olefin resin composition further includes, based on 100 parts by weight of total amount of the components (A), (B) and (C), (D) 0.01 to 5 parts by weight of a radical initiator and (E) 0 to 5 parts by weight of a polyfunctional compound having in its molecule two or more radically polymerizable functional groups. The composition can be used as a material for a substrate having low permittivity, low dielectric tangent, low water absorbability, and excellent heat resistance.

摘要翻译： 一种环状烯烃树脂组合物，其包含（A）35〜85重量份的玻璃化转变温度为60〜200℃的环状烯烃聚合物，（B）10〜60重量份的柔性共聚物，由 聚合至少两种选自烯烃化合物，二烯化合物和芳族乙烯基烃化合物的单体，并且玻璃化转变温度为0℃或更低，和（C）5至55重量份的 改性聚烯烃。 环状烯烃树脂组合物还包含基于100重量份的组分（A），（B）和（C）的总量，（D）0.01至5重量份的自由基引发剂和（E）0 至5重量份的在其分子中具有两个或更多个可自由基聚合的官能团的多官能化合物。 该组合物可以用作具有低介电常数，低介电切线，低吸水性和优异的耐热性的基材的材料。

公开(公告)号：US20080249235A1

公开(公告)日：2008-10-09

申请号：US11885236

申请日：2006-01-31

申请人： Kazuyoshi Kaneko ,  Toshiyuki Hirose ,  Hiroyasu Yamaoka ,  Kenichi Goto ,  Akira Hasegawa

发明人： Kazuyoshi Kaneko ,  Toshiyuki Hirose ,  Hiroyasu Yamaoka ,  Kenichi Goto ,  Akira Hasegawa

IPC分类号： C08L53/02 ,  C08L23/08

CPC分类号： H05K1/032 ,  C08L21/00 ,  C08L23/02 ,  C08L25/02 ,  C08L35/06 ,  C08L45/00 ,  C08L47/00 ,  C08L65/00 ,  H05K2201/0158 ,  C08L2666/02 ,  C08L2666/06 ,  C08L2666/04

摘要： A cyclic olefin resin composition which can be suitably used as a material for a substrate having low permittivity, low dielectric tangent, low water absorbability, excellent heat resistance, and the like, and a substrate obtained from the resin composition are provided. In particular, there is provided a novel cyclic olefin resin composition that can be suitably used as a material for a substrate for high frequency circuit dealing with high frequency signal transmission. The cyclic olefin resin composition comprises (A) 5 to 95 parts by weight of a cyclic olefin polymer having a glass transition temperature of 60 to 200° C. and (B) 5 to 95 parts by weight of a flexible copolymer, prepared by polymerizing at least two monomers selected from the group consisting of an olefin compound, a diene compound and an aromatic vinyl hydrocarbon compound, and having a glass transition temperature of 0° C. or below. The cyclic olefin resin composition further comprises, based on 100 parts by weight of total amount of the components (A) and (B), (D) 0.01 to 5 parts by weight of a radical initiator and (E) 0 to 5 parts by weight of a polyfunctional compound having in its molecule two or more radically polymerizable functional groups.

摘要翻译： 提供了可以适合用作具有低介电常数，低介电切线，低吸水性，优异的耐热性等的基材的材料的环烯烃树脂组合物和由该树脂组合物获得的基材。 特别地，提供了一种新的环烯烃树脂组合物，其可以适合用作用于处理高频信号传输的高频电路的基板的材料。 环状烯烃树脂组合物包含（A）5至95重量份的玻璃化转变温度为60至200℃的环烯烃聚合物和（B）5至95重量份的通过聚合制备的柔性共聚物 选自烯烃化合物，二烯化合物和芳族乙烯基烃化合物中的至少两种单体，玻璃化转变温度为0℃以下。 环状烯烃树脂组合物还包含基于100重量份的组分（A）和（B）的总量，（D）0.01至5重量份的自由基引发剂和（E）0至5重量份的 其分子中具有两个或更多个可自由基聚合的官能团的多官能化合物的重量。

公开(公告)号：US20070255030A1

公开(公告)日：2007-11-01

申请号：US11660308

申请日：2005-08-29

申请人： Takaki Sakamoto ,  Jun Shiraga ,  Noriyuki Konnai ,  Takayuki Kobayashi ,  Kazuyoshi Kaneko ,  Toshiyuki Hirose ,  Keita Nakanishi ,  Hiroaki Nagai

发明人： Takaki Sakamoto ,  Jun Shiraga ,  Noriyuki Konnai ,  Takayuki Kobayashi ,  Kazuyoshi Kaneko ,  Toshiyuki Hirose ,  Keita Nakanishi ,  Hiroaki Nagai

IPC分类号： C08L45/00

CPC分类号： C08L65/00 ,  C08K5/0025 ,  C08K5/14

摘要： Provided is a shaped article for clean rooms comprising a resin composition prepared by melt-kneading 100 parts by weight of a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C., from 1 to 150 parts by weight of a flexible copolymer (B) prepared by polymerizing at least two monomers selected from a group consisting of olefins, dienes and aromatic vinyl-hydrocarbons, and having a glass transition temperature of 0° C. or lower, from 0.001 to 1 part by weight of a radical initiator (C), and from 0 to 1 part by weight of a polyfunctional compound (D) having at least two radical-polymerizable functional groups in the molecule. The shaped article for clean rooms has good chemical resistance, heat resistance and dimensional accuracy, it is inhibited from releasing a volatile component around it, and it has good abrasion resistance and is inhibited from producing particles.

摘要翻译： 本发明提供一种洁净室用成型体，其特征在于，包括将100重量份玻璃化转变温度为60〜200℃的环状烯烃聚合物（A），1〜150重量份 通过聚合选自烯烃，二烯和芳族乙烯基烃的至少两种单体并且具有0℃或更低的玻璃化转变温度，0.001至1重量份的柔性共聚物（B） 的自由基引发剂（C）和0-1重量份在分子中具有至少两个可自由基聚合的官能团的多官能化合物（D）。 用于洁净室的成形制品具有良好的耐化学性，耐热性和尺寸精度，抑制其周围挥发性成分的释放，具有良好的耐磨性，并且抑制了颗粒的产生。

公开(公告)号：US20080315066A1

公开(公告)日：2008-12-25

申请号：US11658992

申请日：2005-07-28

申请人： Tooru Tanaka ,  Toshiyuki Hirose

发明人： Tooru Tanaka ,  Toshiyuki Hirose

IPC分类号： B28B7/34 ,  C08F10/14 ,  C08L23/00

CPC分类号： C08J5/18 ,  C08J2323/20 ,  C08L23/20 ,  C08L23/24 ,  H01C17/02 ,  H01G2/103 ,  H05K3/4611 ,  C08L2666/02

摘要： A poly 4-methyl-1-pentene resin composition which includes a polymer containing 80% by mass or more of 4-methyl-1-pentene in which the resin composition has a melting point of 170 to 240° C. and a semicrystallization time of 70 to 220 seconds. Also provided are a release film having good releasibility, a mold for production of a sealed electronic element product having excellent heat resistance and releasibility and an LED mold, which are obtained by molding the resin composition.

摘要翻译： 聚4-甲基-1-戊烯树脂组合物，其包含含有80质量％以上的4-甲基-1-戊烯的聚合物，其中树脂组合物的熔点为170〜240℃，半结晶时间 70到220秒。 还提供了具有良好剥离性的脱模膜，用于生产具有优异的耐热性和可剥离性的密封电子元件产品的模具和通过模制树脂组合物而获得的LED模具。

公开(公告)号：US20080304393A1

公开(公告)日：2008-12-11

申请号：US11631950

申请日：2005-07-01

申请人： Atsushi Shibuya ,  Toshiyuki Hirose

发明人： Atsushi Shibuya ,  Toshiyuki Hirose

IPC分类号： G11B7/00 ,  C08K5/3435

CPC分类号： C08K5/3435 ,  C08K5/0008 ,  C08K5/49 ,  C08L23/0823 ,  G02B1/04 ,  G11B2007/0006

摘要： Provided is a resin composition suitable for an optical element in which the moldability, thermal resistance, mechanical strength, and low birefringence are not impaired, the deterioration is hardly generated although the laser light nearby the UV is used, change in the optical properties during the use are extremely small, particularly the light transmittance is maintained high, and a foreign substance is hardly deposited on a surface of the molded product such as an optical element, also provided is an optical element obtained by molding the resin composition, and an optical pickup device using the optical element. The thermoplastic resin composition contains the polymer having a specific structure and two kinds of specific optical stabilizers in a specific mass ratio among a hindered amine light stabilizer having the molecular weight of 400 to 5,000; the optical element is obtained by molding the thermoplastic resin composition; and the optical pickup device includes the optical element.

摘要翻译： 本发明提供一种适用于不损害成型性，耐热性，机械强度，低双折射性的光学元件的树脂组合物，尽管使用了UV附近的激光，但几乎不发生劣化， 使用非常小，特别是透光率保持较高，并且异物难以沉积在诸如光学元件的成型产品的表面上，还提供了通过模制树脂组合物获得的光学元件和光学拾取器 装置使用光学元件。 热塑性树脂组合物含有具有特定结构的聚合物和两种具有分子量为400至5,000的受阻胺光稳定剂之间的比质量比的特定光学稳定剂; 光学元件通过模制热塑性树脂组合物而获得; 并且光学拾取装置包括光学元件。

公开(公告)号：US20070249792A1

公开(公告)日：2007-10-25

申请号：US11628640

申请日：2005-06-09

申请人： Nobuo Kawahara ,  Shinichi Kojoh ,  Shingo Matsuo ,  Hideyuki Kaneko ,  Tomoaki Matsugi ,  Norio Kashiwa ,  Munehito Funaya ,  Naritoshi Hirota ,  Tooru Tanaka ,  Toshiyuki Hirose ,  Nobuhisa Mikawa ,  Kouichi Kizu ,  Keiji Okada

发明人： Nobuo Kawahara ,  Shinichi Kojoh ,  Shingo Matsuo ,  Hideyuki Kaneko ,  Tomoaki Matsugi ,  Norio Kashiwa ,  Munehito Funaya ,  Naritoshi Hirota ,  Tooru Tanaka ,  Toshiyuki Hirose ,  Nobuhisa Mikawa ,  Kouichi Kizu ,  Keiji Okada

IPC分类号： C08F10/14 ,  B65D1/09

CPC分类号： C08F210/14 ,  C08F110/14 ,  D01F6/04 ,  D01F6/30 ,  C08F2500/15 ,  C08F2500/17 ,  C08F2500/03 ,  C08F210/16 ,  C08F210/06

摘要： A novel olefin-based polymer has excellent thermal resistance, as well as excellent balance among various properties. The olefin-based polymer is an olefin-based polymer comprising 50 to 100% by weight of a constituent unit derived from 4-methyl-1-pentene, and 0 to 50% by weight of a constituent unit derived from at least one olefin selected from olefins having 2 to 20 carbon atoms except 4-methyl-1-pentene, and having the following properties: i) the diad isotacticity is 70% or greater, ii) the ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) as measured by gel permeation chromatography (GPC) is in the range of 1.0 to 3.5, and iii) the intrinsic viscosity [η] is 0.5 (dl/g) or greater.

摘要翻译： 一种新型的烯烃基聚合物具有优异的耐热性，以及各种性能之间的良好平衡。 所述烯烃类聚合物是含有50〜100重量％的来自4-甲基-1-戊烯的构成单元和0〜50重量％的来源于所选择的至少一种烯烃的构成单元的烯烃系聚合物 来自具有2-甲基-1-戊烯的碳原子数为2〜20的烯烃，具有以下性质：i）二单体全同立构规整度为70％以上，ii）重均分子量（Mw / Mn） Mw）与通过凝胶渗透色谱法（GPC）测定的数均分子量（Mn）的比例在1.0〜3.5的范围内，和iii）特性粘度η为0.5（dl / g）以上。

公开(公告)号：US07314905B2

公开(公告)日：2008-01-01

申请号：US10521189

申请日：2004-03-26

申请人： Shigetoshi Nishijima ,  Shinichi Imuta ,  Toshiyuki Hirose

发明人： Shigetoshi Nishijima ,  Shinichi Imuta ,  Toshiyuki Hirose

IPC分类号： C08F10/14 ,  B32B27/32 ,  B32B11/08 ,  B65B33/00

CPC分类号： C08J5/18 ,  B29C33/68 ,  B29K2023/00 ,  B32B27/32 ,  C08J2323/02 ,  H05K3/4611 ,  Y10S428/91 ,  Y10T428/31913 ,  Y10T428/31938

摘要： A film that has high rigidity and high heat resistance and good releasability from a roughened copper foil surface, which is subjected to surface oxidization or etching treatment with acid, such as a black oxidized copper foil surface and that is suitable as a release film for producing an MLB; and a process for producing the same. A drawn film having a layer (A) which comprises a copolymer that is made from 4-methyl-1-pentene and ethylene or an α-olefin, except 4-methyl-1-pentene, having 3 to 20 carbon atoms and that comprises 80% or more by mole of 4-methyl-1-pentene, the thermal coefficient of contraction of the film being 20% or more in the film-drawn direction, or the peel area of the film being 50% or more when the film, together with a copper foil surface subjected to roughening treatment, is subjected to heating and pressing treatment. This film is suitable for producing an MLB and has good releasability from the roughened copper foil surface, for example, a black oxidized copper foil surface.

摘要翻译： 具有高刚性和高耐热性以及从被粗糙化的铜箔表面剥离的良好剥离性的薄膜，其经过表面氧化或酸蚀刻处理，例如黑色氧化铜箔表面，并且适合作为用于生产 一个MLB; 及其制造方法。 具有层（A）的拉伸膜，其包含由4-甲基-1-戊烯和乙烯或除了4-甲基-1-戊烯以外的具有3-20个碳原子的α-烯烃的共聚物，其包含 80％以上的4-甲基-1-戊烯，膜的热收缩率为20％以上，膜的剥离面积为50％以上时，膜的收缩率为50％以上 与经受粗糙化处理的铜箔表面一起进行加热和压制处理。 该膜适用于生产MLB，并且具有从粗糙化的铜箔表面，例如黑色氧化铜箔表面的良好的剥离性。

公开(公告)号：US20060261988A1

公开(公告)日：2006-11-23

申请号：US11383308

申请日：2006-05-15

申请人： Toshiyuki Hirose

发明人： Toshiyuki Hirose

IPC分类号： H03M7/00

CPC分类号： H03M7/3086

摘要： A character string retrieving circuit includes a delay circuit (10) for delaying a match/no match signal created in each clock period to indicate whether or not a character matched with a retrieval target exists in a dictionary by one clock period, creating circuits (2 (i), 3 (i), 5 (i) and 6 (i)) for creating in advance signals of two kinds of a signal (ps1 [i]) to assume that a character matched with a retrieval target exists in a dictionary in the clock period and a signal (ps0 [i]) to assume that a character matched with a retrieval target does not exist in a dictionary in the clock period as signals to predict retrieved results in a certain clock period later and a selecting circuit (4) (i) for selecting a signal with a correct assumption from the signals of 2 kinds in accordance with the match/no match signal delayed by the delay circuit (10), wherein a signal selected by the selecting circuit (4) (i) is used in the next clock period. Thus, in the character string retrieving circuit provided within a data compressing circuit using the LZ77 method, faster character string retrieval can be realized based on pipeline processing.

摘要翻译： 字符串检索电路包括延迟电路（10），用于延迟在每个时钟周期中产生的匹配/不匹配信号，以指示在字典中与检索对象匹配的字符是否存在一个时钟周期，产生电路（2 （i），3（i），5（i）和6（i）），用于提前产生两种信号（ps 1 [i]）的信号，以假设与检索目标匹配的字符存在于 字典在时钟周期中，以及信号（ps 0 [i]），以假设与检索对象匹配的字符在时钟周期中不存在于字典中，作为预测的信号在特定时钟周期内检索到的结果，以及选择 电路（4）（i），用于根据由延迟电路（10）延迟的匹配/不匹配信号从2种信号中选择具有正确假设的信号，其中由选择电路（4）选择的信号， （i）在下一个时钟周期使用。 因此，在使用LZ77方法的数据压缩电路内提供的字符串检索电路中，可以基于流水线处理来实现更快的字符串检索。