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    N-pyrrolidonyl methyltriphenyl phosphonium salts and method for their preparation and use
    4.
    发明授权
    N-pyrrolidonyl methyltriphenyl phosphonium salts and method for their preparation and use 失效
    N-吡咯烷酮基甲基三苯基鏻盐及其制备和使用方法

    公开(公告)号：US4997952A

    公开(公告)日：1991-03-05

    申请号：US420767

    申请日：1989-10-12

    申请人： Kolazi S. Narayanan ,  Paul D. Taylor

    发明人： Kolazi S. Narayanan ,  Paul D. Taylor

    IPC分类号： C07F9/572

    CPC分类号： C07F9/5721

    摘要： A novel triphenylphosphonium salts of chloromethyl pyrrolidone having the formula: ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 may be the same or different and may be hydrogen, lower alkyl, lower alkoxy, lower alkenyl, lower cycloalkyl, and lower carboalkoxy, phenyl, substituted phenyl, naphthyl, and substituted naphthyl, R.sub.4 is lower alkyl or phenyl and X is an anion. The compounds are useful in Wittig-type reactions and as phase transfer catalysts. A method for preparing the inventive compound is also disclosed.

    摘要翻译： 具有下式的氯甲基吡咯烷酮的新型三苯基鏻盐：其中R 1，R 2和R 3可以相同或不同，并且可以是氢，低级烷基，低级烷氧基，低级烯基，低级环烷基和低级烷氧羰基，苯基， 取代的苯基，萘基和取代的萘基，R4是低级烷基或苯基，X是阴离子。 该化合物可用于Wittig型反应和相转移催化剂。 还公开了制备本发明化合物的方法。

    Alkenyl ether polycarbonates
    6.
    发明授权
    Alkenyl ether polycarbonates 失效
    烯基醚聚碳酸酯

    公开(公告)号：US5254710A

    公开(公告)日：1993-10-19

    申请号：US13270

    申请日：1993-02-03

    申请人： Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

    发明人： Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

    IPC分类号： C07C43/23 ,  C07C69/96

    CPC分类号： C07C69/96 ,  C07C43/23

    摘要： This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--; R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.

    摘要翻译： 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯，其中A选自低级烷基和R'HC = CHOR-; R和R“各自独立地为具有2至20个碳原子的二价基团，并且选自亚烷基，单烷氧基或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，该基团任选地 被卤素，烷基，氰基，硝基或烷氧基取代; R'是氢或低级烷基; （n）的值为1〜10，（m）为0〜10的数值。 条件是当m为0时，R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。

    Alk-1-enyloxy carbonates
    8.
    发明授权
    Alk-1-enyloxy carbonates 失效
    烷基-1-烯氧基碳酸酯

    公开(公告)号：US5364691A

    公开(公告)日：1994-11-15

    申请号：US490854

    申请日：1990-03-09

    申请人： Paul D. Taylor ,  Kolazi S. Narayanan ,  Jeffrey S. Plotkin

    发明人： Paul D. Taylor ,  Kolazi S. Narayanan ,  Jeffrey S. Plotkin

    IPC分类号： C07C43/23 ,  C07C69/96 ,  C08F2/50 ,  C08F18/24 ,  C08F26/02

    CPC分类号： C07C69/96 ,  C07C43/23

    摘要： This invention relates to radiation curable alk-1-enyloxy carbonate reaction products of a hydroxylated compound having the formula A-ROH and a dialk-1-enyloxy carbonate having the formula ##STR1## wherein R is a polymeric radical selected from the group of polyester, polyacetal, polyurethane, polyether, and polycarbonate, said polymers containing from about 10 to 50 repeating monomer units;A' is a terminating moiety and is hydrogen, lower alkyl or hydroxy;R' is hydrogen or lower alkyl;B is a linear, branched or cyclic divalent radicalhaving from 2 to 12 carbon atoms and is selected from the group of alkylene, mono or poly alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, lower alkyl, cyano, nitro or alkoxy and m has a value of from 1 to 10. The products of this invention are defined by the formula: ##STR2## wherein A' is a terminating moiety and is hydrogen, lower alkyl or ##STR3##

    摘要翻译： 本发明涉及具有式A-ROH的羟基化化合物和具有式“IMAGE”的二烷基-1-烯氧基碳酸酯的可辐射固化的烷-1-烯氧基碳酸酯反应产物，其中R是选自聚酯的聚合基 聚缩醛，聚氨酯，聚醚和聚碳酸酯，所述聚合物含有约10至50个重复单体单元; A'为终止部分，为氢，低级烷基或羟基; R'是氢或低级烷基; B是具有2至12个碳原子的直链，支链或环状二价基团，并且选自亚烷基，单或多烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷基和亚芳基，其基团任选被卤素 ，低级烷基，氰基，硝基或烷氧基，m的值为1至10.本发明的产物由下式定义：其中A'为终止部分，为氢，低级烷基或 图像>

    Alkenyl ether polycarbonates
    10.
    发明授权
    Alkenyl ether polycarbonates 失效
    烯基醚聚碳酸酯

    公开(公告)号：US5358978A

    公开(公告)日：1994-10-25

    申请号：US13269

    申请日：1993-02-03

    申请人： Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

    发明人： Jeffrey S. Plotkin ,  Fulvio J. Vara ,  James A. Dougherty ,  Paul D. Taylor ,  Kolazi S. Narayanan

    IPC分类号： C07C43/23 ,  C07C69/96 ,  C08F2/50 ,  C08F220/18 ,  C08F220/26

    CPC分类号： C07C69/96 ,  C07C43/23

    摘要： This invention relates to alkenyl ether polycarbonates having the formula ##STR1## wherein A is selected from the group consisting of lower alkyl and R'HC.dbd.CHOR--, R and R" are each independently a divalent radical having from 2 to 20 carbon atoms and are selected from the group of alkylene, mono- or poly- alkoxylated alkylene, alkenylene, alkynylene, arylene, alkarylene and aralkylene radicals, which radicals are optionally substituted with halo, alkyl, cyano, nitro or alkoxy; R' is hydrogen or lower alkyl; (n) has a value of from 1 to 10 and (m) has a value of from 0 to 10; with the proviso that R" contains at least 3 carbon atoms when m is zero. The invention also concerns the preparation and use of said alkenyl ether polycarbonates.

    摘要翻译： 本发明涉及具有式“IMAGE”的烯基醚聚碳酸酯，其中A选自低级烷基和R'HC = CHOR-，R和R“各自独立地为具有2-20个碳原子的二价基团 选自亚烷基，单 - 或多 - 烷氧基化亚烷基，亚烯基，亚炔基，亚芳基，亚烷芳基和亚芳基，该基团任选被卤素，烷基，氰基，硝基或烷氧基取代; R'是氢或低级烷基; （n）的值为1〜10，（m）为0〜10的数值。 条件是当m为0时，R“至少包含3个碳原子。 本发明还涉及所述烯基醚聚碳酸酯的制备和用途。