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公开(公告)号:US20080281031A1
公开(公告)日:2008-11-13
申请号:US12158439
申请日:2006-12-20
摘要: The invention relates to compositions of polyvinylidene fluoride (PVDF) and its copolymers that have been modified with an onium salt. The PVDF compositions exhibit an increased melting point, a reduced heat distortion and piezo properties. The improved properties can be further enhanced through annealing, and/or the addition of nanoclays. Additionally, the combination of PVDF, nanoclays and annealing can also produce a PVDF with an increased melting point and piezoelectric properties.
摘要翻译: 本发明涉及已经用鎓盐改性的聚偏二氟乙烯(PVDF)及其共聚物的组合物。 PVDF组合物表现出增加的熔点,减少的热变形和压电性能。 通过退火和/或纳米粘土的添加可以进一步提高改进的性能。 此外,PVDF,纳米粘土和退火的组合也可以产生具有增加的熔点和压电性质的PVDF。
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公开(公告)号:US08263695B2
公开(公告)日:2012-09-11
申请号:US12158439
申请日:2006-12-20
IPC分类号: C08K3/34
摘要: The invention relates to compositions of polyvinylidene fluoride (PVDF) and its copolymers that have been modified with an onium salt. The PVDF compositions exhibit an increased melting point, a reduced heat distortion and piezo properties. The improved properties can be further enhanced through annealing, and/or the addition of nanoclays. Additionally, the combination of PVDF, nanoclays and annealing can also produce a PVDF with an increased melting point and piezoelectric properties.
摘要翻译: 本发明涉及已经用鎓盐改性的聚偏二氟乙烯(PVDF)及其共聚物的组合物。 PVDF组合物表现出增加的熔点,减少的热变形和压电性能。 通过退火和/或纳米粘土的添加可以进一步提高改进的性能。 此外,PVDF,纳米粘土和退火的组合也可以产生具有增加的熔点和压电性质的PVDF。
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3.
公开(公告)号:US07781509B2
公开(公告)日:2010-08-24
申请号:US12252656
申请日:2008-10-16
申请人: Nicholas J. Rodak , Brian Edgecombe , Noah E. Macy
发明人: Nicholas J. Rodak , Brian Edgecombe , Noah E. Macy
IPC分类号: C08K9/04
CPC分类号: C08K9/04 , C01B33/44 , C01P2002/22 , C01P2002/72 , C01P2002/86 , C01P2002/88
摘要: A modified clay may be made by contacting a clay with an unsaturated cationic compound and an alkoxyamine, or an adduct thereof. The resulting pre-activated clay, which contains a cationic alkoxyamine bound to the clay, may be further treated with a monomer to provide a polymer that is bound to the clay, thereby forming a nanocomposite material. The nanocomposite material may in turn be blended with another polymer prepared from the same or a different monomer.
摘要翻译: 改性粘土可以通过使粘土与不饱和阳离子化合物和烷氧基胺或其加合物接触来制备。 所得到的预活化粘土含有与粘土结合的阳离子烷氧基胺,可进一步用单体处理,以提供与粘土结合的聚合物,由此形成纳米复合材料。 纳米复合材料又可以与由相同或不同单体制备的另一种聚合物共混。
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公开(公告)号:US20080169451A1
公开(公告)日:2008-07-17
申请号:US11815038
申请日:2006-03-03
申请人: Gary S. Silverman , Thomas P. Mc Andrew , Scott C. Schmidt , David A. Mountz , Mark A. Aubart , Nicholas J. Rodak
发明人: Gary S. Silverman , Thomas P. Mc Andrew , Scott C. Schmidt , David A. Mountz , Mark A. Aubart , Nicholas J. Rodak
CPC分类号: C08L65/00 , C08F290/06 , C08F293/005 , C08F2438/01 , C08G61/124 , C08G61/126 , C08G73/0266 , C08L33/10 , C08L79/02 , C08L2666/14 , C08L2666/02
摘要: The invention relates to the synthesis of polythiophene (PAT) copolymers, and their use as conductive polymers in final applications. Specifically, copolymers of PAT with (meth)acrylates, or amides are useful as additives in blends of different polymer matrices in many commercial applications.
摘要翻译: 本发明涉及聚噻吩(PAT)共聚物的合成及其在最终应用中作为导电聚合物的用途。 具体地说,PAT与(甲基)丙烯酸酯的共聚物或酰胺在许多商业应用中可用作不同聚合物基质的共混物中的添加剂。
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5.
公开(公告)号:US08674142B2
公开(公告)日:2014-03-18
申请号:US12721885
申请日:2010-03-11
CPC分类号: B01J23/04 , B01J31/122 , B01J2231/64 , C07F9/505
摘要: The invention relates to the use of polycyclic aromatic hydrocarbons (PAHs) such as naphthalene and its alkyl, aryl, or heteroatom substituted analogs, that act as catalysts in the presence of an alkali metal (Li, K, Na) for the reduction of electron-deficient and electron-rich triaryl phosphines to their corresponding alkali metal diaryl phosphide salts. The process is also useful for the catalysis of triaryl phosphine chalcogen adducts such as the sulfides, oxides, and selenides, diaryl(halo)phosphines, triaryl phosphine-borane adducts, and tetra-aryl bis(phosphines) that can also be reduced to their corresponding alkali metal diaryl phosphide salts. The invention also relates to small molecule PAHs and polymer tethered PAHs naphthenics.
摘要翻译: 本发明涉及在碱金属(Li,K,Na)存在下用作还原电子的作为催化剂的萘及其烷基,芳基或杂原子取代的类似物的多环芳烃(PAH)的用途 缺陷和富电子的三芳基膦与其相应的碱金属二芳基磷酸盐。 该方法还可用于催化三芳基膦硫属化合物加合物如硫化物,氧化物和硒化物,二芳基(卤代)膦,三芳基膦 - 硼烷加合物和四芳基双(膦),其也可以还原成它们 相应的碱金属二芳基磷酸盐。 本发明还涉及小分子PAHs和聚合物系链PAHs环烷烃。
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公开(公告)号:US08541541B2
公开(公告)日:2013-09-24
申请号:US11815038
申请日:2006-03-03
申请人: Gary S. Silverman , Thomas P. McAndrew , Scott C. Schmidt , David A. Mountz , Mark A. Aubart , Nicholas J. Rodak
发明人: Gary S. Silverman , Thomas P. McAndrew , Scott C. Schmidt , David A. Mountz , Mark A. Aubart , Nicholas J. Rodak
IPC分类号: C08G75/00
CPC分类号: C08L65/00 , C08F290/06 , C08F293/005 , C08F2438/01 , C08G61/124 , C08G61/126 , C08G73/0266 , C08L33/10 , C08L79/02 , C08L2666/14 , C08L2666/02
摘要: The invention relates to the synthesis of polythiophene (PAT) copolymers, and their use as conductive polymers in final applications. Specifically, copolymers of PAT with (meth)acrylates, or amides are useful as additives in blends of different polymer matrices in many commercial applications.
摘要翻译: 本发明涉及聚噻吩(PAT)共聚物的合成及其在最终应用中作为导电聚合物的用途。 具体地说,PAT与(甲基)丙烯酸酯的共聚物或酰胺在许多商业应用中可用作不同聚合物基质的共混物中的添加剂。
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公开(公告)号:US07928158B2
公开(公告)日:2011-04-19
申请号:US12375999
申请日:2007-07-31
申请人: Nicholas J. Rodak , Nafih Mekhilef , Thomas Bole
发明人: Nicholas J. Rodak , Nafih Mekhilef , Thomas Bole
CPC分类号: C08L33/02 , C08K3/34 , C08L35/06 , C08L2205/06 , C08L2666/04
摘要: The present invention relates to copolymer process aids having a carboxylic anhydride or acid functionality and a hydrophobic functionality. The copolymer process aid can be used in the exfoliation of a nanoclay, where it can be made in situ; and can also serve as a compatibilizer for exfoliated nanoclays with a polymer matrix, including with impact modified polymer matrices.
摘要翻译: 本发明涉及具有羧酸酐或酸官能度和疏水官能度的共聚物加工助剂。 共聚物加工助剂可用于纳米粘土的剥离,其中可以原位制备; 并且还可以用作具有聚合物基质的剥离纳米粘土的增容剂,包括具有抗冲改性聚合物基质。
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公开(公告)号:US20100029835A1
公开(公告)日:2010-02-04
申请号:US12375999
申请日:2007-07-31
申请人: Nicholas J. Rodak , Nafih Mekhilef , Thomas Bole
发明人: Nicholas J. Rodak , Nafih Mekhilef , Thomas Bole
CPC分类号: C08L33/02 , C08K3/34 , C08L35/06 , C08L2205/06 , C08L2666/04
摘要: The present invention relates to copolymer process aids having a carboxylic anhydride or acid functionality and a hydrophobic functionality. The copolymer process aid can be used in the exfoliation of a nanoclay, where it can be made in situ; and can also serve as a compatibilizer for exfoliated nanoclays with a polymer matrix, including with impact modified polymer matrices.
摘要翻译: 本发明涉及具有羧酸酐或酸官能度和疏水官能度的共聚物加工助剂。 共聚物加工助剂可用于纳米粘土的剥离,其中可以原位制备; 并且还可以用作具有聚合物基质的剥离纳米粘土的增容剂,包括具有抗冲改性聚合物基质。
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