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公开(公告)号：USH495H
公开(公告)日：1988-07-05
申请号：US72300
申请日：1987-07-13
IPC分类号： C09K8/32
CPC分类号： C09K8/32
摘要： An oil-based drilling mud which comprises:(a) a hydrocarbon liquid substantially immiscible in water;(b) about 1 to about 100 parts by weight of water per 100 parts of the hydrocarbon liquid;(c) about 2 to about 50 lb/bbl. of at least one emulsifier;(d) about 0.5 to about 5 lb/bbl. of a wetting agent;(e) about 50 to about 750 lb/bbl. of a weighting agent;(f) about 0.1 to about 25 lb/bbl. of a water insoluble, oil soluble terpolymer, said terpolymer having the formula: ##STR1## wherein R.sub.1 and R.sub.3 are selected from the group consisting of hydrogen and a methyl group, wherein R.sub.2 is selected from the group consisting of C.sub.3 H.sub.5, C.sub.6 H.sub.4 --CH.sub.3, C.sub.6 H.sub.4 (CH.sub.3).sub.2 and CnH.sub.2n+1, wherein n=1 to 30 and R.sub.4 is selected from the group consisting of C.sub.5 H.sub.4 N, CnH.sub.2n NH.sub.3 and CnH.sub.2n N(CH.sub.3).sub.3, wherein n=1 to 30 and x is about 40 to about 98 mole percent, y is about 1 to about 50 mole percent, and z is about 1 to about 50 mole percent, wherein y and z are less than 60 mole percent, and M is an amine or a metal cation selected from the group consisting of aluminum, iron, lead, Groups IA, IIA, IVA, VIA, VIIA, VIIIA, IB and IIB of the Periodic Table of Elements.
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2.发明授权Hydrocarbon soluble polymer complexes useful as viscosifiers in fracturing operations 失效用于压裂作业中的增粘剂的烃溶性聚合物配合物
公开(公告)号：US4579671A
公开(公告)日：1986-04-01
申请号：US651899
申请日：1984-09-19
CPC分类号： C09K8/64 , Y10S507/922
摘要： A process for fracturing a subterranean formation surrounding a gas or oil well which comprises injecting said subterranean formation under hydraulic pressure with a fluid comprising about 0.1 to about 75 percent of an interpolymer complex dissolved in a solvent system of a nonpolar organic liquid and a polar cosolvent (as desired), said polymer complex comprises the interaction product of a sulfonated polymer and an amine containing polymer, wherein the sulfonate content of the sulfonated polymer is about 4 meq. per 100 gram of polymer to about 200 meq. per 100 gram of polymer and the basic nitrogen content of the amine containing polymer is about 4 meq. per 100 gram of polymer to about 500 meq. per 100 gram of polymer, and by the addition of polar cosolvent to such solution of polymer complex modifying its rheological properties over a wide range and their subsequent use as fracturing fluids.
摘要翻译： 一种用于压裂围绕气体或油井的地下地层的方法，其中包括在液压下用含有约0.1至约75％的溶解在非极性有机液体和极性助溶剂的溶剂体系中的互聚物络合物的流体注入所述地下地层 （根据需要），所述聚合物复合物包括磺化聚合物和含胺聚合物的相互作用产物，其中磺化聚合物的磺酸盐含量为约4meq。 每100克聚合物至约200meq。 每100克聚合物，并且含胺聚合物的碱性氮含量为约4meq。 每100克聚合物至约500meq。 每100克聚合物，并通过向这种聚合物络合物溶液加入极性助溶剂，改变其在很宽的范围内的流变性能，并随后用作压裂液。
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3.发明授权Controlled hydraulic fracturing via nonaqueous solutions containing low charge density polyampholytes 失效通过含有低电荷密度聚阴离子的非水溶液控制水力压裂
公开(公告)号：US4739834A
公开(公告)日：1988-04-26
申请号：US521
申请日：1987-01-05
CPC分类号： C09K8/64 , Y10S507/922
摘要： A process for fracturing a subterranean formation surrounding a gas or oil well which comprises:(a) injecting into said subterranean formation under hydraulic pressure a fluid comprising a solution of terpolymer dissolved in a solvent system, said solvent system comprising an organic liquid and a polar cosolvent, said polar cosolvent being less than about 15 weight percent of said solvent system, said terpolymer comprising a water-insoluble, oil-soluble terpolymer dissolved in said solvent system, the concentration of said terpolymer in said solution being about 0.2 to about 10 weight percent and the viscosity of said solution being less than about 2,000 cps, said terpolymer having the formula: ##STR1## wherein R.sub.1 =C.sub.6 H.sub.5, C.sub.6 H.sub.4 --CH.sub.3, C.sub.6 H.sub.4 --(CH.sub.3).sub.3, Cn H.sub.2 NH; wherein n=1-30; wherein x is about 50 to about 98 mole percent; y is about 1 to about 50 mole percent; z is about 1 to about 50 mole percent; wherein y and z are less than 60 mole percent; and M is an amine or a metal cation selected from the group consisting of antimony, tin, lead, Groups IA, IIA, IB and IIB of the Periodic Table of Elements; and(b) adding water to said solution of said polymer, said polar cosolvent transferring from said organic liquid to said water, thereby causing said organic liquid to gel within the fractures of said subterranean formation.
摘要翻译： 一种用于压裂围绕气体或油井的地层的方法，其包括：（a）在液压下将包含溶解在溶剂体系中的三元共聚物溶液的流体注入所述地层中，所述溶剂体系包含有机液体和极性 共溶剂，所述极性助溶剂小于所述溶剂体系的约15重量％，所述三元共聚物包含溶解在所述溶剂体系中的水不溶性油溶性三元共聚物，所述三元共聚物在所述溶液中的浓度为约0.2至约10重量％ 所述三元共聚物具有下式：其中R1 = C6H5，C6H4-CH3，C6H4-（CH3）3，CnH2NH; 其中n = 1-30; 其中x为约50至约98摩尔％; y为约1至约50摩尔％; z为约1至约50摩尔％; 其中y和z小于60摩尔％; M是选自元素周期表的锑，锡，铅，IA，IIA，IB和IIB族的胺或金属阳离子; 和（b）向所述聚合物的所述溶液中加入水，所述极性助溶剂从所述有机液体转移到所述水中，从而使所述有机液体在所述地层的裂缝内凝胶化。
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公开(公告)号：USH837H
公开(公告)日：1990-11-06
申请号：US375445
申请日：1989-07-05
IPC分类号： C09K8/36
CPC分类号： C09K8/36
摘要： An oil-based drilling mud which comprises an organic liquid substantially immiscible in water; about 1 to about 10 parts by weight of water per 100 parts by weight of the organic liquid; about 20 to about 50 lb./bbl. of at least one emulsifier; weighting material necessary to achieve the desired density; and about 0.25 to about 4.0 lb/bbl. of a hydrocarbon soluble polymeric complex formed from a water insoluble anionic polymer and a cationic polymer.
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5.发明授权Hydrocarbon soluble polymer complexes useful as viscosifiers in fracturing operations 失效用于压裂作业中的增粘剂的烃溶性聚合物配合物
公开(公告)号：US4615393A
公开(公告)日：1986-10-07
申请号：US673004
申请日：1984-11-19
IPC分类号： C09K8/64 , E21B43/26 , E21B43/267
CPC分类号： C09K8/64 , Y10S507/922
摘要： A process for fracturing a subterranean formation surrounding a gas or oil well which comprises injecting into said subterranean formation under hydraulic pressure a fluid comprising about 0.01 to about 25 weight percent of a water insoluble polymer complex dissolved in a solvent system of a nonpolar organic liquid, said polymer complex comprising the interaction product of a metal neutralized sulfonated polymer and an amine containing polymer, wherein the sulfonate content of the sulfonated polymer is about 4 meq. per 100 gram of polymer to about 200 meq. per 100 gram of polymer and the basic nitrogen content of the amine containing polymer is about 4 meq. per 100 gram of polymer to about 500 meq. per 100 gram of polymer.
摘要翻译： 一种用于压裂围绕气体或油井的地层的方法，其包括在水压下将包含约0.01至约25重量％的溶解在非极性有机液体的溶剂体系中的水不溶性聚合物配合物的流体注入所述地下地层， 所述聚合物复合物包含金属中和的磺化聚合物和含胺聚合物的相互作用产物，其中磺化聚合物的磺酸盐含量为约4meq。 每100克聚合物至约200meq。 每100克聚合物，并且含胺聚合物的碱性氮含量为约4meq。 每100克聚合物至约500meq。 每100克聚合物。
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公开(公告)号：US4627926A
公开(公告)日：1986-12-09
申请号：US651900
申请日：1984-09-19
CPC分类号： C09K8/882 , C08F226/10 , C09K8/12 , C09K8/62 , Y10S507/922 , Y10S507/925
摘要： A method of completing a subterranean formation of an oil or gas well to increase the recovery of hydrocarbons from the producing reservoir which comprises dissolving about 0.25 to about 20 lb/bbl of a water soluble terpolymer in an aqueous solution to viscosify said aqueous solution and pumping said aqueous solution with said water base terpolymer dissolved therein into said well to control the sub-surface pressures of said well, wherein said terpolymer has the formula: ##STR1## wherein x is about 70 to about 98 mole %, y is about 1 to about 15 mole %, z is about 1 to about 15 mole %, wherein y and z are less than 60 mole %, and M is selected from the group consisting of amines and a metallic cation being selected from the group consisting of lead, iron, aluminum, Groups IA, IIA, IB and II of the Periodic Table of Elements.
摘要翻译： 一种完成油井或气井的地层形成以提高从生产储层中回收烃的方法，其包括在水溶液中溶解约0.25至约20磅/桶的水溶性三元共聚物以使所述水溶液粘稠和泵送 所述水溶液与所述水基三元共聚物溶解在所述孔中以控制所述孔的下表面压力，其中所述三元共聚物具有下式：其中x为约70至约98摩尔％，y为约1至 约15摩尔％，z为约1至约15摩尔％，其中y和z小于60摩尔％，M选自胺和金属阳离子，所述胺和金属阳离子选自铅，铁 ，铝，元素周期表的IA，IIA，IB和II组。
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公开(公告)号：US4683952A
公开(公告)日：1987-08-04
申请号：US903450
申请日：1986-09-04
CPC分类号： C09K8/46 , C04B24/2688 , C09K8/42
摘要： A cement fluid-loss composition and its use in a well cementing process are disclosed. The cement fluid loss composition comprises an aqueous slurry of about 35 to about 90 weight percent of water based on weight percent of dry cement; and about 0.1 to about 2 weight percent of a terpolymer based on weight percent of dry cement, said terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, more preferably about 50 to about 95 mole %, and most preferably about 80 to about 90, y is about 1 to about 50 mole %, more preferably about 2 to about 20 mole %, and most preferably about 5 to about 10 mole %, and z is about 1 to about 50 mole %, more preferably about 2 to about 20, and most preferably about 5 to about 10, y is equal to z, B is about 1 to about 50 mole %, more preferably about 2 to about 20 mole %, and most preferably about 5 to about 10 mole %, wherein B, y and z are less than 60 mole %.
摘要翻译： 公开了一种水泥流体损失组合物及其在井固定方法中的应用。 水泥流体损失组合物包含基于干燥水泥重量百分数的约35至约90重量％的水的含水浆料; 和约0.1至约2重量％的基于重量百分比的干燥水泥的三元共聚物，所述三元共聚物具有下式：其中x为约40至约98摩尔％，更优选约50至约95摩尔％，以及 最优选约80至约90，y为约1至约50摩尔％，更优选约2至约20摩尔％，最优选约5至约10摩尔％，z为约1至约50摩尔％ 更优选约2至约20，最优选约5至约10，y等于z，B为约1至约50摩尔％，更优选约2至约20摩尔％，最优选约5至约20摩尔％ 10摩尔％，其中B，y和z小于60摩尔％。
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8.发明授权Low and high temperature drilling fluids based on sulfonated terpolymer ionomers 失效基于磺化三元共聚物离聚物的低温高温钻井液
公开(公告)号：US4978461A
公开(公告)日：1990-12-18
申请号：US325423
申请日：1989-03-20
IPC分类号： C09K8/32
CPC分类号： C09K8/32
摘要： The present invention relates to sulfonated thermoplastic terpolymers which are terpolymers of p-methyl styrene, styrene and sodium styrene sulfonate wherein these sulfonated terpolymers function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill fits and lift cuttings from the holes in the drilling operation for oil an gas wells. The sulfonated thermoplastic terpolymer of the latex have about 5 to about 100 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic terpolymer, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic polymer, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic terpolymer in the oil drilling and by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymer.The drilling muds formed from these lattices of the sulfonated thermoplastic terpolymers exhibits markedly improved low and high temperature rheological properties as compared to drilling muds formed from sulfonated thermoplastic copolymers.
摘要翻译： 本发明涉及作为对甲基苯乙烯，苯乙烯和苯乙烯磺酸钠的三元共聚物的磺化热塑性三元共聚物，其中当将这些磺化三元共聚物加入到用作维持压力的流体的油基钻井泥浆中时，其作为增粘剂起作用， 并在钻井作业中从钻孔中提取切屑用于油井。 乳液的磺化热塑性三元共聚物具有约5至约100meq。 每100克磺化热塑性三元共聚物的磺酸盐基团，其中磺化基团被金属阳离子或胺或铵抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性聚合物的混合物中，其中极性助溶剂增加磺化热塑性三元共聚物在石油钻井中的溶解度，并且通过降低磺化聚合物的磺酸盐基团之间的强离子相互作用 。 与由磺化热塑性共聚物形成的钻井泥浆相比，由磺化热塑性三元共聚物的这些晶格形成的钻井泥浆显示出显着改善的低温和高温流变性能。
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公开(公告)号：US4626285A
公开(公告)日：1986-12-02
申请号：US651897
申请日：1984-09-19
CPC分类号： C04B24/2688 , C09K8/46 , C09K8/487 , C04B2103/46
摘要： A cement fluid loss composition which comprises an aqueous slurry of about 35 to about 90 weight percent of water based on weight percent of dry cement; and about 0.1 to about 2 weight percent of a terpolymer based on weight percent of dry cement, said terpolymer having the formula: ##STR1## wherein x is about 40 to about 98 mole %, y is about 1 to about 50 mole %, z is about 1 to about 50 mole %, y is equal to z, A is about 1 to about 50 mole %, wherein A, y and z are less than 60 mole % and M is selected from the group consisting of amines and a metallic cation being selected from the group consisting of lead, iron, aluminum, Groups IA, IIA, IVA, VIA, VIIA, VIIIA, IB and IIB of the Periodic Table of Elements.
摘要翻译： 一种水泥流体损失组合物，其包含基于干燥水泥重量百分数约35至约90重量％的水的含水浆料; 和约0.1至约2重量％的三元共聚物，基于干水泥的重量百分比，所述三元共聚物具有下式：其中x为约40至约98摩尔％，y为约1至约50摩尔％，z为 为约1至约50摩尔％，y等于z，A为约1至约50摩尔％，其中A，y和z小于60摩尔％，M选自胺和金属 阳离子选自元素周期表的铅，铁，铝，IA，IIA，IVA，VIA，VIIA，VIIIA，IB和IIB族。
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公开(公告)号：US4738997A
公开(公告)日：1988-04-19
申请号：US807674
申请日：1985-12-11
IPC分类号： C08L95/00
CPC分类号： C08L95/00
摘要： A bitumen-containing composition which comprises;(a) bitumen;(b) about 0.5 to about 30 parts by weight of a polymer complex per 100 parts by weight of the bitumen; and(c) about 0 to about 100 parts by weight of a filler per 100 parts by weight of the bitumen.
摘要翻译： 含有沥青的组合物，其包含： （a）沥青; （b）每100重量份沥青约0.5至约30重量份的聚合物复合物; 和（c）每100重量份沥青约0至约100重量份的填料。
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