Phenylsulfonylureas, processes for their preparation, and their use as herbicides and plant growth regulations
    1.
    发明授权
    Phenylsulfonylureas, processes for their preparation, and their use as herbicides and plant growth regulations 有权
    苯磺酰脲,其制备方法,以及它们作为除草剂和植物生长条件的用途

    公开(公告)号:US06239306B1

    公开(公告)日:2001-05-29

    申请号:US09241213

    申请日:1999-02-01

    IPC分类号: C07C32716

    摘要: Compounds of the formula (I) and their salts as defined in claim 1, in which R1 is CO—Q—R8, where R8=H or R R2 and R3 are H or (C1-C4)alkyl, R4 is H, R, RO, OH, RCO, RSO2, PhSO2 R5 is RSO2, PhSO2, PhCO, RNHSO2, R2NSO2, RCO, CHO, COCOR′, CW—T—R9, CW—NR10R11, CW—N(R12)2 or R4 and R5 together are the chain (CH2)mB or —B1—(CH2)m1B— where B=SO2, m=3, 4; m1=2, 3; T and W=O, S; Q=O, S, NR13 where R13=H, R; R6=H, R, RO, RCO, ROCO, Hal, NO2, CN; R7=H, CH3; R9=R; R10, R11=H, R; N(R12)2=heterocycle A=pyrimidinyl and triazinyl radical or an analog thereof, where R=(substituted) aliphatic hydrocarbon radical, are suitable as selective herbicides. They are prepared by analogous processes via sulfonamides, some of which are new, of the formula (II) (see claim 4).

    摘要翻译: 式(I)的化合物及其盐如权利要求1所定义,其中R 1为CO-Q-R 8,其中R 8 = H或R 2,R 3为H或(C 1 -C 4)烷基,R 4为H,R ,OH,RCO,RSO2,PhSO2R5是RSO2,PhSO2,PhCO,RNHSO2,R2NSO2,RCO,CHO,COCOR',CW-T-R9,CW-NR10R11,CW-N(R12)2或R4和R5一起是链 (CH2)mB或-B1-(CH2)m1B-,其中B = SO2,m = 3,4; m1 = 2,3; T和W = O,S; Q = O,S,NR 13其中R 13 = H,R; R 6 = H,R,RO,RCO,ROCO,Hal,NO 2,CN; R 7 = H,CH 3; R9 = R; R10,R11 = H,R; N(R 12)2 =杂环A =嘧啶基和三嗪基或其类似物,其中R =(取代的)脂族烃基适合作为选择性除草剂。 它们通过磺酰胺类似的方法制备,其中一些是新的式(II)(参见权利要求4)。

    N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use
    2.
    发明授权
    N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use 失效
    N-酰基磺酰胺,除草剂和解毒剂的新型混合物及其用途

    公开(公告)号:US06235680B1

    公开(公告)日:2001-05-22

    申请号:US08863476

    申请日:1997-05-27

    IPC分类号: A01N2532

    摘要: Novel N-acylsulfonamides, novel mixtures of herbicides and antidotes, and their use Safeners against phytotoxic side effects of pesticides in crop plants are compounds of the formula (I) and salts thereof where R1 is hydrogen, a hydrocarbon radical, a hydrocarbonoxy radical, a hydrocarbonthio radical or a heterocyclyl radical, each of the last-mentioned 4 radicals being unsubstituted or substituted by one or more identical or different radicals selected from the group consisting of halogen, cyano, nitro, amino, hydroxyl, carboxyl, formyl, carboxamide, sulfonamide and radicals of the formula —Za—Ra R2 is hydrogen or (C1-C4)-alkyl or R1 and R2 together with the group of the formula —CO—N— are the radical of a 3- to 8-membered saturated or unsaturated ring and R3 to R5, n and m are as defined in claim 1. The compounds can be prepared by the process of claim 8.

    摘要翻译: 新型N-酰基磺酰胺,除草剂和解毒剂的新型混合物及其用途农药对作物植物的植物毒副作用的安全剂是式(I)化合物及其盐,其中R 1是氢,烃基,烃氧基,烃硫基 或杂环基,每个最后提到的4个基团是未取代的或被一个或多个选自卤素,氰基,硝基,氨基,羟基,羧基,甲酰基,甲酰胺,磺酰胺和基团的相同或不同的基团取代 式-Za-RaR2是氢或(C1-C4) - 烷基或R1和R2与式-CO-N-的基团是3-至8-元饱和或不饱和环的基团和R3至R5 ,n和m如权利要求1所定义。化合物可以通过权利要求8的方法制备。

    Method for controlling harmful plants in rice with
2-benzoyl-1,3-cyclohexanedione derivatives
    5.
    发明授权
    Method for controlling harmful plants in rice with 2-benzoyl-1,3-cyclohexanedione derivatives 失效
    用2-苯甲酰基-1,3-环己二酮衍生物控制水稻有害植物的方法

    公开(公告)号:US5318947A

    公开(公告)日:1994-06-07

    申请号:US856170

    申请日:1992-06-09

    CPC分类号: A01N41/10 A01N35/06

    摘要: Compounds of the formula I ##STR1## where R.sup.1 to R.sup.9 are as defined in claim 1 are known as herbicides. When these compounds are applied in traditionally used amounts, this often results in damage to crop plants in the crops, when it is desired to achieve sufficient action against weeds typically occurring therein. However, according to the invention it is possible to reduce the application rates to 0.001 to 0.5 kg of a.i./ha in rice growing, and the action obtained against important harmful plants in rice from the species Sagittaria, Cyperus and Scirpus Eleocharis is nevertheless sufficient.

    摘要翻译: PCT No.PCT / EP90 / 01721 Sec。 371日期:1992年6月9日 102(e)日期1992年6月9日PCT提交1990年10月12日PCT公布。 出版物WO91 / 05470 日本1991年5月2日。式I的化合物(I)其中R1至R9如权利要求1中所定义,作为除草剂是已知的。 当这些化合物以传统使用的量施用时,当期望通过其中通常发生的杂草达到足够的作用时,这通常导致作物对作物的损害。 然而,根据本发明,可以将水稻种植中的施用率降低至0.001至0.5kg的a.i./ha,而对于来自S the属(Sagittaria),莎草(Scperus)和Ele the属(Scirpus Eleocharis)的水稻中重要的有害植物所获得的作用仍然足够。

    (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators
    9.
    发明授权
    (Het) arylsulfonylureas having an amino function, their presentation and their use as herbicides and plant growth regulators 失效
    (Het)芳基磺酰脲具有氨基功能,它们的表现及其作为除草剂和植物生长调节剂的用途

    公开(公告)号:US06410482B1

    公开(公告)日:2002-06-25

    申请号:US08855251

    申请日:1997-05-13

    IPC分类号: C07D40112

    摘要: (Het)Arylsulfonylureas having an imino function, their preparation, and their use as herbicides and plant growth regulators Compounds of the formula (I) and salts thereof in which A is a (hetero)aromatic or heterocyclic bridge linked to the group SO2 by a direct bond, or via O, S, NH, CH2 or via alkylated NH or alkylated methylene, B is a group having an imino-containing fragment N═C—N, N═C—S, N═C—O or N═C—C which is linked to A by one of the nitrogen atoms of the fragment, R═H or an aliphatic radical, W═O or S and X, Y and Z are as defined in claim 1 are suitable as herbicides and plant growth regulators. The preparation is carried out for example similarly to known processes via novel intermediates of the formula (XII) (cf. claims 6 and 10),

    摘要翻译: (Het)具有亚氨基功能的芳基磺酰脲,它们的制备及其作为除草剂和植物生长调节剂的用途式(I)化合物及其盐,其中A是通过直接连接到基团SO 2上的(杂)芳族或杂环桥 或通过O,S,NH,CH 2或通过烷基化NH或烷基化亚甲基,B是具有亚氨基的片段N = CN,N = CS,N = CO或N = CC的基团,其通过 所述片段的氮原子之一R = H或脂族基,W = O或S和X,Y和Z如权利要求1中所定义,适合作为除草剂和植物生长调节剂。 通过式(XII)的新型中间体(参见权利要求6和10)类似于已知方法进行制备,