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公开(公告)号：US20100252730A1
公开(公告)日：2010-10-07
申请号：US12668813
申请日：2008-07-14
CPC分类号： H01J49/4205 , H01J49/02 , H01J49/4225
摘要： A mass spectrometer is disclosed comprising a quadrupole rod set ion trap (2, 3) wherein a potential field is created at the exit of the ion trap (4, 5) which decreases with increasing radius in one radial direction. Ions within the ion trap (2, 3) are mass selectively excited in a radial direction. Ions which have been excited in the radial direction experience a potential field which no longer confines the ions axially within the ion trap but which instead acts to extract the ions and hence causes the ions to be ejected axially from the ion trap (2, 3).
摘要翻译： 公开了一种质谱仪，其包括四极杆组离子阱（2,3），其中在离子阱（4,5）的出口产生一个电势场，该离子阱在一个径向方向上随着半径的增加而减小。 离子阱（2,3）内的离子质量选择性地沿径向激发。 已经在径向方向被激发的离子经历了不再将离子轴向限定在离子阱内的势场，而是作用于提取离子并因此导致离子从离子阱（2,3）轴向地排出， 。
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公开(公告)号：US08426803B2
公开(公告)日：2013-04-23
申请号：US12668813
申请日：2008-07-14
CPC分类号： H01J49/4205 , H01J49/02 , H01J49/4225
摘要： A mass spectrometer is disclosed comprising a quadrupole rod set ion trap wherein a potential field is created at the exit of the ion trap which decreases with increasing radius in one radial direction. Ions within the ion trap are mass selectively excited in a radial direction. Ions which have been excited in the radial direction experience a potential field which no longer confines the ions axially within the ion trap but which instead acts to extract the ions and hence causes the ions to be ejected axially from the ion trap.
摘要翻译： 公开了一种质谱仪，其包括四极杆组离子阱，其中在一个径向方向上随半径增加而在离子阱的出口产生电势场。 离子阱内的离子质量选择性地沿径向激发。 已经在径向方向被激发的离子经历了不再将离子轴向限定在离子阱内的势场，而是作用于提取离子并因此导致离子从离子阱轴向喷出。
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公开(公告)号：US20110049358A1
公开(公告)日：2011-03-03
申请号：US12812342
申请日：2009-01-12
IPC分类号： H01J49/00
CPC分类号： H01J49/4225 , H01J49/4285
摘要： A linear ion trap (6,7,8)is disclosed comprising a central quadrupole rod set (6)and a post-filter quadrupole rod set (8). A 180° phase difference is maintained between axially adjacent rod electrodes of the central quadrupole rod set (6) and the post-filter quadrupole (8) so that an axial pseudo-potential barrier is created between the central quadrupole rod set (6) and the post-filter quadrupole (8). A supplementary AC voltage is applied to the rods of the central quadrupole (6) in order to radially excite ions which are desired to be ejected from the ion trap. The ions are ejected from the ion trap (6,7,8) non-adiabatically in an axial direction.
摘要翻译： 公开了一种线性离子阱（6,7,8），其包括中心四极杆组（6）和后过滤四极杆组（8）。 在中心四极杆组（6）和后过滤器四极（8）的轴向相邻杆电极之间保持180°相位差，使得在中心四极杆组（6）和 后滤器四极杆（8）。 向中心四极杆（6）的杆施加补充的交流电压，以便径向地激发希望从离子阱排出的离子。 离子从离子阱（6,7,8）沿轴向非绝热地排出。
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公开(公告)号：US08212208B2
公开(公告)日：2012-07-03
申请号：US12812342
申请日：2009-01-12
CPC分类号： H01J49/4225 , H01J49/4285
摘要： A linear ion trap (6, 7, 8)is disclosed comprising a central quadrupole rod set (6)and a post-filter quadrupole rod set (8). A 180° phase difference is maintained between axially adjacent rod electrodes of the central quadrupole rod set (6) and the post-filter quadrupole (8) so that an axial pseudo-potential barrier is created between the central quadrupole rod set (6) and the post-filter quadrupole (8). A supplementary AC voltage is applied to the rods of the central quadrupole (6) in order to radially excite ions which are desired to be ejected from the ion trap. The ions are ejected from the ion trap (6, 7, 8) non-adiabatically in an axial direction.
摘要翻译： 公开了一种线性离子阱（6,7,8），其包括中心四极杆组（6）和后过滤器四极杆组（8）。 在中心四极杆组（6）和后过滤器四极（8）的轴向相邻杆电极之间保持180°相位差，使得在中心四极杆组（6）和 后滤器四极杆（8）。 向中心四极杆（6）的杆施加补充的交流电压，以便径向地激发希望从离子阱排出的离子。 离子从离子阱（6,7,8）沿轴向非绝热地喷出。
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公开(公告)号：US20100148056A1
公开(公告)日：2010-06-17
申请号：US12516610
申请日：2007-12-14
IPC分类号： H01J49/40
CPC分类号： H01J49/401
摘要： A mass spectrometer is disclosed comprising an orthogonal acceleration Time of Flight mass analyser. A pulse or packet of ions is released either from an ion trap (7) or alternatively from a travelling wave ion guide arranged upstream of an orthogonal acceleration electrode (2) which forms part of the Time of Flight mass analyser. Ions in the pulse or packet of ions which is released become temporally dispersed and the orthogonal acceleration electrode (2) is energised multiple times prior the release of a subsequent pulse or packet of ions.
摘要翻译： 公开了一种质谱仪，其包括正交加速时间飞行质量分析器。 从离子阱（7）或替代地从布置在作为飞行时间质量分析器的一部分的正交加速电极（2）的上游的行波离子导向器释放脉冲或包离子。 释放的脉冲或离子束中的离子变得暂时分散，并且在随后的脉冲或包离子的释放之前，正交加速电极（2）被多次通电。
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公开(公告)号：US07919747B2
公开(公告)日：2011-04-05
申请号：US12297481
申请日：2007-04-30
CPC分类号： H01J49/065 , H01J49/0031 , H01J49/022 , H01J49/062 , H01J49/36 , H01J49/4235 , Y10T436/24
摘要： An ion guide or mass analyser (2) is disclosed comprising a plurality of electrodes (2a) having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser (2). The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages (4) are applied to the electrodes (2a) of the ion guide or mass analyser (2) in order to urge ions along the length of the ion guides or mass analyser (2). The amplitude of the transient DC voltage (4) applied to the electrode (2a) may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser (2) in reverse order of their mass to charge ratio.
摘要翻译： 公开了一种离子导向器或质量分析器（2），其包括具有孔的多个电极（2a），在使用中通过该孔具有离子。 在离子导向器或质量分析器（2）的出口处产生伪势垒。 伪势垒的幅度或深度与离子的质荷比成反比。 一个或多个瞬态DC电压（4）被施加到离子导向器或质量分析器（2）的电极（2a），以促使沿着离子导向器或质量分析器（2）的长度的离子。 施加到电极（2a）的瞬态直流电压（4）的振幅可以随时间增加，从而离子引导或质量分析器（2）以与其质荷比相反的顺序发射离子。
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公开(公告)号：US08633435B2
公开(公告)日：2014-01-21
申请号：US12445774
申请日：2007-10-16
申请人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
发明人： Daniel James Kenny , Robert Harold Bateman , Martin Green , Jason Lee Wildgoose , Steven Derek Pringle
CPC分类号： H01J49/005 , H01J49/0031 , H01J49/004 , H01J49/0045 , H01J49/065 , H01J49/34 , H01J49/4235
摘要： A collision or fragmentation cell is disclosed comprising a plurality of electrodes wherein a first RF voltage is applied to an upstream group of electrodes and a second different RF voltage is applied to a downstream group of electrodes. The radial confinement of parent ions entering the collision or fragmentation cell is optimized by the first RF voltage applied to the upstream group of electrodes and the radial confinement of daughter or fragment ions produced within the collision or fragmentation cell is optimized by the second different RF voltage applied to the downstream group of electrodes.
摘要翻译： 公开了包括多个电极的碰撞或分裂单元，其中将第一RF电压施加到上游电极组，并且将第二不同的RF电压施加到下游电极组。 通过施加到上游电极组的第一RF电压来优化进入碰撞或破碎电池的母体离子的径向约束，并且通过第二不同RF电压优化在碰撞或断裂电池内产生的子或碎片离子的径向约束 应用于下游电极组。
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8.发明授权Mass spectrometer device and method using scanned phase applied potentials in ion guidance 有权离子引导中使用扫描相应用电位的质谱仪装置和方法公开(公告)号：US08455819B2
公开(公告)日：2013-06-04
申请号：US13078198
申请日：2011-04-01
CPC分类号： H01J49/065 , H01J49/0031 , H01J49/022 , H01J49/062 , H01J49/36 , H01J49/4235 , Y10T436/24
摘要： An ion guide or mass analyser is disclosed comprising a plurality of electrodes having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser. The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages are applied to the electrodes of the ion guide or mass analyser in order to urge ions along the length of the ion guides or mass analyser. The amplitude of the transient DC voltage applied to the electrode may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser in reverse order of their mass to charge ratio.
摘要翻译： 公开了一种离子导向器或质量分析器，其包括具有孔的多个电极，在使用中离子传播通过该孔。 在离子导向器或质量分析器的出口处产生伪势垒。 伪势垒的幅度或深度与离子的质荷比成反比。 一个或多个瞬态直流电压被施加到离子导向器或质量分析器的电极，以沿着离子导向器或质量分析器的长度推动离子。 施加到电极的瞬态直流电压的幅度可以随时间增加，使得离子从离子导向器或质量分析器以其质荷比的相反顺序被发射。
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公开(公告)号：US08183524B2
公开(公告)日：2012-05-22
申请号：US12516610
申请日：2007-12-14
IPC分类号： H01J49/00
CPC分类号： H01J49/401
摘要： A mass spectrometer is disclosed comprising an orthogonal acceleration Time of Flight mass analyser. A pulse or packet of ions is released either from an ion trap or alternatively from a travelling wave ion guide arranged upstream of an orthogonal acceleration electrode which forms part of the Time of Flight mass analyser. Ions in the pulse or packet or ions which is released become temporally dispersed and the orthogonal acceleration electrode is energized multiple times prior the release of a subsequent pulse or packet of ions.
摘要翻译： 公开了一种质谱仪，其包括正交加速时间飞行质量分析器。 离子的脉冲或分组从离子阱或者替代地布置在构成飞行时间质量分析器的一部分的正交加速电极的上游的行波离子导向器释放。 释放的脉冲或包或离子中的离子变得暂时分散，并且在随后的脉冲或包离子的释放之前，正交加速电极被多次通电。
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公开(公告)号：US20110180704A1
公开(公告)日：2011-07-28
申请号：US13078198
申请日：2011-04-01
CPC分类号： H01J49/065 , H01J49/0031 , H01J49/022 , H01J49/062 , H01J49/36 , H01J49/4235 , Y10T436/24
摘要： An ion guide or mass analyser is disclosed comprising a plurality of electrodes having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser. The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages are applied to the electrodes of the ion guide or mass analyser in order to urge ions along the length of the ion guides or mass analyser. The amplitude of the transient DC voltage applied to the electrode may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser in reverse order of their mass to charge ratio.
摘要翻译： 公开了一种离子导向器或质量分析器，其包括具有孔的多个电极，在使用中离子传播通过该孔。 在离子导向器或质量分析器的出口处产生伪势垒。 伪势垒的幅度或深度与离子的质荷比成反比。 一个或多个瞬态直流电压被施加到离子导向器或质量分析器的电极，以沿着离子导向器或质量分析器的长度推动离子。 施加到电极的瞬态直流电压的幅度可以随时间增加，使得离子从离子导向器或质量分析器以其质荷比的相反顺序被发射。
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