公开(公告)号：US5728790A

公开(公告)日：1998-03-17

申请号：US510848

申请日：1995-08-03

申请人： Masashi Seki ,  Eiichi Kawasaki ,  Takayoshi Sekido ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Kousuke Suewaka

发明人： Masashi Seki ,  Eiichi Kawasaki ,  Takayoshi Sekido ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Kousuke Suewaka

IPC分类号： C08L73/02 ,  C09D133/06 ,  C08F224/00 ,  B05D1/06 ,  B32B15/16 ,  C08F212/08 ,  C08F222/02 ,  C08F226/02

CPC分类号： C09D133/068 ,  C08L73/02 ,  Y10T428/24

摘要： The present invention relates to a thermosetting powder paint comprising, as essential components, (A) a copolymer of particular composition composed of a glycidyl group-containing monomer, styrene and other monomer copolymerizable therewith and, as curing agents capable of reacting with the component (A) to crosslink the component (A), (B) an aliphatic polycarboxylic acid and (C) a linear anhydride of an aliphatic polycarboxylic acid; a coating method using the above thermosetting powder paint; and a coated article obtained by using the above thermosetting powder paint. The above thermosetting powder paint, when used as a paint for automobile, has excellent storage stability and gives a coating film having excellent appearance, properties, weathering resistance and yellowing resistance; therefore, the paint can be favorably used particularly as an top coat and an intermediate coat for automobile and its parts.

摘要翻译： 本发明涉及一种热固性粉末涂料，其包含作为必要组分的（A）由含缩水甘油基的单体，苯乙烯和可与其共聚的其它单体组成的特定组成的共聚物，以及作为能够与组分反应的固化剂 A）使组分（A），（B）脂族多元羧酸和（C）脂族多元羧酸的直链酸酐交联; 使用上述热固性粉末涂料的涂布方法; 和通过使用上述热固性粉末涂料获得的涂布制品。 上述热固性粉末涂料在用作汽车涂料时具有优异的储存稳定性，并且具有优异的外观，性能，耐候性和耐黄变性的涂膜。 因此，该涂料可以特别用作汽车及其部件的顶涂层和中间涂层。

公开(公告)号：US6008301A

公开(公告)日：1999-12-28

申请号：US969760

申请日：1997-11-13

申请人： Takahisa Miyawaki ,  Tsuyoshi Matsumoto ,  Mitsuyuki Mizoguchi ,  Masashi Seki ,  Eiichi Kawasaki

发明人： Takahisa Miyawaki ,  Tsuyoshi Matsumoto ,  Mitsuyuki Mizoguchi ,  Masashi Seki ,  Eiichi Kawasaki

IPC分类号： C08L73/02 ,  C09D133/06 ,  C08F8/14

CPC分类号： C09D133/068 ,  C08L73/02

摘要： A thermosetting powder paint composition is disclosed which can realize simultaneous manifestation of I) excellent stability before film forming (in storage), II) excellent low temperature melting property/low temperature curing property in forming a film, and III) excellent film properties and physical properties after film forming;and which comprises (A) a copolymer component which is obtained by radical polymerization in a reaction system containing (a-1) an ethylenically unsaturated monomer having a glycidyl group and a unsaturated double bond in the molecule, (a-2) styrene, and (a-3) the other monomer in a specific condition, (B) a curing agent component which is a linear acid anhydride of an aliphatic divalent carboxylic acid having a specific structure, and (C) a curing catalyst component having a specific structure.

摘要翻译： 公开了可以实现I）在成膜（储存）之前优异的稳定性的同时表现的热固性粉末涂料组合物，II）在形成膜时具有优异的低温熔融性/低温固化性，以及III）优异的膜性能和物理性 成膜后的性能; （A-1）在分子中含有缩水甘油基和不饱和双键的烯键式不饱和单体（a-2）苯乙烯，和（A-1）共聚物成分， （a-3）特定条件下的其它单体，（B）作为具有特定结构的脂肪族二元羧酸的线性酸酐的固化剂成分，（C）具有特定结构的固化催化剂成分。

公开(公告)号：US6084009A

公开(公告)日：2000-07-04

申请号：US839104

申请日：1997-04-23

申请人： Mitsuyuki Mizoguchi ,  Yoshiro Fuseya ,  Yoshihiro Fujita ,  Yukiatsu Ishino ,  Masashi Seki ,  Takahisa Miyawaki

发明人： Mitsuyuki Mizoguchi ,  Yoshiro Fuseya ,  Yoshihiro Fujita ,  Yukiatsu Ishino ,  Masashi Seki ,  Takahisa Miyawaki

IPC分类号： C08L51/04 ,  C09D133/06 ,  C08L33/00

CPC分类号： C09D133/068 ,  C08L51/04 ,  Y10S524/904 ,  Y10S525/902 ,  Y10S525/934

摘要： A thermosetting powder paint composition comprising:(A) a (meth)acrylic copolymer having glycidyl groups;(B) a polybasic carboxylic acid and/or polybasic carboxylic anhydride; and(C) particles having a core/shell structure each comprising a core having Tg of 20.degree. C. or below, the core being covered at least partially with a shell having Tg of 40.degree. C. or above, and said shell having no glycidyl group.The paint composition is excellent in weather resistance as well as in impact resistance and chipping resistance.

摘要翻译： 一种热固性粉末涂料组合物，其包含：（A）具有缩水甘油基的（甲基）丙烯酸共聚物; （B）多元羧酸和/或多元羧酸酐; 和（C）具有核/壳结构的颗粒，每个颗粒包含Tg为20℃或更低的芯，所述芯至少部分地被Tg覆盖在40℃以上的壳体上，并且所述壳体没有 缩水甘油基。 涂料组合物的耐候性以及耐冲击性和耐崩裂性优异。

公开(公告)号：US06388012B1

公开(公告)日：2002-05-14

申请号：US09543089

申请日：2000-04-04

申请人： Hiroyuki Sakayama ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Tsuyoshi Matsumoto

发明人： Hiroyuki Sakayama ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Tsuyoshi Matsumoto

IPC分类号： C08L2300

CPC分类号： C09D5/037

摘要： A thermosetting powder paint composition comprising (A) a resin composition component, (B) a hardener component and (C) a solid flow controlling component, wherein the component (A) contains a resin composition component having reactivity with the component (B), the component (B) contains a hardener having reactivity with the component (A), the component (C) contains a vinyl polymer which is solid at 20° C., and the relation between SPA of the component (A) and SPC of the component (C) satisfies the following numerical formula (1) and the following numerical formula (2) simultaneously. By this constitution, excellent blocking-resistance in storing as the powder paint composition and excellent appearance properties of a paint film formed by coating the powder paint composition can be simultaneously manifested. 8≦SPA≦13  (1) 7≦SPC≦SPA  (2).

摘要翻译： 一种热固性粉末涂料组合物，其包含（A）树脂组合物组分，（B）固化剂组分和（C）固体流动控制组分，其中组分（A）含有与组分（B）具有反应性的树脂组合物组分， 组分（B）含有与组分（A）具有反应性的固化剂，组分（C）含有在20℃下为固体的乙烯基聚合物，组分（A）的SPA与SPC之间的关系 组分（C）同时满足以下数学式（1）和以下数值式（2）。 通过这种结构，可以同时表现出通过涂覆粉末涂料组合物形成的涂膜作为粉末涂料组合物的优异的耐粘连性和优异的外观性能。

公开(公告)号：US06333380B1

公开(公告)日：2001-12-25

申请号：US09495895

申请日：2000-02-02

申请人： Hiroyuki Sakayama ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Tsuyoshi Matsumoto

发明人： Hiroyuki Sakayama ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Takahisa Miyawaki ,  Tsuyoshi Matsumoto

IPC分类号： C08G6348

CPC分类号： C08G81/021

摘要： There are disclosed a thermosetting resin composition for a powder paint in which a resin composition component (A) is a (block) copolymer obtained by allowing a vinyl-based polymer G (branch) block (component (a-1)) to graft-react with a vinyl-based polymer S (back bone) block (component (a-2)), and if the solubility parameters of the components (a-1) and (a-2) are represented by SPG and SPG, respectively, SPG and SPS satisfy the following numerical formula (I), and a thermosetting powder paint composition comprising a resin composition component (A) and a hardener composition component (B) wherein the component (A) is said thermosetting resin composition for a powder paint. By these compositions, a thermosetting powder paint composition having excellent storage stabilities, appearance properties, physical properties and chemical properties can be provided. Particularly, there can be provided a thermosetting powder paint composition suitably applied to painting of bodies of vehicles such as automobiles and parts of vehicles such as automobiles (aluminum wheel, wiper, pillar, door handle, fender, bonnet, air spoiler, stabilizer, front grill and the like), particularly, to top painting. SPG

摘要翻译： 公开了一种粉末涂料用热固性树脂组合物，其中树脂组合物组分（A）是通过使乙烯基类聚合物G（分支）嵌段（组分（a-1））接枝而获得的（嵌段）共聚物， 与乙烯基类聚合物S（背面骨）嵌段（成分（a-2））反应，如果成分（a-1）和（a-2）的溶解度参数分别用SPG和SPG表示， SPG和SPS满足以下数值式（I），和包含树脂组合物组分（A）和硬化剂组合物组分（B）的热固性粉末涂料组合物，其中组分（A）是所述粉末涂料用热固性树脂组合物。 通过这些组合物，可以提供具有优异的储存稳定性，外观性质，物理性质和化学性质的热固性粉末涂料组合物。 特别地，可以提供一种适用于汽车，汽车等车辆（铝轮，刮水器，支柱，门把手，挡泥板，发动机罩，空气扰流板，稳定器，前部等）的车体的涂装的热固性粉末涂料组合物 格栅等），特别是顶画。

公开(公告)号：US6121378A

公开(公告)日：2000-09-19

申请号：US136290

申请日：1998-08-19

申请人： Takahisa Miyawaki ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Hiroyuki Sakayama ,  Tsuyoshi Matsumoto

发明人： Takahisa Miyawaki ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Hiroyuki Sakayama ,  Tsuyoshi Matsumoto

IPC分类号： C08L83/04 ,  C09D133/06 ,  C08F8/00

CPC分类号： C09D133/068 ,  C08L83/04

摘要： A thermosetting powder paint composition for top coating excellent in weather resistance and storage stability, which comprising 100 parts by weight of an acrylic copolymer (A) having an epoxy group, and 0.01 to 2.0 parts by weight of an organic modified polysiloxane (B) containing at least one functional group, at least two silicon atoms and no radical-polymerizable unsaturated bond wherein the component (B) is contained in the condition that a part or all thereof has reacted and bonded with the component (A) or the component (C), or all thereof has not reacted with them.

摘要翻译： 包含100重量份具有环氧基的丙烯酸共聚物（A）和0.01〜2.0重量份含有有机改性聚硅氧烷（B）的耐候性和保存稳定性优异的顶涂层用热固性粉末涂料组合物，其含有 至少一个官能团，至少两个硅原子和无自由基聚合性不饱和键，其中组分（B）的一部分或全部与组分（A）或组分（C ），或其全部未与其反应。

公开(公告)号：US06359067B1

公开(公告)日：2002-03-19

申请号：US09446660

申请日：1999-12-23

申请人： Takahisa Miyawaki ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Hiroyuki Sakayama ,  Tsuyoshi Matsumoto

发明人： Takahisa Miyawaki ,  Yoshio Kikuta ,  Mitsuyuki Mizoguchi ,  Hiroyuki Sakayama ,  Tsuyoshi Matsumoto

IPC分类号： C08L5300

CPC分类号： C09D153/025 ,  C08L51/06 ,  C08L53/00 ,  C09D133/04 ,  C09D151/003 ,  C09D151/006 ,  C08L2666/24 ,  C08L2666/02

摘要： A thermosetting powder coating composition which comprises a resin composition (A) having a sea-island type microphase separation structure constituted of a continuous phase (a sea phase) comprising an acrylic copolymer and a dispersion phase (an island phase) comprising a thermoplastic elastomer and a curing agent (B) and in which the total amount of a thermosetting elastomer (a-2) constituting the dispersion phase is in the range of 0.5 to 20 parts by weight with respect to 100 parts by weight of the resin composition (A). This powder coating composition is excellent in chipping resistance, impact resistance, weathering resistance and appearance properties, and it is particularly suitable for the coating of vehicles.

摘要翻译： 一种热固性粉末涂料组合物，其包含具有由包含丙烯酸共聚物的连续相（海相）和包含热塑性弹性体的分散相（岛相）构成的海岛型微相分离结构的树脂组合物（A） 固化剂（B），其中构成分散相的热固性弹性体（a-2）的总量相对于树脂组合物（A）100重量份为0.5〜20重量份， 。 该粉末涂料组合物的耐崩裂性，耐冲击性，耐候性和外观性能优异，特别适用于车辆涂料。

公开(公告)号：US06762259B2

公开(公告)日：2004-07-13

申请号：US10149381

申请日：2002-06-12

申请人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

发明人： Tadahito Nobori ,  Katsuhiko Funaki ,  Atsushi Shibahara ,  Makoto Suzuki ,  Kazumi Mizutani ,  Hiromi Jouyama ,  Isao Hara ,  Takaomi Hayashi ,  Shinji Kiyono ,  Setsuko Fujiyoshi ,  Hiroyuki Sakayama ,  Mitsuyuki Mizoguchi ,  Tsuyoshi Matsumoto ,  Yoshiharu Hirose

IPC分类号： C08F446

CPC分类号： C09D129/12 ,  C08F2/38 ,  C08F4/00 ,  C09D125/00 ,  C09D133/04 ,  C09D135/06 ,  C09D139/00

摘要： The purpose of the present invention is to provide polymerization catalyst which can produce quite efficiently (co)polymer having number average molecular weight and number of molecules which are accurately controlled in producing method of (co)polymer by the polymerization of polar unsaturated compound, and provide living polymerized (co)polymer obtained according to the producing method. For the purpose, polymerization catalyst composition which comprises the composition comprising organic oxysalt compound and hydroxycarbonyl compound having at least both an alcoholic hydroxyl group and a carbonyl group in the same molecule is provided and the polar unsaturated compound is polymerized by using the polymerization catalyst composition. The composition containing the obtained (co)polymer were able to provide thermosetting powder coating composition having particularly excellent characteristics.

摘要翻译： 本发明的目的是提供聚合催化剂，其可以产生具有数均分子量和分子数的非常有效的（共）聚合物，其通过极性不饱和化合物的聚合制备（共）聚合物的方法被精确控制，以及 提供根据制造方法获得的活性聚合（共）聚合物。 为此，提供了包含含有有机氧化锡化合物和在同一分子中至少具有醇羟基和羰基两者的羟基羰基化合物的组合物的聚合催化剂组合物，并且通过使用聚合催化剂组合物聚合极性不饱和化合物。 含有所得（共）聚合物的组合物能够提供具有特别优异特性的热固性粉末涂料组合物。

公开(公告)号：US06875815B2

公开(公告)日：2005-04-05

申请号：US10445830

申请日：2003-05-28

申请人： Mitsuyuki Mizoguchi ,  Yoshiharu Hirose

发明人： Mitsuyuki Mizoguchi ,  Yoshiharu Hirose

IPC分类号： C08G59/42 ,  C09D5/03 ,  C09D125/08 ,  C09D129/00 ,  C09D133/14 ,  C09D135/00 ,  C09D163/00 ,  C08F8/00 ,  C08L25/02 ,  C08L37/00

CPC分类号： C09D163/00 ,  C08L2666/04

摘要： Disclosed is a thermosetting powder coating composition comprising (A) a glycidyl group-containing acrylic resin obtained by (co)polymerizing monomers containing an ethylenically unsaturated monomer having a glycidyl group and/or a β-methylglycidyl group, (B) a polycarboxyl curative, and (C) an alcohol adduct of a styrene/maleic anhydride copolymer. Also disclosed are a cross-linked cured film of the composition and a process for preparing the composition. According to the invention, blending efficiency and dispersibility of the components of a powder coating, particularly those between the resin component and the curative component, are improved without changing a conventional production process of a powder coating, i.e., a process consisting of melt blending, cooling solidification, pulverization and sieving, and thereby a thermosetting powder coating composition, which is capable of forming a cross-linked cured film improved in appearance properties (high gloss, etc.), physical properties (hardness, scratch/mar resistance, etc.), and chemical properties (acid resistance, solvent resistance, etc.), particularly in scratch/mar resistance and/or chemical properties, and having a 60° gloss value of not less than 80, and which is favorably used for coating of automotive bodies and automotive parts, can be provided.

摘要翻译： 公开了一种热固性粉末涂料组合物，其包含（A）通过（共）聚合含有具有缩水甘油基和/或β-甲基缩水甘油基的烯属不饱和单体的单体获得的含缩水甘油基的丙烯酸树脂，（B）聚羧基固化剂， 和（C）苯乙烯/马来酸酐共聚物的醇加成物。 还公开了组合物的交联固化膜和制备该组合物的方法。 根据本发明，粉末涂料的组分的混合效率和分散性，特别是树脂组分和固化剂组分之间的组分的混合效率和分散性得到改善，而不改变常规的粉末涂料的生产方法，即熔融共混， 冷却固化，粉碎和筛分，从而可以形成改善外观性能（高光泽度等），物理性能（硬度，耐擦伤/耐擦伤性等）的交联固化膜的热固性粉末涂料组合物 ），化学性质（耐酸性，耐溶剂性等），特别是耐划痕/耐擦伤性和/或化学性质，并且具有不小于80°的60°光泽值，并且其有利地用于汽车涂料 可以提供车身和汽车零件。