公开(公告)号：US20180072665A1

公开(公告)日：2018-03-15

申请号：US15563276

申请日：2016-03-24

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Toshikatsu Kojima ,  Hiroyuki Kageyama

IPC: C07C381/00 ,  H01M4/60 ,  C01B32/70 ,  H01M10/0525 ,  H01M10/0562 ,  C08L71/02

Abstract: The present invention provides an organic sulfur material comprising carbon, hydrogen, and sulfur as constituent elements, and having peaks in the vicinity of 480 cm−1, 1250 cm−1, 1440 cm−1, and 1900 cm−1 in a Raman spectrum detected by Raman spectroscopy. The peak in the vicinity of 1440 cm−1 is the most intense peak. This organic sulfur material, which is produced by using a liquid organic starting material, achieves high capacity. This organic sulfur material preferably does not have peaks in the vicinity of 846 cm−1 or 1066 cm−1.

公开(公告)号：US10710960B2

公开(公告)日：2020-07-14

申请号：US15563276

申请日：2016-03-24

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Toshikatsu Kojima ,  Hiroyuki Kageyama

IPC: C07C381/00 ,  C01B32/70 ,  H01M10/052 ,  C01B32/75 ,  H01M4/36 ,  H01M4/62 ,  H01M4/38 ,  H01M4/58 ,  C01B17/00 ,  H01M4/60 ,  H01M10/0562 ,  C08L71/02 ,  H01M10/0525 ,  G01N21/65

Abstract: The present invention provides an organic sulfur material comprising carbon, hydrogen, and sulfur as constituent elements, and having peaks in the vicinity of 480 cm−1, 1250 cm−1, 1440 cm−1, and 1900 cm−1 in a Raman spectrum detected by Raman spectroscopy. The peak in the vicinity of 1440 cm−1 is the most intense peak. This organic sulfur material, which is produced by using a liquid organic starting material, achieves high capacity. This organic sulfur material preferably does not have peaks in the vicinity of 846 cm−1 or 1066 cm−1.

公开(公告)号：US20160268606A1

公开(公告)日：2016-09-15

申请号：US15021041

申请日：2014-09-10

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Tomonari Takeuchi ,  Atsushi Sakuda ,  Hiroyuki Kageyama ,  Hikari Sakaebe ,  Kuniaki Tatsumi

IPC: H01M4/58 ,  H01M10/0525 ,  H01M10/0562 ,  H01M4/1397 ,  H01M10/44 ,  H01M4/04 ,  H01M4/136 ,  H01M4/38 ,  H01M10/058

CPC classification number: H01M4/5815 ,  C01B17/22 ,  C01G49/009 ,  C01P2002/72 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/0433 ,  H01M4/0445 ,  H01M4/136 ,  H01M4/1397 ,  H01M4/364 ,  H01M4/38 ,  H01M4/58 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/058 ,  H01M10/446 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2220/20 ,  H01M2220/30 ,  H01M2300/0065 ,  H01M2300/0068 ,  Y02T10/7011

Abstract: The main object is to provide a novel material with excellent charge and discharge characteristics, such as a high utilization rate of a positive electrode, a high capacity, and good cycle characteristic, in which the material is a compound containing as the major component lithium sulfide useful as a cathode active material for lithium secondary batteries. The invention provides a lithium sulfide-iron-carbon composite containing lithium, iron, sulfur and carbon as constituent elements, with lithium sulfide (Li2S), as the main phase, having a crystallite size of 50 nm or less as calculated from the half width of the diffraction peak based on the (111) plane of Li2S as determined by X-ray powder diffraction.

Abstract translation: 主要目的是提供一种具有优异的充放电特性的新型材料，例如正极的高利用率，高容量和良好的循环特性，其中该材料是含有主要组分的硫化锂 可用作锂二次电池的正极活性物质。 本发明提供一种以锂，铁，硫和碳为组成元素的硫化锂 - 铁 - 碳复合材料，其中以硫化锂（Li2S）为主相，其半峰宽为50nm以下，微晶尺寸为50nm以下 基于通过X射线粉末衍射测定的Li 2 S的（111）面的衍射峰。

公开(公告)号：US10290870B2

公开(公告)日：2019-05-14

申请号：US15021041

申请日：2014-09-10

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Atsushi Sakuda ,  Hiroyuki Kageyama ,  Hikari Sakaebe ,  Kuniaki Tatsumi

IPC: H01M4/58 ,  H01M4/38 ,  H01M10/0525 ,  H01M10/0562 ,  H01M4/1397 ,  H01M4/36 ,  H01M4/04 ,  H01M4/136 ,  H01M10/058 ,  H01M10/44 ,  C01B17/22 ,  C01G49/00 ,  H01M4/02

Abstract: The main object is to provide a novel material with excellent charge and discharge characteristics, such as a high utilization rate of a positive electrode, a high capacity, and good cycle characteristic, in which the material is a compound containing as the major component lithium sulfide useful as a cathode active material for lithium secondary batteries. The invention provides a lithium sulfide-iron-carbon composite containing lithium, iron, sulfur and carbon as constituent elements, with lithium sulfide (Li2S), as the main phase, having a crystallite size of 50 nm or less as calculated from the half width of the diffraction peak based on the (111) plane of Li2S as determined by X-ray powder diffraction.

公开(公告)号：US20180006298A1

公开(公告)日：2018-01-04

申请号：US15527185

申请日：2015-11-18

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Hiroyuki Kageyama ,  Atsushi Sakuda ,  Hikari Sakaebe

IPC: H01M4/36 ,  H01M4/583 ,  H01M4/38 ,  C01G49/12 ,  H01M4/136 ,  H01M4/134 ,  H01M10/0525 ,  H01M4/58

CPC classification number: H01M4/364 ,  C01B17/22 ,  C01G49/00 ,  C01G49/12 ,  H01M4/134 ,  H01M4/136 ,  H01M4/36 ,  H01M4/38 ,  H01M4/58 ,  H01M4/5815 ,  H01M4/583 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0562 ,  H01M10/0565 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

Abstract: A composite containing phosphorus, lithium, iron, sulfur, and carbon as constituent elements wherein lithium sulfide (Li2S) is present in an amount of 90 mol % or more, and wherein the crystallite size calculated from the half-width of a diffraction peak based on the (111) plane of Li2S as determined by X-ray powder diffraction measurement is 80 nm or less. The composite exhibits a high capacity (in particular, a high discharge capacity) useful as an electrode active material for a lithium-ion secondary battery (in particular, a cathode active material for a lithium-ion secondary battery), without the need for stepwise pre-cycling treatment.

公开(公告)号：US08979974B2

公开(公告)日：2015-03-17

申请号：US13923740

申请日：2013-06-21

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Katsuhiro Nomura ,  Hiroyuki Kageyama ,  Masakazu Date ,  Tadahiro Fujitani

IPC: C22B7/00 ,  C22B1/00 ,  C22B11/00 ,  C22B34/34 ,  C22B59/00 ,  C22C16/00 ,  C22C28/00 ,  C22B3/00 ,  C22B34/36 ,  C22B3/24 ,  C22B7/02

CPC classification number: C22B1/005 ,  C22B3/24 ,  C22B7/007 ,  C22B7/009 ,  C22B7/02 ,  C22B11/042 ,  C22B11/048 ,  C22B34/34 ,  C22B34/36 ,  C22B59/00 ,  C22C16/00 ,  C22C28/00 ,  Y02P10/214 ,  Y02P10/234

Abstract: The present invention provides a composition for collecting a metal component from a metal component-containing material, the composition containing a compound containing at least one element selected from the group consisting of lanthanoid elements and elements in group 2 of the periodic table, and a compound containing at least one element selected from the group consisting of elements in groups 3, 4, 12, and 13 of the periodic table and transition metal elements in the 4th period of the periodic table. The present invention further provides a method for collecting a metal component using this composition. With the use of the composition of the present invention, a metal component can be easily and efficiently collected from a material containing a highly useful metal component such as noble or rare metal.

Abstract translation: 本发明提供一种用于从含金属成分的材料收集金属成分的组合物，该组合物含有含有选自元素周期表第2族中的镧系元素和元素中的至少一种元素的化合物和化合物 含有选自元素周期表第3,4,12族元素中的至少一种元素和周期表第4周期中的过渡金属元素。 本发明还提供使用该组合物收集金属成分的方法。 通过使用本发明的组合物，可以从含有贵金属或稀有金属等高度有用的金属成分的材料容易且有效地收集金属成分。

公开(公告)号：US10367196B2

公开(公告)日：2019-07-30

申请号：US15527185

申请日：2015-11-18

Applicant: National Institute of Advanced Industrial Science and Technology

Inventor： Tomonari Takeuchi ,  Hiroyuki Kageyama ,  Atsushi Sakuda ,  Hikari Sakaebe

IPC: H01M4/36 ,  C01G49/00 ,  C01B17/22 ,  H01M4/58 ,  H01M10/052 ,  H01M10/0562 ,  H01M10/0565 ,  C01G49/12 ,  H01M4/134 ,  H01M4/136 ,  H01M4/38 ,  H01M4/583 ,  H01M10/0525

Abstract: A composite containing phosphorus, lithium, iron, sulfur, and carbon as constituent elements wherein lithium sulfide (Li2S) is present in an amount of 90 mol % or more, and wherein the crystallite size calculated from the half-width of a diffraction peak based on the (111) plane of Li2S as determined by X-ray powder diffraction measurement is 80 nm or less. The composite exhibits a high capacity (in particular, a high discharge capacity) useful as an electrode active material for a lithium-ion secondary battery (in particular, a cathode active material for a lithium-ion secondary battery), without the need for stepwise pre-cycling treatment.

公开(公告)号：US20130283978A1

公开(公告)日：2013-10-31

申请号：US13923740

申请日：2013-06-21

Applicant: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

Inventor： Katsuhiro Nomura ,  Hiroyuki Kageyama ,  Masakazu Date ,  Tadahiro Fujitani

IPC: C22B59/00 ,  C22B3/00 ,  C22B1/00

CPC classification number: C22B1/005 ,  C22B3/24 ,  C22B7/007 ,  C22B7/009 ,  C22B7/02 ,  C22B11/042 ,  C22B11/048 ,  C22B34/34 ,  C22B34/36 ,  C22B59/00 ,  C22C16/00 ,  C22C28/00 ,  Y02P10/214 ,  Y02P10/234

Abstract: The present invention provides a composition for collecting a metal component from a metal component-containing material, the composition containing a compound containing at least one element selected from the group consisting of lanthanoid elements and elements in group 2 of the periodic table, and a compound containing at least one element selected from the group consisting of elements in groups 3, 4, 12, and 13 of the periodic table and transition metal elements in the 4th period of the periodic table. The present invention further provides a method for collecting a metal component using this composition. With the use of the composition of the present invention, a metal component can be easily and efficiently collected from a material containing a highly useful metal component such as noble or rare metal.

Abstract translation: 本发明提供一种用于从含金属成分的材料收集金属成分的组合物，该组合物含有含有选自元素周期表第2族中的镧系元素和元素中的至少一种元素的化合物和化合物 含有选自元素周期表第3,4,12族元素中的至少一种元素和周期表第4周期中的过渡金属元素。 本发明还提供使用该组合物收集金属成分的方法。 通过使用本发明的组合物，可以从含有贵金属或稀有金属等高度有用的金属成分的材料容易且有效地收集金属成分。