摘要:
A biaxially stretched heat-shrinkable laminated film is disclosed which possesses good heat-shrinkability, excellent melt hole resistance and heat-resistant sealing property (the heat resistance of a seal portion), and highly satisfactory cold resistance, retains transparency even after shrinkage, and serves advantageously as a wrap for packaging foodstuffs. The laminated film is provided as an oxygen barrier layer with a layer of a mixture of vinylidene chloride resin and a low melting point polyamide resin having a crystalline melting point of not higher than 210.degree. C. This mixed resin has been cross-linked by applying the electron beam to the laminate in a dosage in the range of 1 to 12 megarads. The laminated film exhibits a heat shrinkage percentage of not less than 15% at 90.degree. C. and excels in gas barrier property.
摘要:
Disclosed herein are a resin composition comprising 5 to 95% by weight of a vinylidene chloride resin and 5 to 95% by weight of a polyamide resin having a low crystalline melting point of not higher than 210.degree. C. and a molded product of said resin composition.The molded product of the present invention shows a molded product excellent in gas-barrier property and impact strength at low temperature, particularly a film, sheet or container.Among the resin compositions of the present invention, since the composition having 60 to 95% by weight of vinylidene chloride resin is particularly rich in gas-barrier property, it is suitable for packaging foods, and since the composition having more than 40% by weight and not more than 95% by weight of polyamide resin is excellent particularly in impact strength at low temperature, it is suitable as the packaging material for use at an extremely low temperature. Moreover, the gas-barrier property and the transparency of the latter molded product which is rich in polyamide resin can be improved by stretching the product so that the dispersed particle of vinylidene chloride resin is made to be flat.
摘要:
Disclosed herein is a smoked food-package produced by packaging a foodstuff with a smokable packaging material and smoking the packaged foodstuff wherein the smokable packaging material comprises at least one layer of a mixture of 5 to 60% by weight of vinylidene chloride resin and 95 to 40% by weight of polyamide, said smokable packaging material having a practical smokability, high oxygen barrier property and high water vapor barrier property, and a smoking process.
摘要:
An improved method of vacuum packaging by using a specific laminated film as a package film, the laminated film being composed of a plastically deformable layer of a synthetic resin having a yield stress more than 50 kg/cm.sup.2 at a temperature of 23.degree. C. and an elongation of less than 30% at elastic limit at a shaping temperature of 50.degree. to 180.degree. C. and an elastic layer of a synthetic resin having an elongation of more than 40% at elastic limit at the shaping temperature.
摘要翻译:通过使用特定层压膜作为包装膜的真空包装的改进方法,该层压膜由在23℃的屈服应力大于50kg / cm 2的合成树脂的可塑性变形层组成,以及 在成形温度为50〜180℃的弹性极限下的伸长率小于30%,在成形温度下的弹性极限伸长率大于40%的合成树脂的弹性层。
摘要:
A laminated material having high workability and gas-impermeability is prepared by the lamination of a layer of vinylidene chloride copolymer containing 3 to 10% by weight of a plasticizer having a number average molecular weight of less than 500 with a carrier layer of synthetic resin containing 5 to 70% by weight of at least one organic additive having a number average molecular weight between 800 and 10,000 and selected from the group consisting of functional oligomers, fats and oils, rosin, and derivatives thereof.
摘要:
A laminated packaging material having high impermeability to gases and high workability is prepared by the lamination of a layer of copolymer of vinylidene chloride containing 3-10% by weight of a plasticizer of a number average molecular weight of less than 500 with another layer of a synthetic resin containing 5-70% by weight of at least one organic additive of a number average molecular weight of about 800-10,000 and selected from the group consisting of glycerides of higher saturated or unsaturated fatty acids and of epoxidized fatty acids, rosin and rosin derivatives, oligomeric copolymers of styrene with isobutylene, butadiene or isoprene, oligomeric polyesters which are formed by polycondensation of aliphatic dicarboxylic acid with 6-10 carbon atoms and polyhydric alcohol with 2-6 carbon atoms and have a number average molecular weight of 1,000-2,000, and oligomeric epoxides formed by polycondensation between epichlorhydrin and bisphenol.
摘要:
A vinylidene chloride copolymer composition is produced by copolymerizing 60 to 95 wt. % of vinylidene chloride and 40 to 5 wt. % of a comonomer in the presence of a rigid polymer which has a softening temperature of 50 to 180.degree. C. and a melt viscosity of 0.1 to 500 poise at 170.degree. C. and is soluble in vinylidene chloride monomer and is not substantially miscible to the vinylidene chloride copolymer, at a ratio of 0.01 to 5 wt. parts per 100 wt. parts of the monomer mixture.
摘要:
A water-insoluble, nonionic water-absorptive polyurethane fiber that combines the properties of high water absorptivity and excellent physical strength is produced by extrusion from a thermoplastic polyurethane resin composition at a temperature higher than its melting point. The thermoplastic polyurethane resin composition, which has a water absorption rate within the range of 200-3,000%, is obtained by reacting a polyisocyanate compound, a water-soluble polyalkylene ether polyol having a weight-average molecular weight of 2,000-13,000 and a chain extender at an equivalent ratio (R ratio) between the equivalent number of NCO groups and the equivalent number of OH groups in the range of 1.0 to 1.8. Also provided is a method of producing the water-absorptive polyurethane fiber.
摘要:
A bar-positioning member comprising a long metal wire or wire rod with at least one indentation to receive a metal bar intersectingly disposed relative to the wire. The indentation is formed by bending part of the wire and it has only one opening which opens along the longitudinal direction of the wire. The indentation has a bottom shaped approximately in conformity with the circumference of the bar.An apparatus for making a bar positioning member, as above described, comprising a pendulumlike mold member swingable about the base end thereof. The mold member has a grip to hold an intermediate portion of the wire, and the contour of the base end is shaped in conformity with the shape of the indentation.
摘要:
The present invention provides a laminated film including at least two layers of an outer layer having a printed portion on a surface and an inner layer subjected to an antifogging treatment in which principal resin comprising a solid content of the printed portion is made of chlorinated polypropylene-based resin or urethane-based resin. This antifog laminated film hardly degrades in an antifogging property even when the antifog laminated film subjected to printing on the outer layer of a surface subjected to the antifogging treatment and the printed surface are strongly brought into contact with each other due to an operation of winding the film into a roll or the like.