公开(公告)号：US20150023842A1

公开(公告)日：2015-01-22

申请号：US14467878

申请日：2014-08-25

Applicant: RENTECH, INC.

Inventor： Harold A. WRIGHT ,  Belma Demirel ,  Sergio Mohedas ,  Bahman Rejai ,  Ray J. Huang ,  Deena Ferdous ,  Jesse W. Taylor ,  Dawid J. Duvenhage ,  Sara L. Rolfe

IPC: B01J8/00 ,  B01J8/18

CPC classification number: B01J8/006 ,  B01J8/18 ,  B01J8/1809 ,  B01J23/745 ,  B01J33/00 ,  B01J35/023 ,  B01J37/0045 ,  B01J37/18 ,  C10G2/32 ,  C10G2/33 ,  C10G2/332 ,  C10G2300/703

Abstract: A method of preparing a spray dried catalyst by combining spray dried catalyst particles with wax so the spray dried catalyst particles are coated with wax, yielding wax coated catalyst particles, and shaping the wax coated catalyst to provide shaped wax coated catalyst. A method of activating Fischer-Tropsch catalyst particles containing oxides by contacting the catalyst particles with a reducing gas in an activation vessel to produce an activated catalyst, wherein contacting is performed in the absence of a liquid medium under activation conditions. A system for activating a Fischer-Tropsch catalyst containing an activation reactor configured to introduce an activation gas to a fixed or fluidized bed of the Fischer-Tropsch catalyst in the absence of a liquid medium and at least one separation device configured to separate a gas stream comprising entrained catalyst fines having an average particle size below a desired cutoff size from the activation reactor.

Abstract translation: 通过将喷雾干燥的催化剂颗粒与蜡组合来制备喷雾干燥的催化剂的方法，使喷雾干燥的催化剂颗粒用蜡涂覆，产生蜡涂覆的催化剂颗粒，并使蜡涂覆的催化剂成形以提供成形的涂蜡催化剂。 通过使催化剂颗粒与活化容器中的还原气体接触以产生活化的催化剂来活化含有氧化物的费 - 托催化剂颗粒的方法，其中在不存在液体介质的条件下进行接触。 一种用于活化费 - 托催化剂的系统，其包含活化反应器，所述活化反应器配置成在没有液体介质的情况下将活化气体引入费 - 托催化剂的固定或流化床，以及至少一个分离装置，其被配置为分离气流 包括夹带的催化剂细粒，其具有低于来自活化反应器的所需截留尺寸的平均粒度。

公开(公告)号：US20130330240A1

公开(公告)日：2013-12-12

申请号：US13962803

申请日：2013-08-08

Applicant: RENTECH, INC.

Inventor： George APANEL ,  Harold A. WRIGHT

IPC: B01J8/26

CPC classification number: C01B3/44 ,  B01J7/00 ,  B01J8/0055 ,  B01J8/006 ,  B01J8/1836 ,  B01J8/26 ,  B01J21/04 ,  B01J23/755 ,  B01J23/94 ,  B01J38/30 ,  B01J38/32 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2219/00006 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G2/32 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/207 ,  C10J3/56 ,  C10J2300/092 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1637 ,  C10J2300/1659 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10K1/002 ,  C10K1/004 ,  C10K1/34 ,  C10K3/003 ,  C10K3/023 ,  C10K3/04 ,  Y02E20/18 ,  Y02E50/32 ,  Y02P20/128 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20

Abstract: A system for production of high-quality syngas comprising a first dual fluidized bed loop having a fluid bed conditioner operable to produce high quality syngas comprising a first percentage of components other than carbon monoxide and hydrogen from a gas feed, wherein the conditioner comprises an outlet for a first catalytic heat transfer stream comprising a catalytic heat transfer material and having a first temperature, and an inlet for a second catalytic heat transfer stream comprising catalytic heat transfer material and having a second temperature greater than the first temperature; a fluid bed combustor operable to combust fuel and oxidant, wherein the fluid bed combustor comprises an inlet connected with the outlet for a first catalytic heat transfer stream of the conditioner, and an outlet connected with the inlet for a second catalytic heat transfer stream of the conditioner; and a catalytic heat transfer material.

Abstract translation: 一种用于生产高品质合成气的系统，包括具有流化床调节器的第一双流化床回路，该流化床调节器可操作以产生高质量的合成气，其包含来自气体进料的一氧化碳和氢气以外的第一百分比的组分，其中所述调节剂包括出口 用于包含催化传热材料并具有第一温度的第一催化传热流，以及包含催化传热材料并具有大于第一温度的第二温度的第二催化传热流的入口; 可操作以燃烧燃料和氧化剂的流化床燃烧器，其中所述流化床燃烧器包括与所述出口连接的用于所述调节器的第一催化传热流的入口，以及与所述入口连接的用于第二催化传热流的出口 护发素 和催化传热材料。

公开(公告)号：US20140314630A1

公开(公告)日：2014-10-23

申请号：US14322323

申请日：2014-07-02

Applicant: RENTECH, INC.

Inventor： George APANEL ,  Harold A. WRIGHT

IPC: B01J8/26

CPC classification number: C01B3/44 ,  B01J7/00 ,  B01J8/0055 ,  B01J8/006 ,  B01J8/1836 ,  B01J8/26 ,  B01J21/04 ,  B01J23/755 ,  B01J23/94 ,  B01J38/30 ,  B01J38/32 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2219/00006 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G2/32 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/207 ,  C10J3/56 ,  C10J2300/092 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1637 ,  C10J2300/1659 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10K1/002 ,  C10K1/004 ,  C10K1/34 ,  C10K3/003 ,  C10K3/023 ,  C10K3/04 ,  Y02E20/18 ,  Y02E50/32 ,  Y02P20/128 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20

Abstract: A system for production of high-quality syngas comprising a first dual fluidized bed loop having a fluid bed conditioner operable to produce high quality syngas comprising a first percentage of components other than carbon monoxide and hydrogen from a gas feed, wherein the conditioner comprises an outlet for a first catalytic heat transfer stream comprising a catalytic heat transfer material and having a first temperature, and an inlet for a second catalytic heat transfer stream comprising catalytic heat transfer material and having a second temperature greater than the first temperature; a fluid bed combustor operable to combust fuel and oxidant, wherein the fluid bed combustor comprises an inlet connected with the outlet for a first catalytic heat transfer stream of the conditioner, and an outlet connected with the inlet for a second catalytic heat transfer stream of the conditioner; and a catalytic heat transfer material.

Abstract translation: 一种用于生产高品质合成气的系统，包括具有流化床调节器的第一双流化床回路，该流化床调节器可操作以产生高质量的合成气，其包含来自气体进料的一氧化碳和氢气以外的第一百分比的组分，其中所述调节剂包括出口 用于包含催化传热材料并具有第一温度的第一催化传热流，以及包含催化传热材料并具有大于第一温度的第二温度的第二催化传热流的入口; 可操作以燃烧燃料和氧化剂的流化床燃烧器，其中所述流化床燃烧器包括与所述出口连接的用于所述调节器的第一催化传热流的入口，以及与所述入口连接的用于第二催化传热流的出口 护发素 和催化传热材料。

公开(公告)号：US20130320267A1

公开(公告)日：2013-12-05

申请号：US13962814

申请日：2013-08-08

Applicant: RENTECH, INC.

Inventor： George APANEL ,  Harold A. WRIGHT

IPC: C10K1/34

CPC classification number: C01B3/44 ,  B01J7/00 ,  B01J8/0055 ,  B01J8/006 ,  B01J8/1836 ,  B01J8/26 ,  B01J21/04 ,  B01J23/755 ,  B01J23/94 ,  B01J38/30 ,  B01J38/32 ,  B01J2208/00274 ,  B01J2208/00292 ,  B01J2219/00006 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/1058 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G2/32 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/207 ,  C10J3/56 ,  C10J2300/092 ,  C10J2300/0976 ,  C10J2300/0986 ,  C10J2300/1637 ,  C10J2300/1659 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10K1/002 ,  C10K1/004 ,  C10K1/34 ,  C10K3/003 ,  C10K3/023 ,  C10K3/04 ,  Y02E20/18 ,  Y02E50/32 ,  Y02P20/128 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/20

Abstract: A method for deep desulfurization of synthesis gas comprising introducing carbonaceous material and optionally steam into a gasifier comprising a heat transfer media, extracting a first heat transfer stream comprising heat transfer media and optionally unconverted carbonaceous material from the gasifier, and introducing at least a portion of the first heat transfer stream into a combustor, introducing oxidant and optionally a fuel into the combustor, extracting a second heat transfer stream comprising heat transfer media from the combustor, and introducing at least a portion of the second heat transfer stream into the gasifier, introducing a compound capable of reacting with sulfur to produce sulfate, sulfide or both, extracting a purge stream comprising ash, sulfate, halide, or a combination thereof from the second heat transfer stream, extracting a flue gas from the combustor, and extracting a gasifier product synthesis gas stream comprising less than 1000 ppm sulfur from the gasifier.

Abstract translation: 一种用于合成气深度脱硫的方法，包括将碳质材料和任选的蒸汽引入到包括传热介质的气化器中，从气化器中提取包含传热介质和任选未转化的碳质材料的第一传热流，并将至少一部分 将第一传热流引入燃烧器中，将氧化剂和任选的燃料引入燃烧器中，从燃烧器中提取包括传热介质的第二传热流，并将第二传热流的至少一部分引入气化器中，引入 能够与硫反应以产生硫酸盐，硫化物或二者的化合物，从第二传热流中提取包含灰分，硫酸盐，卤化物或其组合的吹扫流，从燃烧器中提取烟道气，以及提取气化器产物 包含来自气体的小于1000ppm的硫的合成气流 r。