Abstract:
Provided are apparatus and methods of gasification using a circulating fluidized bed reactor comprising a separate pyrolysis reaction chamber, one or more primary char gasification chambers, and one or more secondary char gasification chambers which comprise an internal vertical reaction volume suitable for containing a particle bed fluidized by a predominantly vertical upwards gas flow. The vertical reaction volume is advantageous in that this provides the possibility for increased retention time of particles, facilitating comparatively slow “productive” temperature moderation based on endothermic char conversion.
Abstract:
An arrangement for gasifying solid fuel includes a gasification reactor for producing further oxidizable product gas from solid fuel and a gas treatment reactor arranged in a flow direction of the product gas in gas flow connection with the gasification reactor. The gas treatment reactor includes a supply for supplying oxygenous gas to the gas treatment reactor for partial oxidization of product gas and for thermal cracking thereof. A radiation heat exchange cooler for cooling the product gas is arranged in connection with the gas treatment reactor to solidify melt components in the product gas. A discharge connection is arranged in the lower portion of the radiation heat exchange cooler for removing solidified melt components from the radiation heat exchange cooler. A method of gasifying solid fuel in a gasification reactor is also presented.
Abstract:
A method, apparatus, and system for a solar-driven chemical plant are disclosed. Some embodiments may include a solar thermal receiver to absorb concentrated solar energy from an array of heliostats and a solar-driven chemical reactor. This chemical reactor may have multiple reactor tubes, in which particles of biomass may be gasified in the presence of a carrier gas in a gasification reaction to produce hydrogen and carbon monoxide products. High heat transfer rates of the walls and tubes may allow the particles of biomass to achieve a high enough temperature necessary for substantial tar destruction and complete gasification of greater than 90 percent of the biomass particles into reaction products including hydrogen and carbon monoxide gas in a very short residence time between a range of 0.01 and 5 seconds.
Abstract:
Systems and methods for producing synthetic gas are provided. The method can include gasifying a feedstock within a gasifier to provide a raw syngas. The raw syngas can be processed within a purification system to provide a treated syngas, and the purification system can include a flash gas separator. The treated syngas and a first heat transfer medium can be converted into a synthetic gas, a second heat transfer medium, and a methanation condensate. The methanation condensate can be introduced to the flash gas separator.
Abstract:
A method, apparatus, and system for a solar-driven bio-refinery that may include a entrained-flow biomass feed system that is feedstock flexible via particle size control of the biomass. Some embodiments include a chemical reactor that receives concentrated solar thermal energy from an array of heliostats. The entrained-flow biomass feed system can use an entrainment carrier gas and supplies a variety of biomass sources fed as particles into the solar-driven chemical reactor. Biomass sources in a raw state or partially torrified state may be used, as long as parameters such as particle size of the biomass are controlled. Additionally, concentrated solar thermal energy can drive gasification of the particles. An on-site fuel synthesis reactor may receive the hydrogen and carbon monoxide products from the gasification reaction use the hydrogen and carbon monoxide products in a hydrocarbon fuel synthesis process to create a liquid hydrocarbon fuel.
Abstract:
A fluidized-bed reactor system with at least two fluidized-bed reactors, each being a circulating fluidized bed, a particle line with a particle separator for transferring fluidized-bed particles from the first to the second reactor, and a particle line exiting at the lower half of the second reactor for transferring fluidized-bed particles back to the first reactor, wherein, at least in the second reactor, two or more reaction zones separated by one or more flow controllers and that the particle line opens into the second reactor above at least one flow controller.
Abstract:
A system configured for the production of at least one product selected from the group consisting of syngas, Fischer-Tropsch synthesis products, power, and chemicals, the system comprising a dual fluidized bed gasification apparatus and at least one apparatus selected from power production apparatus configured to produce power from the gasification product gas, partial oxidation reactors configured for oxidation of at least a portion of the product gas, tar removal apparatus configured to reduce the amount of tar in the product gas, Fischer-Tropsch synthesis apparatus configured to produce Fischer-Tropsch synthesis products from at least a portion of the product gas, chemical production apparatus configured for the production of at least one non-Fischer-Tropsch product from at least a portion of the product gas, and dual fluidized bed gasification units configured to alter the composition of the product gas. Methods of operating the system are also provided.
Abstract:
A fuel gasification system including a gasification furnace including a fluidized bed formed by fluidizing reactant gas for gasifying fuel charged into gasification gas and flammable solid content, a combustion furnace for combustion of the flammable solid content into which the flammable solid content produced in the furnace is introduced together with bed material and that includes a fluidized bed formed by fluidizing reactant gas, a material separator such as hot cyclone that separates bed material from exhaust gas introduced from the combustion furnace, the separated bed material being fed through a downcomer to the gasification furnace, and a tar decomposing mechanism that heats the gasification gas produced in the furnace to decompose tar contained in the gasification gas.
Abstract:
A tar removal device removes tar contained in a gasification gas (9) generated in a gasification furnace of a two-towered gasifier having a combustion furnace (43) heating a heating medium (A) and the gasification furnace (47) introducing the heating medium (A) heated in the combustion furnace to perform gasification of a starting material (48).The tar removal device includes a tar separation unit (2) that introduces the gasification gas from the gasification furnace to fluidize the circulating particles (B) so as to adhere the tar in the gasification gas to the circulating particles, and a tar combustion unit (3) that introduces the circulating particles to which the tar is adhered at the tar separation unit, fluidizes the circulating particles using air (15) so as to burn the tar adhered to the circulating particles, supplies the combustion gas (16) in which the tar is burnt to the combustion furnace as a gas for combustion, and returns the circulating particles from which the tar is burnt and removed to the combustion furnace.
Abstract:
This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150° C. to 1500° C. range as well as in excess of 1500° C. In a preferred embodiment, such coals are dealt with a two stage gasification process—a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.