公开(公告)号：US4379062A

公开(公告)日：1983-04-05

申请号：US318814

申请日：1981-11-06

Applicant: Raymond D. Prengaman

Inventor： Raymond D. Prengaman

IPC: C10M111/00 ,  C10M1/10

CPC classification number: C10M111/00 ,  C10M2201/05 ,  C10M2201/053 ,  C10M2201/0603 ,  C10M2201/0613 ,  C10M2201/062 ,  C10M2201/0623 ,  C10M2201/063 ,  C10M2201/0653 ,  C10M2201/0663 ,  C10M2201/0803 ,  C10M2201/0853 ,  C10M2201/0863 ,  C10M2201/0873 ,  C10M2201/1006 ,  C10M2201/102 ,  C10M2201/1023 ,  C10M2201/1033 ,  C10M2201/105 ,  C10M2201/1053 ,  C10M2201/123 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2203/1045 ,  C10M2203/1065 ,  C10M2203/1085 ,  C10N2210/02 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

Abstract: A thread sealing and lubricating composition which can be employed at elevated temperatures without carburization of stainless steel fittings is disclosed. The composition contains 8-25% finely divided copper flakes, 5-20% finely divided aluminum particles, and 4-15% non-metallic, non-carbon powder suspended in a petroleum vehicle. The preferred composition contains 10% copper flakes, 5% aluminum powder, 5% non-metallic powder and 80% viscous petroleum vehicle.

Abstract translation: 公开了一种螺纹密封和润滑组合物，其可以在高温下使用，而不会使不锈钢配件渗碳。 该组合物含有8-25％细碎的铜薄片，5-20％细碎的铝颗粒和悬浮在石油载体中的4-15％非金属非碳粉末。 优选的组合物包含10％的铜薄片，5％的铝粉，5％的非金属粉末和80％的粘稠的石油载体。

公开(公告)号：US4376093A

公开(公告)日：1983-03-08

申请号：US270134

申请日：1981-06-03

Applicant: Raymond D. Prengaman

Inventor： Raymond D. Prengaman

IPC: C22C11/00 ,  C22C11/10 ,  H01M4/14 ,  H01M4/68 ,  C22C11/08

CPC classification number: C22C11/10 ,  H01M4/685

Abstract: Low antimony lead alloys suitable for use as grid material in maintenance-free high capacity lead acid batteries are disclosed. The alloys comprise 0.6 to 1.1 weight percent antimony, 0.06 to 0.25 weight percent arsenic, 0.1 to 0.4 weight percent tin, 0.06 to 0.11 weight percent copper, and the balance lead. A preferred alloy contains 0.8 weight percent antimony, 0.15 weight percent arsenic, 0.25 weight percent tin and 0.08 weight percent copper.

Abstract translation: 公开了适用于无需维护的大容量铅酸电池中的栅格材料的低锑铅合金。 该合金包含0.6-1.1重量％的锑，0.06-0.25重量％的砷，0.1-0.4重量％的锡，0.06-0.11重量百分比的铜和余量的铅。 优选的合金包含0.8重量％的锑，0.15重量％的砷，0.25重量％的锡和0.08重量百分比的铜。

公开(公告)号：US4373654A

公开(公告)日：1983-02-15

申请号：US211435

申请日：1980-11-28

Applicant: Raymond D. Prengaman ,  James L. Howard

Inventor： Raymond D. Prengaman ,  James L. Howard

IPC: B23K1/00 ,  C25C7/02 ,  B23K31/02 ,  B23P17/00

CPC classification number: C25C7/02 ,  Y10S228/901 ,  Y10T29/49117 ,  Y10T29/49213

Abstract: A lead anode for electrowinning metals from sulfuric acid solutions is formed by soldering a sheet of lead anode material endwise in a slot, which extends longitudinally along and partially through a lead alloy coated copper bus bar and into which the sheet fits tightly, and thereafter depositing lead alloy filler at all joints between the bar and anode. Anodes thus constructed have a uniform, smooth joint between the bar and sheet and thus are corrosion resistant and exhibit uniform conductivity.

Abstract translation: 用于从硫酸溶液中电解金属的铅阳极通过将铅阳极材料片沿端部焊接在槽中而形成，该槽沿纵向延伸并且部分地穿过铅合金涂覆的铜汇流条并且板紧密地嵌入其中，然后沉积 棒和阳极之间的所有接头处都有铅合金填料。 如此构造的阳极在棒材和片材之间具有均匀的光滑接合，因此具有耐腐蚀性并且具有均匀的导电性。

公开(公告)号：US4439398A

公开(公告)日：1984-03-27

申请号：US321051

申请日：1981-11-13

Applicant: Raymond D. Prengaman

Inventor： Raymond D. Prengaman

IPC: C22C11/00 ,  C22C1/02 ,  C22C11/02 ,  C22C24/00

CPC classification number: C22C11/02 ,  C22C1/02

Abstract: Calcium and aluminum are alloyed into lead by adding a eutectic calcium-aluminum alloy to molten lead preferably at a temperature of at least 1020.degree.. The eutectic alloy contains about 73% calcium and about 27% aluminum.

Abstract translation: 优选在至少1020℃的温度下，通过向熔融铅中加入共晶钙铝合金将钙和铝合金化成铅。 共晶合金含有约73％的钙和约27％的铝。

公开(公告)号：US4236978A

公开(公告)日：1980-12-02

申请号：US119743

申请日：1980-02-08

Applicant: Raymond D. Prengaman ,  Herschel B. McDonald

Inventor： Raymond D. Prengaman ,  Herschel B. McDonald

IPC: C25D9/06 ,  C25C1/08 ,  C25C1/12 ,  C25C1/18 ,  C25C7/02 ,  C25D17/10 ,  C25B1/30 ,  C25B11/02 ,  C25B11/12 ,  C25B11/16

CPC classification number: C25C7/02

Abstract: An improved insoluble anode for electrowinning is described which comprises a graphite substrate covered by a tight fitting sheet of a nonconductive electrolytically inert mesh material over which covered substrate is electrodeposited a layer of lead dioxide. The anode is formed by covering the graphite substrate with a sheet of the inert mesh material and thereafter electrodepositing lead dioxide thereon until a smooth layer of lead dioxide completely covers the mesh material. The anodes are electrolytically stable and are not susceptible to cracking.

Abstract translation: 描述了用于电解沉积的改进的不溶性阳极，其包括由非导电电解惰性网状材料的紧密贴片覆盖的石墨基底，在该基底上将被覆的基底电沉积二氧化铅层。 阳极通过用一片惰性网状材料覆盖石墨基板，然后在其上电沉积二氧化铅直到二氧化铅的平滑层完全覆盖网状材料而形成。 阳极电解稳定，不易开裂。

公开(公告)号：US4229271A

公开(公告)日：1980-10-21

申请号：US42158

申请日：1979-05-24

Applicant: Raymond D. Prengaman ,  Herschel B. McDonald

Inventor： Raymond D. Prengaman ,  Herschel B. McDonald

IPC: C25C1/18 ,  H01M10/54

CPC classification number: C25C1/18 ,  C22B13/045 ,  H01M10/54 ,  Y02P10/212 ,  Y02W30/84

Abstract: A process for recovery of substantially all lead values in battery sludge as metallic lead is disclosed. By means of the process, lead is substantially completely and efficiently recovered as metallic lead in an environmentally acceptable manner. The process comprises (a) subjecting the sludge to low temperature reducing conditions; (b) converting lead sulfates to insoluble nonsulfur containing compounds while solubilizing all sulfur materials and thereafter separating the solid residue by solid-liquid separation techniques; (c) dissolving the solid products resulting from steps (a) and (b) in an acid selected from the group consisting of fluoboric and fluosilicic acid; (d) collecting the supernatant from step (c) by means of solid-liquid separation techniques; and (e) electrowinning the lead from the collected supernatant. The lead peroxide reduction of step (a) may be effected by low temperature reducing roasts or by contacting the lead peroxide with sulfur dioxide gas or sulfites.

Abstract translation: 公开了一种用于回收作为金属铅的电池污泥中基本上所有铅值的方法。 通过该方法，铅以环境可接受的方式基本上完全有效地作为金属铅回收。 该方法包括（a）使污泥经受低温降低条件; （b）将硫酸铅转化成不溶性含硫化合物，同时溶解所有硫物质，然后用​​固液分离技术分离固体残渣; （c）将由步骤（a）和（b）得到的固体产物溶解在选自氟硼酸和氟硅酸的酸中; （d）通过固液分离技术从步骤（c）中收集上清液; 和（e）从收集的上清液中电解提取铅。 步骤（a）的过氧化铅还原可以通过低温还原焙烧或使过氧化铅与二氧化硫气体或亚硫酸盐接触来实现。

公开(公告)号：US5172850A

公开(公告)日：1992-12-22

申请号：US751523

申请日：1991-08-29

Applicant: Raymond D. Prengaman ,  Clifford E. Morgan

Inventor： Raymond D. Prengaman ,  Clifford E. Morgan

IPC: B23K1/002 ,  C25C7/02

CPC classification number: B23K1/002 ,  C25C7/02 ,  Y10T29/49888

Abstract: An electrowinning anode is formed by tightly joining a sheet of lead anode material to a copper busbar using solder to fill the joint. The busbar is optimally coated with a tin alloy by dipping the busbar into the alloy prior to being joined with the sheet. A lead coating is electrodeposited onto the busbar and the soldered joint to provide a complete metallurgical seal and good resistance to acid corrosion.

Abstract translation: 通过使用焊料将铅阳极材料片紧密地连接到铜母线以填充接​​头而形成电解阳极。 母线通过在与片材接合之前将母线浸入合金中来最佳地涂覆有锡合金。 铅涂层电沉积到母线和焊接接头上，以提供完整的冶金密封和良好的抗酸腐蚀性能。

公开(公告)号：US4230545A

公开(公告)日：1980-10-28

申请号：US093514

申请日：1979-11-13

Applicant: Raymond D. Prengaman ,  Herschel B. McDonald

Inventor： Raymond D. Prengaman ,  Herschel B. McDonald

IPC: C25C1/18 ,  C25C3/34

CPC classification number: C25C1/18

Abstract: An electrolyte and a process for reducing lead peroxide formation when electrowinning lead from inorganic acid solutions are disclosed. In accordance with the invention, arsenic is added to an inorganic acid electrolyte containing lead, whereby oxygen is evolved at the anode while lead peroxide formation is reduced or eliminated during electrolysis.

Abstract translation: 公开了电解质和当从无机酸溶液中电解提取铅时减少过氧化铅形成的方法。 根据本发明，将砷添加到含铅的无机酸电解质中，由此在电解期间减少或消除过氧化铅形成，在阳极处放出氧。

公开(公告)号：US3953244A

公开(公告)日：1976-04-27

申请号：US582119

申请日：1975-05-30

Applicant: Raymond D. Prengaman

Inventor： Raymond D. Prengaman

IPC: C22C11/02 ,  C22F1/12 ,  B23K19/00

CPC classification number: C22C11/02 ,  C22F1/12 ,  Y10S72/70 ,  Y10T29/49988 ,  Y10T29/49991

Abstract: Stable wrought lead-calcium-tin alloys can be prepared by casting an alloy of lead having a calcium content of from about 0.02% or 0.03% to about 0.1% by weight and having a tin content such that the tin to calcium weight ratio or relative tin content is from about 7:1 to 10:1 and preferably is more than 10:1 up to about 100:1, with the proviso that the absolute tin content be from about 0.3% to about 2.0%; and thereafter cold working the casting at a time period of within about 24 hours after casting for the lead-calcium-tin alloys having a tin to calcium weight ratio of from about 7:1 to 10:1 and within about 48 hours after casting for the lead-calcium-tin alloys having a tin to calcium weight ratio of from more than 10:1 up to about 100:1.Aged work pieces heated sufficiently to dissolve the precipitated calcium phases can be similarly treated.

Abstract translation: 稳定的锻造铅 - 钙 - 锡合金可以通过铸造具有约0.02％或约0.03％至约0.1％的钙含量的铅合金制备，并且具有使锡与钙的重量比或相对 锡含量为约7:1至10:1，优选大于10:1至约100:1，条件是绝对锡含量为约0.3％至约2.0％; 然后在铸造之后的约24小时内对铸件进行冷加工，其中锡 - 锡重量比为约7:1至10:1的铅 - 钙 - 锡合金和铸造后约48小时内 锡 - 钙重量比大于10:1至高达约100:1的铅 - 钙 - 锡合金。