公开(公告)号：US10723678B2

公开(公告)日：2020-07-28

申请号：US15765617

申请日：2016-11-08

Applicant: SABIC Global Technologies B.V.

Inventor： Theo Van Der Kort ,  Kuldeep Wadhwa ,  Anthoni Van Zijl

IPC: C07C7/20 ,  C07C11/167 ,  C07C7/00 ,  C07C7/04

Abstract: The presently disclosed subject matter provides a method for inhibiting the formation of popcorn polymer in the vapor phase of a butadiene extraction/purification system. In a non-limiting embodiment, a method for inhibiting the formation of popcorn polymer includes injecting nitric oxide into the upper portion, i.e., headspace of a butadiene distillation column.

公开(公告)号：US11879102B2

公开(公告)日：2024-01-23

申请号：US17424701

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G57/02 ,  C08J11/14 ,  C08L23/06 ,  B29B17/04 ,  C08J11/00 ,  C10G9/14 ,  C10G50/00 ,  C10G69/12 ,  C10G1/10 ,  C10G47/00 ,  B29C48/275 ,  B29B17/02 ,  C08J11/06 ,  C10G51/02 ,  C08J11/12 ,  B29B17/00

CPC classification number: C10G57/02 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G50/00 ,  C10G51/023 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of ethylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of a pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising ethylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an ethylene-based polymer; wherein in step (d): ⋅ · the coil outlet temperature is 2: 800 and:::; 870° C., preferably 2: 820 and:::; 870° C.; and ⋅ · the weight ratio of steam to feed C is >0.3 and

公开(公告)号：US12024683B2

公开(公告)日：2024-07-02

申请号：US17424560

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G57/02 ,  B29B17/02 ,  B29B17/04 ,  B29C48/275 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G50/00 ,  C10G51/02 ,  C10G69/12 ,  B29B17/00

CPC classification number: C10G57/02 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G50/00 ,  C10G51/023 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: A process for the production of ethylene-based polymers from waste plastics feedstocks includes the steps in this order of: providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; providing a hydrocarbon stream B; supplying a feed C including a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace having cracking coil(s); performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; supplying the cracked hydrocarbon stream D to a separation unit to obtain a product stream E containing ethylene; supplying the product stream E to a polymerisation reactor; and performing a polymerisation reaction to obtain an ethylene-based polymer; wherein in step (d): the coil outlet temperature is ≥800 and ≤870° C.; and the weight ratio of steam to feed C is >0.3 and

公开(公告)号：US11685867B2

公开(公告)日：2023-06-27

申请号：US17425466

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G57/02 ,  B29B17/04 ,  C08J11/00 ,  C10G9/14 ,  C10G50/00 ,  C10G69/12 ,  C10G1/10 ,  C10G47/00 ,  B29C48/275 ,  B29B17/02 ,  C08J11/06 ,  C10G51/02 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  B29B17/00

CPC classification number: C10G57/02 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G50/00 ,  C10G51/023 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer. The process of the present invention allows for optimisation of the quantity of waste plastic material that finds its way back into a polymer that is produced as outcome of the process.

公开(公告)号：US11667854B2

公开(公告)日：2023-06-06

申请号：US17425173

申请日：2020-01-24

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Anthoni Van Zijl ,  Nicolas Goyheneix ,  Lara Galan-Sanchez ,  Christoph Roosen ,  Johan Pastwa ,  Safa Farajzadeh Bibalan

IPC: C10G50/00 ,  C10G55/04 ,  B29B17/04 ,  C08J11/00 ,  C10G9/14 ,  C10G57/02 ,  C10G69/12 ,  C10G1/10 ,  C10G47/00 ,  B29C48/275 ,  B29B17/02 ,  C08J11/06 ,  C10G51/02 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  B29B17/00

CPC classification number: C10G50/00 ,  B29B17/02 ,  B29B17/04 ,  B29C48/277 ,  C08J11/00 ,  C08J11/06 ,  C08J11/12 ,  C08J11/14 ,  C08L23/06 ,  C10G1/10 ,  C10G9/14 ,  C10G47/00 ,  C10G51/023 ,  C10G57/02 ,  C10G69/12 ,  B29B2017/0089 ,  B29B2017/0203 ,  B29B2017/0496 ,  C08J2300/30 ,  C08L2207/20 ,  C10G2300/1003 ,  C10G2300/1085 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/20

Abstract: The present invention relates to a process for the production of propylene-based polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising propylene; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an propylene-based polymer; wherein in step (d): •⋅ the coil outlet temperature is 2:: 800 and:::; 850° C., preferably 2:: 805 and:::; 835° C.; and •⋅ the weight ratio of steam to feed C is >0.3 and