公开(公告)号：US20180127543A1

公开(公告)日：2018-05-10

申请号：US15803963

申请日：2017-11-06

Applicant: SHOWA DENKO K.K.

Inventor： Kentaro WATANABE ,  Yasuyuki UEDA ,  Takeshi IGARASHI

IPC: C08G65/329 ,  C10M107/38 ,  C08G65/337 ,  C08G65/332 ,  C08G65/333

CPC classification number: C08G65/329 ,  C08G65/332 ,  C08G65/33317 ,  C08G65/33375 ,  C08G65/337 ,  C08G2650/48 ,  C10M107/38 ,  C10M2213/043 ,  C10M2213/0606 ,  C10N2230/56 ,  C10N2240/204

Abstract: In an organic fluorine compound, an organic group including a single aromatic ring or a condensed ring consisting of aromatic rings at a non-bonded terminal is bonded to each of all of terminals of a chain structure including a perfluoropolyether structure.

公开(公告)号：US20170253567A1

公开(公告)日：2017-09-07

申请号：US15509080

申请日：2015-09-04

Applicant: SHOWA DENKO K.K.

Inventor： Tienan JIN ,  Weili SI ,  Yoshinori YAMAMOTO ,  Takeshi IGARASHI

IPC: C07D241/38 ,  C07C17/266 ,  C07C41/30 ,  C07D333/78 ,  C07C1/26 ,  C07C67/343

Abstract: This method for producing a fullerene derivative is a method for producing a fullerene derivative having a partial structure shown by formula (1) by reacting a predetermined halogenated compound and two carbon atoms adjacent to each other for forming a fullerene skeleton in a mixed solvent of an aromatic solvent and an aprotic polar solvent having a C═O or S═O bond in the presence of at least one metal selected from the group comprising manganese, iron, and zinc; (in formula (1), C* are each carbon atoms adjacent to each other for forming a fullerene skeleton, A is a linking group having 1-4 carbon atoms for forming a ring structure with two C*, in which a portion thereof may be a substituted or condensed group).

公开(公告)号：US20160347703A1

公开(公告)日：2016-12-01

申请号：US15116672

申请日：2015-02-20

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Kentaro WATANABE

IPC: C07C69/65 ,  C07C69/753 ,  C10M107/38 ,  C07C69/88

CPC classification number: C07C69/65 ,  C07C69/753 ,  C07C69/76 ,  C07C69/88 ,  C07C2604/00 ,  C10M105/54 ,  C10M107/38 ,  C10M2211/0425 ,  C10M2213/043 ,  C10N2230/06 ,  C10N2240/204 ,  C10N2250/121

Abstract: A fullerene derivative of the present invention has a fullerene skeleton and a plurality of perfluoropolyether chains in a molecule, wherein the perfluoropolyether chains are bonded to the fullerene skeleton via methano groups, and a lubricant and fluororesin composition of the present invention contain the derivative.

公开(公告)号：US20150376110A1

公开(公告)日：2015-12-31

申请号：US14315460

申请日：2014-06-26

Applicant: Showa Denko K.K. ,  Tohoku University

Inventor： Tienan JIN ,  Weili SI ,  Yoshinori YAMAMOTO ,  Takeshi IGARASHI

IPC: C07C69/78 ,  C07D333/24 ,  C07C69/92 ,  C07C67/333

CPC classification number: C07D333/24 ,  C07C67/333 ,  C07C69/94 ,  C07C2604/00

Abstract: Disclosed is a fullerene derivative represented by the following formula (1): wherein FLN is a fullerene backbone, R1 is a substituted or non-substituted alkyl group with a carbon number less than or equal to 24, and Ar1 is a substituted or non-substituted aryl group with a carbon number less than or equal to 24.

Abstract translation: 公开了下述式（1）所示的富勒烯衍生物：其中，FLN为富勒骨架，R1为碳数小于等于24的取代或未取代的烷基，Ar1为取代或非取代的烷基， 取代的碳数小于或等于24的芳基。

公开(公告)号：US20210062407A1

公开(公告)日：2021-03-04

申请号：US16756250

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Tomoyuki TAKEI ,  Yu GAO ,  Masumi KURITANI

IPC: D06M11/74 ,  C01B32/05 ,  C08J5/06 ,  D06M23/10

Abstract: By sequentially performing: a step (I) of dissolving fullerene C70 in an organic solvent to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution and drying the extracted carbon fiber, a carbon fiber on which fullerene C70 adsorbs is obtained.

公开(公告)号：US20180086771A1

公开(公告)日：2018-03-29

申请号：US15828987

申请日：2017-12-01

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Yasuyuki UEDA ,  Kentaro WATANABE

IPC: C07D487/22 ,  C07D487/18 ,  C07D487/08 ,  C07D209/70 ,  C10M105/70 ,  C10M105/54

CPC classification number: C07D487/22 ,  C07D209/70 ,  C07D487/08 ,  C07D487/18 ,  C10M103/02 ,  C10M105/00 ,  C10M105/54 ,  C10M105/70 ,  C10M2213/0606 ,  C10M2215/223 ,  C10N2220/082 ,  C10N2230/54 ,  C10N2240/204 ,  C10N2250/121 ,  C10N2280/00

Abstract: A fullerene derivative, used as a lubricant, includes, in a molecule: a fullerene backbone; and n pyrrolidine rings each being condensed to the fullerene backbone, each of the pyrrolidine rings including one aryl group including a group including m perfluoropolyether chains, “m” being an integer from 2 to 5 and “n” being an integer from 1 to 5.

公开(公告)号：US20210062409A1

公开(公告)日：2021-03-04

申请号：US16757863

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Tomoyuki TAKEI ,  Yu GAO ,  Masumi KURITANI

IPC: D06M11/74 ,  C01B32/05 ,  C08J5/06

Abstract: A carbon fiber is obtained by sequentially performing: a step (I) of dissolving a fullerene mixture including fullerenes C60 and C70 in an organic solvent to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution and drying the extracted carbon fiber.

公开(公告)号：US20210062408A1

公开(公告)日：2021-03-04

申请号：US16757861

申请日：2018-10-17

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Tomoyuki TAKEI ,  Yu GAO ,  Masumi KURITANI

IPC: D06M11/74

Abstract: By sequentially performing: a step (I) of dissolving fullerene C60 in a polyalkylene glycol to prepare a fullerene solution; a step (II) of immersing a material carbon fiber in the fullerene solution; and a step (III) of extracting the carbon fiber from the fullerene solution, washing the extracted carbon fiber with water, and drying the carbon fiber washed with water, a carbon fiber on which fullerene C60 adsorbs is obtained.

公开(公告)号：US20190203140A1

公开(公告)日：2019-07-04

申请号：US16322564

申请日：2017-08-08

Applicant: SHOWA DENKO K.K.

Inventor： Takeshi IGARASHI ,  Kentaro WATANABE ,  Yasuyuki UEDA

IPC: C10M107/38 ,  C08G65/332

Abstract: One embodiment of the present invention is a fullerene derivative represented by general formula (1) (wherein FLN is a fullerene backbone; each A is independently a monovalent group including a divalent perfluoropolyether group; each R is each independently a hydrogen atom, a hydrocarbon group, or an alkoxycarbonyl group including a divalent perfluoropolyether group; at least one of the 2m R is a hydrocarbon group or an alkoxycarbonyl group including a divalent perfluoropolyether group; m is an integer from 1 to 5; and n is an integer from 1 to 6).