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    GAS-BARRIER RESIN COMPOSITION AND USE THEREOF
    1.
    发明申请
    GAS-BARRIER RESIN COMPOSITION AND USE THEREOF 有权

    公开(公告)号：US20210147669A1

    公开(公告)日：2021-05-20

    申请号：US16624055

    申请日：2018-07-17

    Applicant: SHOWA DENKO K.K. ,  JAPAN POLYETHYLENE CORPORATION

    Inventor： Junichi KURODA ,  Yoshikuni OKUMURA ,  Shinya HAYASHI ,  Masahiro UEMATSU ,  Takaaki HATTORI ,  Yuichiro YASUKAWA

    IPC: C08L29/04 ,  C08L23/08

    Abstract: A gas-barrier resin (A) having an oxygen permeability coefficient of 1.0×10−14 (cm3·cm/cm2·s·Pa) or less; and a copolymer (B) containing monomer structural units represented by the formula (1), the formula (2), and the formula (3): where: R1 represents a hydrogen atom or a methyl group; R2 represents a hydrocarbon group having 1 to 20 carbon atoms that may be substituted with a halogen atom, a hydroxy group, an alkoxy group, or an amino group; 1, m, and n represent numerical values representing molar proportions of the respective monomer structural units, and n may represent 0; and p represents an integer of from 1 to 4, wherein a ratio of a mass of the copolymer (B) to a total mass of the gas-barrier resin (A) and the copolymer (B) is from 1 mass % to 40 mass %.

    METHOD FOR RECOVERING OLEFIN
    2.
    发明申请
    METHOD FOR RECOVERING OLEFIN 有权

    公开(公告)号：US20220234024A1

    公开(公告)日：2022-07-28

    申请号：US17615466

    申请日：2020-07-30

    Applicant: SHOWA DENKO K.K.

    Inventor： Yoshihiro WATANABE ,  Yoshikuni OKUMURA

    IPC: B01J20/22 ,  C07C7/12 ,  B01J20/26 ,  B01D53/047

    Abstract: Provided is a method for recovering, by pressure swing adsorption, unreacted olefins from a stream of a chemical reaction process in which an olefin is used as a material, the method enables desorption of gas at a relatively high desorption operation pressure, more preferably at a pressure not lower than the atmospheric pressure, and enables reuse of a separation agent. As the separation agent, a metal complex is used, in which pressure P3 at which a local maximum of dA/dP is obtained during adsorption and pressure P4 at which a local maximum of dA/dP is obtained during desorption are located between an adsorption operation pressure P1 and a desorption operation pressure P2, where dA/dP represents a value obtained by differentiating A by P, assuming that an olefin adsorption amount (A) is a function of an adsorption pressure (P), i.e., A=f(P), on an adsorption isotherm indicating the pressure (P) and the adsorption amount (A).

    MOLDED ARTICLE FOR HYDROCARBON ADSORPTION
    5.
    发明申请
    MOLDED ARTICLE FOR HYDROCARBON ADSORPTION 有权
    用于石油吸收的模制品

    公开(公告)号：US20160175810A1

    公开(公告)日：2016-06-23

    申请号：US14906818

    申请日：2014-07-01

    Applicant: SHOWA DENKO K.K

    Inventor： Yoshihiro WATANABE ,  Keisuke KISHIDA ,  Yoshikuni OKUMURA

    IPC: B01J20/22 ,  B01J20/30 ,  B01J20/26

    CPC classification number: B01J20/223 ,  B01D53/02 ,  B01D2253/1122 ,  B01D2253/20 ,  B01D2257/7022 ,  B01J20/226 ,  B01J20/261 ,  B01J20/2803 ,  B01J20/3007 ,  C07C7/12 ,  C07F1/08 ,  C07F3/06 ,  C07C11/167

    Abstract: Provided is a molded article for hydrocarbon adsorption, in which a porous metal complex, the structure of which may vary with adsorption and desorption of gases, can exhibit to a sufficient degree the adsorption and desorption capabilities inherent to the complex. This molded article for hydrocarbon adsorption is characterized by including (A) a metal complex constituted by metal ions, and organic ligands capable of bonding to the metal ions, and (B) a polymer binder component containing within its molecules a total of 0.3 mmol/g to 8.0 mmol/g, inclusive, of at least one functional group selected from group consisting of the carboxyl group, the hydroxyl group, amino groups, the mercapto group, epoxy groups, and the sulfo group.

    Abstract translation: 提供一种用于烃吸附的模制品，其中其结构可随气体的吸附和解吸而变化的多孔金属络合物可以充分展现复合物固有的吸附和解吸能力。 用于烃吸附的成型品的特征在于包括（A）由金属离子构成的金属络合物和能够与金属离子键合的有机配体，（B）含有其分子内的总共0.3mmol / g至8.0mmol / g，包括至少一种选自羧基，羟基，氨基，巯基，环氧基和磺基的官能团。

    PRODUCTION METHOD OF POLAR GROUP-CONTAINING OLEFIN POLYMERS
    8.
    发明申请
    PRODUCTION METHOD OF POLAR GROUP-CONTAINING OLEFIN POLYMERS 有权
    含极性烯烃聚合物的生产方法

    公开(公告)号：US20150368376A1

    公开(公告)日：2015-12-24

    申请号：US14762598

    申请日：2014-01-22

    Applicant: THE UNIVERSITY OF TOKYO ,  SHOWA DENKO K.K.

    Inventor： Shingo ITO ,  Kyoko NOZAKI ,  Yusuke OTA ,  Yoshikuni OKUMURA ,  Junichi KURODA

    IPC: C08F10/02 ,  C07F15/00

    CPC classification number: C08F10/02 ,  C07F9/5442 ,  C07F15/006 ,  C07F15/0066 ,  C08F4/60031 ,  C08F4/80 ,  C08F220/02 ,  C08F210/02 ,  C08F4/7031 ,  C08F218/12 ,  C08F4/7098 ,  C08F214/14 ,  C08F220/44 ,  C08F220/18 ,  C08F218/08 ,  C08F218/10

    Abstract: The present invention relates to a method for producing a homopolymer of olefin represented by formula (1): CH2═CHR1 (R1 is a hydrogen atom or hydrocarbon group having 1 to 20 carbon atoms) or a copolymer of two or more thereof or a method for producing a copolymer of olefin represented by formula (1) with olefin containing a polar group represented by formula (2): CH2═CHR2R3 (R2 is a hydrogen atom or methyl group, R3 is —COOR12, —CN, —OCOR12, —OR12, —CH2—OCOR12, —CH2OH, —CH2—N(R13)2 or —CH2-Hal (R12, R13 and Hal have the same meanings as stated in the description), using as a catalyst a metal complex of group 10 elements in the periodic system typified by the structure represented by formula 1 (“Men” represents a menthyl group and “Me” represents a methyl group). The present invention enables the production of high molecular weight polymers of the polar group-containing monomers such as polar group-containing allyl compounds.

    Abstract translation: 本发明涉及一种由式（1）表示的烯烃均聚物的制造方法：CH2 = CHR1（R1为氢原子或碳原子数1〜20的烃基）或其两种以上的共聚物或方法 用于由式（1）表示的烯烃的共聚物与由式（2）表示的极性基团的烯烃：CH2 = CHR2R3（R2是氢原子或甲基，R3是-COOR12，-CN，-OCOR12， - OR12，-CH2-OCOR12，-CH2OH，-CH2-N（R13）2或-CH2-Hal（R12，R13和Hal具有与说明书中所述相同的含义），使用组10的金属络合物作为催化剂 由式1表示的结构（“Men”表示薄荷基，“Me”表示甲基）表示的周期性体系中的元素，本发明能够制备含极性基团的单体的高分子量聚合物， 作为极性基团的烯丙基化合物。

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