公开(公告)号：US20220234024A1

公开(公告)日：2022-07-28

申请号：US17615466

申请日：2020-07-30

Applicant: SHOWA DENKO K.K.

Inventor： Yoshihiro WATANABE ,  Yoshikuni OKUMURA

IPC: B01J20/22 ,  C07C7/12 ,  B01J20/26 ,  B01D53/047

Abstract: Provided is a method for recovering, by pressure swing adsorption, unreacted olefins from a stream of a chemical reaction process in which an olefin is used as a material, the method enables desorption of gas at a relatively high desorption operation pressure, more preferably at a pressure not lower than the atmospheric pressure, and enables reuse of a separation agent. As the separation agent, a metal complex is used, in which pressure P3 at which a local maximum of dA/dP is obtained during adsorption and pressure P4 at which a local maximum of dA/dP is obtained during desorption are located between an adsorption operation pressure P1 and a desorption operation pressure P2, where dA/dP represents a value obtained by differentiating A by P, assuming that an olefin adsorption amount (A) is a function of an adsorption pressure (P), i.e., A=f(P), on an adsorption isotherm indicating the pressure (P) and the adsorption amount (A).

公开(公告)号：US20160159823A1

公开(公告)日：2016-06-09

申请号：US14906908

申请日：2014-07-01

Applicant: SHOWA DENKO K.K.

Inventor： Keisuke KISHIDA ,  Yoshihiro WATANABE ,  Yoshikuni OKUMURA

IPC: C07F3/06 ,  B01J20/22 ,  B01D69/14 ,  B01D53/02 ,  B01D53/22 ,  C07C7/12 ,  B01J20/28

CPC classification number: C07F3/06 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D69/14 ,  B01D2253/112 ,  B01D2253/20 ,  B01D2256/24 ,  B01D2257/7022 ,  B01D2325/12 ,  B01J20/226 ,  B01J20/28035 ,  B01J20/3483 ,  C07C7/12 ,  C07C201/12 ,  C07D213/06 ,  C07D213/68 ,  C07D213/70 ,  Y02C10/08 ,  C07C11/167 ,  C07C205/57

Abstract: A separating material superior to conventional separating materials, and a separation method are provided, with which 1,3-butadiene is selectively separated and recovered from a mixed gas including 1,3-butadiene and C4 hydrocarbons other than 1,3-butadiene. A metal complex, which comprises a dicarboxylic acid compound (I) (see (I) below) represented by general formula (I), an ion of a metal such as beryllium, and a dipyridyl compound (II) represented by general formula (II), namely L-Z-L (II) (see L below), is characterized by including, as the dipyridyl compound (II), at least two different dipyridyl compounds (II). The metal complex is used as a 1,3-butadiene separating material. Formula (I) L is represented by any of the compounds below.

Abstract translation: 提供优于常规分离材料的分离材料和分离方法，其中从包含1,3-丁二烯和除1,3-丁二烯之外的C 4烃的混合气体中选择性地分离和回收1,3-丁二烯。 一种金属络合物，其包含由通式（I）表示的二羧酸化合物（I）（见（I）），金属如铍的离子和由通式（II）表示的二吡啶基化合物（II） ），即LZL（II）（见下文L），其特征在于包括作为二吡啶基化合物（II）的至少两种不同的联吡啶基化合物（II）。 金属络合物用作1,3-丁二烯分离材料。 式（I）L由下列任何化合物表示。

公开(公告)号：US20160175810A1

公开(公告)日：2016-06-23

申请号：US14906818

申请日：2014-07-01

Applicant: SHOWA DENKO K.K

Inventor： Yoshihiro WATANABE ,  Keisuke KISHIDA ,  Yoshikuni OKUMURA

IPC: B01J20/22 ,  B01J20/30 ,  B01J20/26

CPC classification number: B01J20/223 ,  B01D53/02 ,  B01D2253/1122 ,  B01D2253/20 ,  B01D2257/7022 ,  B01J20/226 ,  B01J20/261 ,  B01J20/2803 ,  B01J20/3007 ,  C07C7/12 ,  C07F1/08 ,  C07F3/06 ,  C07C11/167

Abstract: Provided is a molded article for hydrocarbon adsorption, in which a porous metal complex, the structure of which may vary with adsorption and desorption of gases, can exhibit to a sufficient degree the adsorption and desorption capabilities inherent to the complex. This molded article for hydrocarbon adsorption is characterized by including (A) a metal complex constituted by metal ions, and organic ligands capable of bonding to the metal ions, and (B) a polymer binder component containing within its molecules a total of 0.3 mmol/g to 8.0 mmol/g, inclusive, of at least one functional group selected from group consisting of the carboxyl group, the hydroxyl group, amino groups, the mercapto group, epoxy groups, and the sulfo group.

Abstract translation: 提供一种用于烃吸附的模制品，其中其结构可随气体的吸附和解吸而变化的多孔金属络合物可以充分展现复合物固有的吸附和解吸能力。 用于烃吸附的成型品的特征在于包括（A）由金属离子构成的金属络合物和能够与金属离子键合的有机配体，（B）含有其分子内的总共0.3mmol / g至8.0mmol / g，包括至少一种选自羧基，羟基，氨基，巯基，环氧基和磺基的官能团。

公开(公告)号：US20160159712A1

公开(公告)日：2016-06-09

申请号：US14906919

申请日：2014-07-01

Applicant: SHOWA DENKO K.K.

Inventor： Keisuke KISHIDA ,  Yoshihiro WATANABE ,  Yoshikuni OKUMURA

IPC: C07C7/12 ,  B01J20/28 ,  B01J20/34 ,  B01D53/047 ,  B01D53/04 ,  B01D53/22 ,  B01D69/10 ,  B01D71/06 ,  B01J20/22 ,  C07F3/06

CPC classification number: C07C7/12 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/228 ,  B01D69/10 ,  B01D69/142 ,  B01D69/147 ,  B01D71/00 ,  B01D71/06 ,  B01D2053/221 ,  B01D2253/20 ,  B01D2256/24 ,  B01D2257/702 ,  B01D2325/12 ,  B01J20/223 ,  B01J20/226 ,  B01J20/28033 ,  B01J20/3425 ,  B01J20/3491 ,  C07F3/06 ,  C07C11/167

Abstract: A separating material superior to conventional separating materials, and a separation method are provided, with which 1,3-butadiene is selectively separated and recovered from a mixed gas including 1,3-butadiene and C4 hydrocarbons other than 1,3-butadiene. A metal complex, which comprises a dicarboxylic acid compound (I) (see (I) below) represented by general formula (I), an ion of a metal such as beryllium, and a bipyridyl compound (II) represented by general formula (II), namely L-Z-L (II) (see (L) below), is characterized by including, as the dicarboxylic acid compound (I), at least two different dicarboxylic acid compounds (I). The metal complex is used as a 1,3-butadiene separating material. Formula (I) L is represented by any of the compounds below. Formula (L)

Abstract translation: 提供优于常规分离材料的分离材料和分离方法，其中从包含1,3-丁二烯和除1,3-丁二烯之外的C 4烃的混合气体中选择性地分离和回收1,3-丁二烯。 一种金属络合物，其包含由通式（I）表示的二羧酸化合物（I）（见（I）），金属如铍的离子和由通式（II）表示的联吡啶基化合物（II） ），即LZL（II）（参见下面的（L）），其特征在于包括作为二羧酸化合物（I）的至少两种不同的二羧酸化合物（I）。 金属络合物用作1,3-丁二烯分离材料。 式（I）L由下列任何化合物表示。 公式（L）

公开(公告)号：US20150329563A1

公开(公告)日：2015-11-19

申请号：US14443573

申请日：2013-12-16

Applicant: SHOWA DENKO K.K.

Inventor： Keisuke KISHIDA ,  Yoshihiro WATANABE

IPC: C07F1/08 ,  B01D53/04 ,  B01D53/047 ,  B01J20/28 ,  C07C7/144 ,  B01J20/22 ,  B01J20/24 ,  B01J20/26 ,  B01D53/22 ,  C07C7/12

CPC classification number: C07F1/08 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D53/22 ,  B01D53/228 ,  B01D53/229 ,  B01D71/022 ,  B01D71/62 ,  B01D2252/2053 ,  B01D2253/204 ,  B01D2256/24 ,  B01D2257/7022 ,  B01J20/223 ,  B01J20/24 ,  B01J20/261 ,  B01J20/28033 ,  B01J20/28038 ,  B01J20/3212 ,  B01J20/3265 ,  C07C7/12 ,  C07C7/144 ,  D21H17/12 ,  C07C9/00 ,  C07C9/10 ,  C07C9/06 ,  C07C6/06

Abstract: A separation material and method for separating and recovering a target gas from a mixed gas including the target gas and a hydrocarbon gas that has the same number of carbon atoms as the target gas, the target gas being a hydrocarbon gas having 2 or 4 carbon atoms and a carbon-carbon double bond. This gas separation material includes: a metal complex containing a 2,3-pyrazinedicarboxylic acid; an ion of at least one type of metal (M); and an organic ligand (B) capable of bidentate coordination to the metal ion represented by general formula (1) or general formula (2), where (M), formula (1) and formula (2) are as defined herein. The metal complex has a composition represented by M2+2A2−2B where M2+ is the ion of the metal (M), A2− is a 2,3-pyrazinedicarboxylate dianion and B is the organic ligand (B) capable of bidentate coordination to the metal ion.

Abstract translation: 一种用于从包括目标气体和与目标气体具有相同碳原子数的烃气体的混合气体中分离和回收目标气体的分离材料和方法，所述目标气体是具有2或4个碳原子的烃气体 和碳 - 碳双键。 该气体分离材料包括：含有2,3-吡嗪二羧酸的金属络合物; 至少一种金属离子（M）; 和能够与由通式（1）或通式（2）表示的金属离子双齿配位的有机配体（B），其中（M），式（1）和式（2）如本文所定义。 金属络合物具有由M2 + 2A2-2B表示的组成，其中M2 +是金属离子（M），A2-是2,3-吡嗪二羧酸根阴离子，B是能够双键配位的有机配体（B） 金属离子