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1.发明授权Process for making a high viscosity base oil with an improved viscosity index 有权制备具有改进的粘度指数的高粘度基础油的方法公开(公告)号：US08222471B2
公开(公告)日：2012-07-17
申请号：US12966738
申请日：2010-12-13
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/40 , B01J2231/20 , C10G1/002 , C10G3/00 , C10G57/02 , C10G2300/1022 , C10G2300/1088 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/4025 , C10G2400/10 , Y02P30/20
摘要： We provide a process, comprising oligomerizing one or more olefins having a boiling point less than 82° C. in a presence of an ionic liquid catalyst and one or more C5+ alpha olefins in a reactor to produce a base oil having a kinematic viscosity at 100° C. of 36 mm2/s or higher and a VI greater than 55; and wherein the one or more olefins having the boiling point less than 82° C. comprise greater than 50 wt % of a total mixture of olefins fed to the reactor. We provide a process, comprising oligomerizing olefins having a low boiling point in a presence of an ionic liquid catalyst and a mixture of C5+ alpha olefins derived from waste plastic to produce a base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a VI greater than 55. We also provide a base oil made by the process.
摘要翻译： 我们提供了一种方法，其包括在反应器中在离子液体催化剂和一种或多种C 5+α-烯烃的存在下使沸点低于82℃的一种或多种烯烃低聚以产生运动粘度为100的基础油 ℃，36mm 2 / s以上，VI大于55; 并且其中沸点小于82℃的一种或多种烯烃占供给反应器的烯烃的总混合物的大于50重量％。 我们提供一种方法，其包括在离子液体催化剂存在下使具有低沸点的烯烃和衍生自废塑料的C5 +α烯烃的混合物低聚以产生在40℃下具有大于1100mm 2的运动粘度的基础油 / s，VI大于55.我们还提供了一个由该过程制成的基础油。
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公开(公告)号：US20120149612A1
公开(公告)日：2012-06-14
申请号：US12966638
申请日：2010-12-13
IPC分类号： C10M169/04 , C07C2/02
CPC分类号： C10M107/02 , C10G50/02 , C10G2400/10 , C10M107/06 , C10M2205/024 , C10M2205/0245 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2240/04 , C10M2205/028 , C10M2205/0285
摘要： A process for making base oil, comprising: oligomerizing one or more olefins having a boiling point less than 82° C. in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 1100 mm2/s or higher. Also, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 300 mm2/s or higher and a low cloud point, wherein a wt % yield of products boiling at 482° C.+ (900° F.+) is at least 65 wt % of a total yield of products from the oligomerizing. Additionally, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a low cloud point.
摘要翻译： 一种制备基础油的方法，包括：在离子液体催化剂存在下，使沸点小于82℃的一种或多种烯烃低聚，生成在40℃下的运动粘度为1100mm 2 / s以上。 而且，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生在40℃下的运动粘度为300mm 2 / s或更高和低浊点的基础油，其中wt％产率 的沸点为482℃的产物+（900°F +）是来自低聚产物的总产率的至少65重量％。 另外，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生具有大于1100mm 2 / s和低浊点的40℃下的运动粘度的基础油。
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3.发明申请METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER 审中-公开制备具有超过20 WT％共轭聚合物的酸催化剂的方法公开(公告)号：US20110319258A1
公开(公告)日：2011-12-29
申请号：US13228143
申请日：2011-09-08
CPC分类号： B01J31/06 , B01J31/0284 , B01J31/0298 , B01J2231/32 , C07C2/58 , C07C2527/126 , C07C2531/02 , C07C2531/06
摘要： A method to make an acidic ionic liquid catalyst, by mixing aluminum chloride in the presence of a hydrocarbon solvent, an organic chloride, and optionally an ionic liquid; wherein the acidic ionic liquid catalyst does not precipitate out solids; and wherein the acidic ionic liquid catalyst has greater than 20 wt % conjunct polymer and a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0. Also a method to make the acidic ionic liquid catalyst comprising: a. mixing aluminum chloride in the presence of a hydrocarbon solvent, and an organic chloride, to make an acid catalyst phase comprising a conjunct polymer; b. adding hydrogen chloride to the acid catalyst phase.
摘要翻译： 一种通过在烃溶剂，有机氯化物和任选的离子液体的存在下混合氯化铝来制备酸性离子液体催化剂的方法; 其中所述酸性离子液体催化剂不会沉淀出固体; 并且其中所述酸性离子液体催化剂具有大于20重量％的结合聚合物，并且Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 还有一种制备酸性离子液体催化剂的方法，包括：a。 在烃溶剂和有机氯化物的存在下混合氯化铝，以制备包含结合聚合物的酸催化剂相; b。 在酸催化剂相中加入氯化氢。
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4.发明授权Process for hydrocarbon conversion using, a method to make, and compositions of, an acid catalyst 有权用于烃转化的方法，酸催化剂的制备方法和组合物公开(公告)号：US08889934B2
公开(公告)日：2014-11-18
申请号：US12335476
申请日：2008-12-15
CPC分类号： B01J31/06 , B01J31/0284 , B01J31/0298 , B01J2231/32 , C07C2/58 , C07C2527/126 , C07C2531/02 , C07C2531/06
摘要： A process for hydrocarbon conversion, comprising: contacting a hydrocarbon with an acid catalyst containing greater than 15 wt % conjunct polymer. The acid catalyst has a molar ratio of Al to a heteroatom selected from the group of N, P, O, S, and combinations thereof greater than 2.0. The hydrocarbon is converted during the contacting. Also a method to make a catalyst having greater than 15 wt % conjunct polymer and a high molar ratio of Al to the heteroatom, wherein an acidic ionic liquid catalyst is made that is effective for catalyzing a reaction. There are also provided catalyst compositions having greater than 15 wt % conjunct polymer.
摘要翻译： 烃转化方法，包括：使烃与含有大于15重量％结合聚合物的酸催化剂接触。 酸催化剂具有Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 在接触期间碳氢化合物被转化。 还有一种制备具有大于15重量％结合聚合物和高摩尔比Al与杂原子的催化剂的方法，其中制备有效催化反应的酸性离子液体催化剂。 还提供了具有大于15重量％结合聚合物的催化剂组合物。
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5.发明申请公开(公告)号：US20120004095A1
公开(公告)日：2012-01-05
申请号：US13228171
申请日：2011-09-08
CPC分类号： B01J31/06 , B01J31/0284 , B01J31/0298 , B01J2231/32 , C07C2/58 , C07C2527/126 , C07C2531/02 , C07C2531/06
摘要： An acid catalyst effective for a conversion of a hydrocarbon, comprising greater than 20 wt % of a conjunct polymer, and an ionic liquid catalyst; wherein the acid catalyst has a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0; and wherein the conversion is alkylation, isomerization, hydrocracking, polymerization, dimerization, oligomerization, acylation, acetylation, metathesis, copolymerization, dehalogenation, dehydration, olefin hydrogenation, or combinations thereof. Also, an acid catalyst effective for a conversion of a hydrocarbon, comprising greater than 15 wt % halide-containing conjunct polymer, and a Lewis acid; wherein less than 0.1 wt % solid precipitates from the catalyst when it is held for three hours or longer at 25° C. or below.
摘要翻译： 一种有效用于转化烃的酸催化剂，其包含大于20重量％的结合聚合物和离子液体催化剂; 其中所述酸催化剂具有Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0; 并且其中转化为烷基化，异构化，加氢裂化，聚合，二聚，低聚，酰化，乙酰化，复分解，共聚，脱卤，脱水，烯烃氢化或其组合。 另外，一种有效用于转化烃的酸催化剂，其包含大于15重量％的含卤化物的结合聚合物和路易斯酸; 其中当在25℃或更低温度下保持3小时或更长时间时，小于0.1重量％的固体从催化剂中沉淀出来。
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公开(公告)号：US08524968B2
公开(公告)日：2013-09-03
申请号：US12966638
申请日：2010-12-13
IPC分类号： C07C2/04 , C07C2/08 , C10M143/00
CPC分类号： C10M107/02 , C10G50/02 , C10G2400/10 , C10M107/06 , C10M2205/024 , C10M2205/0245 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2240/04 , C10M2205/028 , C10M2205/0285
摘要： A process for making base oil, comprising: oligomerizing one or more olefins having a boiling point less than 82° C. in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 1100 mm2/s or higher. Also, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 300 mm2/s or higher and a low cloud point, wherein a wt % yield of products boiling at 482° C.+ (900° F.+) is at least 65 wt % of a total yield of products from the oligomerizing. Additionally, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a low cloud point.
摘要翻译： 一种制备基础油的方法，包括：在离子液体催化剂存在下，使沸点小于82℃的一种或多种烯烃低聚，生成在40℃下的运动粘度为1100mm 2 / s以上。 而且，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生在40℃下的运动粘度为300mm 2 / s或更高和低浊点的基础油，其中wt％产率 的沸点为482℃的产物+（900°F +）是来自低聚产物的总产率的至少65重量％。 另外，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生具有大于1100mm 2 / s和低浊点的40℃下的运动粘度的基础油。
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7.发明申请PROCESS FOR PRODUCING A LOW VOLATILITY GASOLINE BLENDING COMPONENT AND A MIDDLE DISTILLATE USING AN IONIC LIQUID 有权用于生产低挥发性汽油混合组分的方法和使用离子液体的中间馏分公开(公告)号：US20110147269A1
公开(公告)日：2011-06-23
申请号：US13035265
申请日：2011-02-25
IPC分类号： C10G57/00
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 4 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译： 一种制备低挥发性汽油调和组分和中间馏分的方法，包括使含离子液体催化剂的包含至少一种具有2至4个碳原子的烯烃和至少一种具有4至6个碳原子的链烷烃的烃流烷烃化， 无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。 另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分 。 而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。
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公开(公告)号：US20100025294A1
公开(公告)日：2010-02-04
申请号：US12184069
申请日：2008-07-31
IPC分类号： C10G49/22
CPC分类号： C10G29/205 , C10G17/09 , C10G2300/1022 , C10G2300/1033 , C10G2300/1081 , C10G2300/1088 , C10G2300/301 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： A process for producing a middle distillate or a middle distillate blending component, comprising contacting a feed comprising an olefin, an isoparaffin, and less than 5 wt % oligomerized olefin, in an ionic liquid alkylation zone with an acidic haloaluminate ionic liquid, at alkylation conditions; and recovering an effluent comprising an alkylated product that has greater than 35 vol % C10+ and less than 1 vol % C55+. Also processes for producing a middle distillate by alkylating isobutane and butene in the presence of defined chloroaluminate ionic liquid catalysts, wherein a separating step separates the middle distillate and wherein the middle distillate is from 20 wt % or higher of the total alkylate product. Also a process for producing middle distillate with FC cracker feed comprising olefins. A separated middle distillate has greater than 30 vol % C10+, less than 1 vol % C55+, and a cloud point less than −50° C.
摘要翻译： 一种制备中间馏分或中间馏分共混组分的方法，包括在烷基化条件下使包含烯烃，异链烷烃和少于5重量％的低聚烯烃的进料在离子液体烷基化区与酸性卤化铝离子液体接触 ; 并回收含有大于35体积％C 10+且小于1体积％C 55+的烷基化产物的流出物。 还有在定义的氯铝酸盐离子液体催化剂的存在下，通过烷基化异丁烷和丁烯生产中间馏分的方法，其中分离步骤分离中间馏分，其中中间馏分为总烷基化产物的20重量％或更高。 还有一种生产含有烯烃的FC裂化器进料的中间馏分的方法。 分离的中间馏分具有大于30体积％的C10 +，小于1体积％的C55 +和浊点小于-50℃。
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9.发明授权Process for producing a low volatility gasoline blending component and a middle distillate using an ionic liquid 有权使用离子液体生产低挥发性汽油调和组分和中间馏分的方法公开(公告)号：US08252968B2
公开(公告)日：2012-08-28
申请号：US13035265
申请日：2011-02-25
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 4 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译： 一种制备低挥发性汽油调和组分和中间馏分的方法，包括使含离子液体催化剂的包含至少一种具有2至4个碳原子的烯烃和至少一种具有4至6个碳原子的链烷烃的烃流烷烃化， 无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。 另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分 。 而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。
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10.发明申请PROCESS FOR MAKING A HIGH VISCOSITY BASE OIL WITH AN IMPROVED VISCOSITY INDEX 有权具有改进粘度指数的高粘度基油的制备方法公开(公告)号：US20120149953A1
公开(公告)日：2012-06-14
申请号：US12966738
申请日：2010-12-13
CPC分类号： C10G50/00 , B01J31/0284 , B01J31/40 , B01J2231/20 , C10G1/002 , C10G3/00 , C10G57/02 , C10G2300/1022 , C10G2300/1088 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/4025 , C10G2400/10 , Y02P30/20
摘要： We provide a process, comprising oligomerizing one or more olefins having a boiling point less than 82° C. in a presence of an ionic liquid catalyst and one or more C5+ alpha olefins in a reactor to produce a base oil having a kinematic viscosity at 100° C. of 36 mm2/s or higher and a VI greater than 55; and wherein the one or more olefins having the boiling point less than 82° C. comprise greater than 50 wt % of a total mixture of olefins fed to the reactor. We provide a process, comprising oligomerizing olefins having a low boiling point in a presence of an ionic liquid catalyst and a mixture of C5+ alpha olefins derived from waste plastic to produce a base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a VI greater than 55. We also provide a base oil made by the process.
摘要翻译： 我们提供了一种方法，其包括在反应器中在离子液体催化剂和一种或多种C 5+α-烯烃的存在下使沸点低于82℃的一种或多种烯烃低聚以产生运动粘度为100的基础油 ℃，36mm 2 / s以上，VI大于55; 并且其中沸点小于82℃的一种或多种烯烃占供给反应器的烯烃的总混合物的大于50重量％。 我们提供一种方法，其包括在离子液体催化剂存在下使具有低沸点的烯烃和衍生自废塑料的C5 +α烯烃的混合物低聚以产生在40℃下具有大于1100mm 2的运动粘度的基础油 / s，VI大于55.我们还提供了一个由该过程制成的基础油。
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