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公开(公告)号：US20100025294A1
公开(公告)日：2010-02-04
申请号：US12184069
申请日：2008-07-31
IPC分类号： C10G49/22
CPC分类号： C10G29/205 , C10G17/09 , C10G2300/1022 , C10G2300/1033 , C10G2300/1081 , C10G2300/1088 , C10G2300/301 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： A process for producing a middle distillate or a middle distillate blending component, comprising contacting a feed comprising an olefin, an isoparaffin, and less than 5 wt % oligomerized olefin, in an ionic liquid alkylation zone with an acidic haloaluminate ionic liquid, at alkylation conditions; and recovering an effluent comprising an alkylated product that has greater than 35 vol % C10+ and less than 1 vol % C55+. Also processes for producing a middle distillate by alkylating isobutane and butene in the presence of defined chloroaluminate ionic liquid catalysts, wherein a separating step separates the middle distillate and wherein the middle distillate is from 20 wt % or higher of the total alkylate product. Also a process for producing middle distillate with FC cracker feed comprising olefins. A separated middle distillate has greater than 30 vol % C10+, less than 1 vol % C55+, and a cloud point less than −50° C.
摘要翻译： 一种制备中间馏分或中间馏分共混组分的方法，包括在烷基化条件下使包含烯烃，异链烷烃和少于5重量％的低聚烯烃的进料在离子液体烷基化区与酸性卤化铝离子液体接触 ; 并回收含有大于35体积％C 10+且小于1体积％C 55+的烷基化产物的流出物。 还有在定义的氯铝酸盐离子液体催化剂的存在下，通过烷基化异丁烷和丁烯生产中间馏分的方法，其中分离步骤分离中间馏分，其中中间馏分为总烷基化产物的20重量％或更高。 还有一种生产含有烯烃的FC裂化器进料的中间馏分的方法。 分离的中间馏分具有大于30体积％的C10 +，小于1体积％的C55 +和浊点小于-50℃。
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公开(公告)号：US07923593B2
公开(公告)日：2011-04-12
申请号：US12184069
申请日：2008-07-31
CPC分类号： C10G29/205 , C10G17/09 , C10G2300/1022 , C10G2300/1033 , C10G2300/1081 , C10G2300/1088 , C10G2300/301 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/06 , C10G2400/08
摘要： A process for producing a middle distillate or a middle distillate blending component, comprising contacting a feed comprising an olefin, an isoparaffin, and less than 5 wt % oligomerized olefin, in an ionic liquid alkylation zone with an acidic haloaluminate ionic liquid, at alkylation conditions; and recovering an effluent comprising an alkylated product that has greater than 35 vol % C10+ and less than 1 vol % C55+. Also processes for producing a middle distillate by alkylating isobutane and butene in the presence of defined chloroaluminate ionic liquid catalysts, wherein a separating step separates the middle distillate and wherein the middle distillate is from 20 wt % or higher of the total alkylate product. Also a process for producing middle distillate with FC cracker feed comprising olefins. A separated middle distillate has greater than 30 vol % C10+, less than 1 vol % C55+, and a cloud point less than −50° C.
摘要翻译： 一种制备中间馏分或中间馏分共混组分的方法，包括在烷基化条件下使包含烯烃，异链烷烃和少于5重量％的低聚烯烃的进料在离子液体烷基化区与酸性卤化铝离子液体接触 ; 并回收含有大于35体积％C 10+且小于1体积％C 55+的烷基化产物的流出物。 还有在定义的氯铝酸盐离子液体催化剂的存在下，通过烷基化异丁烷和丁烯生产中间馏分的方法，其中分离步骤分离中间馏分，其中中间馏分为总烷基化产物的20重量％或更高。 还有一种生产含有烯烃的FC裂化器进料的中间馏分的方法。 分离的中间馏分具有大于30体积％的C10 +，小于1体积％的C55 +和浊点小于-50℃。
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3.发明申请PROCESS FOR PRODUCING A LOW VOLATILITY GASOLINE BLENDING COMPONENT AND A MIDDLE DISTILLATE 有权生产低挥发性汽油混合组分和中间馏分的方法公开(公告)号：US20100025292A1
公开(公告)日：2010-02-04
申请号：US12184109
申请日：2008-07-31
IPC分类号： C10G57/00
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译： 一种生产低挥发性汽油调和组分和中间馏分的方法，包括使含有2-6个碳原子的至少一种烯烃和至少一种具有4至6个碳原子的链烷烃的烃流与离子液体催化剂烷基化，和 无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。 另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分 。 而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。
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4.发明授权Process for producing a low volatility gasoline blending component and a middle distillate 有权制备低挥发性汽油调和成分和中间馏分的方法公开(公告)号：US07919663B2
公开(公告)日：2011-04-05
申请号：US12184109
申请日：2008-07-31
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 6 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译： 一种生产低挥发性汽油调和组分和中间馏分的方法，包括使含有2-6个碳原子的至少一种烯烃和至少一种具有4至6个碳原子的链烷烃的烃流与离子液体催化剂烷基化，和 无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。 另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分 。 而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。
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公开(公告)号：US20100025298A1
公开(公告)日：2010-02-04
申请号：US12184121
申请日：2008-07-31
IPC分类号： C10G35/06
CPC分类号： C10G50/00 , C10G2300/1022 , C10G2300/1081 , C10G2300/1092 , C10G2300/202 , C10G2300/30 , C10G2300/307 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/08
摘要： A process for producing a jet fuel, comprising contacting an olefin and an isoparaffin with an unsupported catalyst system comprising an ionic liquid catalyst and a halide containing additive in an alkylation zone under alkylation conditions to make an alkylate product, and recovering the jet fuel from the alkylate product, wherein the jet fuel meets the boiling point, flash point, smoke point, heat of combustion, and freeze point requirements for Jet A-1 fuel. Also a process for producing a jet fuel, comprising providing a feed produced in a FC cracker comprising olefins, mixing the feed with an isoparaffin, alkylating the mixed feed in an ionic liquid alkylation zone, and separating the jet fuel from the alkylated product. We also provide a process comprising alkylating isobutane and butene in the presence of specific chloroaluminate ionic liquid catalysts, to produce a jet fuel.
摘要翻译： 一种用于生产喷气燃料的方法，包括使烯烃和异链烷烃与烷基化条件下在烷基化区中含有离子液体催化剂和含卤化物的添加剂的非载体催化剂体系接触以制备烷基化物产物，并从 烷基化产物，其中喷气燃料满足Jet A-1燃料的沸点，闪点，烟点，燃烧热和冷冻点要求。 还有一种生产喷气燃料的方法，包括提供在包含烯烃的FC裂化器中产生的进料，将进料与异链烷烃混合，在离子液体烷基化区烷基化混合进料，以及将喷气燃料与烷基化产物分离。 我们还提供了一种方法，包括在特定的氯铝酸盐离子液体催化剂存在下烷基化异丁烷和丁烯，以产生喷气燃料。
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公开(公告)号：US20100025289A1
公开(公告)日：2010-02-04
申请号：US12184130
申请日：2008-07-31
IPC分类号： C10L1/00
CPC分类号： C10G50/00
摘要： A middle distillate, comprising hydrocarbons having a boiling range between 150° C. and 350° C., a NMR branching index greater than 60, and a CH3/CH2 hydrogen ratio greater than 2.6. Also, there is provided the middle distillate made by a process compressing alkylating an isoparaffin with an olefin under alkylation conditions over an unsupported ionic liquid catalyst, and providing an amount of halide containing additive to the alkylating step to achieve the NMR branching index and the CH3/CH2 hydrogen ratio.
摘要翻译： 中间馏分，其包含沸点在150℃和350℃之间的烃，NMR支化指数大于60，CH 3 / CH 2氢比大于2.6的烃。 另外，提供了通过在烷基化条件下在非负载离子液体催化剂上压缩烷基化异链烷烃与烯烃的方法制得的中间馏分，并且在烷基化步骤中提供一定量的含有卤化物的添加剂以获得NMR支化指数和CH3 / CH 2氢比。
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公开(公告)号：US07955495B2
公开(公告)日：2011-06-07
申请号：US12184130
申请日：2008-07-31
IPC分类号： C10L1/08
CPC分类号： C10G50/00
摘要： A middle distillate, comprising hydrocarbons having a boiling range between 150° C. and 350° C., a NMR branching index greater than 60, and a CH3/CH2 hydrogen ratio greater than 2.6. Also, there is provided the middle distillate made by a process compressing alkylating an isoparaffin with an olefin under alkylation conditions over an unsupported ionic liquid catalyst, and providing an amount of halide containing additive to the alkylating step to achieve the NMR branching index and the CH3/CH2 hydrogen ratio.
摘要翻译： 中间馏分，其包含沸点在150℃和350℃之间的烃，NMR支化指数大于60，CH 3 / CH 2氢比大于2.6的烃。 另外，提供了通过在烷基化条件下在非负载离子液体催化剂上压缩烷基化异链烷烃与烯烃的方法制得的中间馏分，并且在烷基化步骤中提供一定量的含有卤化物的添加剂以获得NMR支化指数和CH3 / CH 2氢比。
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公开(公告)号：US07919664B2
公开(公告)日：2011-04-05
申请号：US12184121
申请日：2008-07-31
CPC分类号： C10G50/00 , C10G2300/1022 , C10G2300/1081 , C10G2300/1092 , C10G2300/202 , C10G2300/30 , C10G2300/307 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/08
摘要： A process for producing a jet fuel, comprising contacting an olefin and an isoparaffin with an unsupported catalyst system comprising an ionic liquid catalyst and a halide containing additive in an alkylation zone under alkylation conditions to make an alkylate product, and recovering the jet fuel from the alkylate product, wherein the jet fuel meets the boiling point, flash point, smoke point, heat of combustion, and freeze point requirements for Jet A-1 fuel. Also a process for producing a jet fuel, comprising providing a feed produced in a FC cracker comprising olefins, mixing the feed with an isoparaffin, alkylating the mixed feed in an ionic liquid alkylation zone, and separating the jet fuel from the alkylated product. We also provide a process comprising alkylating isobutane and butene in the presence of specific chloroaluminate ionic liquid catalysts, to produce a jet fuel.
摘要翻译： 一种用于生产喷气燃料的方法，包括使烯烃和异链烷烃与烷基化条件下在烷基化区中包含离子液体催化剂和含卤化物的添加剂的非载体催化剂体系接触以制备烷基化物产物，并从 烷基化产物，其中喷气燃料满足Jet A-1燃料的沸点，闪点，烟点，燃烧热和冷冻点要求。 还有一种生产喷气燃料的方法，包括提供在包含烯烃的FC裂化器中产生的进料，将进料与异链烷烃混合，在离子液体烷基化区烷基化混合进料，以及将喷气燃料与烷基化产物分离。 我们还提供了一种方法，包括在特定的氯铝酸盐离子液体催化剂存在下烷基化异丁烷和丁烯，以产生喷气燃料。
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公开(公告)号：US08524968B2
公开(公告)日：2013-09-03
申请号：US12966638
申请日：2010-12-13
IPC分类号： C07C2/04 , C07C2/08 , C10M143/00
CPC分类号： C10M107/02 , C10G50/02 , C10G2400/10 , C10M107/06 , C10M2205/024 , C10M2205/0245 , C10N2220/021 , C10N2220/022 , C10N2230/02 , C10N2240/04 , C10M2205/028 , C10M2205/0285
摘要： A process for making base oil, comprising: oligomerizing one or more olefins having a boiling point less than 82° C. in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 1100 mm2/s or higher. Also, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 300 mm2/s or higher and a low cloud point, wherein a wt % yield of products boiling at 482° C.+ (900° F.+) is at least 65 wt % of a total yield of products from the oligomerizing. Additionally, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a low cloud point.
摘要翻译： 一种制备基础油的方法，包括：在离子液体催化剂存在下，使沸点小于82℃的一种或多种烯烃低聚，生成在40℃下的运动粘度为1100mm 2 / s以上。 而且，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生在40℃下的运动粘度为300mm 2 / s或更高和低浊点的基础油，其中wt％产率 的沸点为482℃的产物+（900°F +）是来自低聚产物的总产率的至少65重量％。 另外，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生具有大于1100mm 2 / s和低浊点的40℃下的运动粘度的基础油。
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10.发明申请PROCESS FOR PRODUCING A LOW VOLATILITY GASOLINE BLENDING COMPONENT AND A MIDDLE DISTILLATE USING AN IONIC LIQUID 有权用于生产低挥发性汽油混合组分的方法和使用离子液体的中间馏分公开(公告)号：US20110147269A1
公开(公告)日：2011-06-23
申请号：US13035265
申请日：2011-02-25
IPC分类号： C10G57/00
CPC分类号： C10G57/005 , C10G2300/1022 , C10G2300/1081 , C10G2300/1088 , C10G2300/20 , C10G2300/301 , C10G2300/304 , C10G2300/305 , C10G2300/4025 , C10G2300/80 , C10G2400/02 , C10G2400/04 , C10G2400/08
摘要： A process for producing a low volatility gasoline blending component and a middle distillate, comprising alkylating a hydrocarbon stream comprising at least one olefin having from 2 to 4 carbon atoms and at least one paraffin having from 4 to 6 carbon atoms with an ionic liquid catalyst and an unsupported halide containing additive, and separating the alkylate into at least the low volatility gasoline blending component and the middle distillate, wherein the middle distillate is a fuel suitable for use as a jet fuel or jet fuel blending component. Also, a process for producing a gasoline blending component and a middle distillate, comprising adjusting a level of a halide containing additive provided to an ionic liquid alkylation reactor to shift selectivity towards heavier products, and recovering a low volatility gasoline blending component and the middle distillate. Also, processes comprising alkylating isobutane with butene over specific chloroaluminate ionic liquids.
摘要翻译： 一种制备低挥发性汽油调和组分和中间馏分的方法，包括使含离子液体催化剂的包含至少一种具有2至4个碳原子的烯烃和至少一种具有4至6个碳原子的链烷烃的烃流烷烃化， 无载体的含卤化物的添加剂，并将烷基化物分离成至少低挥发性汽油调和组分和中间馏分，其中中间馏分是适合用作喷气燃料或喷气燃料混合组分的燃料。 另外，制备汽油调和成分和中间馏分的方法，包括调节提供给离子液体烷基化反应器的含卤化物添加剂的含量以使选择性向较重的产物转移，以及回收低挥发性汽油调和组分和中间馏分 。 而且，包括在特定氯铝酸盐离子液体上使异丁烷与丁烯烷基化的方法。
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