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    METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER
    1.
    发明申请
    METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER 审中-公开
    制备具有超过20 WT％共轭聚合物的酸催化剂的方法

    公开(公告)号：US20110319258A1

    公开(公告)日：2011-12-29

    申请号：US13228143

    申请日：2011-09-08

    申请人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    发明人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： B01J31/06 ,  C08F4/52

    CPC分类号： B01J31/06 ,  B01J31/0284 ,  B01J31/0298 ,  B01J2231/32 ,  C07C2/58 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/06

    摘要： A method to make an acidic ionic liquid catalyst, by mixing aluminum chloride in the presence of a hydrocarbon solvent, an organic chloride, and optionally an ionic liquid; wherein the acidic ionic liquid catalyst does not precipitate out solids; and wherein the acidic ionic liquid catalyst has greater than 20 wt % conjunct polymer and a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0. Also a method to make the acidic ionic liquid catalyst comprising: a. mixing aluminum chloride in the presence of a hydrocarbon solvent, and an organic chloride, to make an acid catalyst phase comprising a conjunct polymer; b. adding hydrogen chloride to the acid catalyst phase.

    摘要翻译： 一种通过在烃溶剂，有机氯化物和任选的离子液体的存在下混合氯化铝来制备酸性离子液体催化剂的方法; 其中所述酸性离子液体催化剂不会沉淀出固体; 并且其中所述酸性离子液体催化剂具有大于20重量％的结合聚合物，并且Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 还有一种制备酸性离子液体催化剂的方法，包括：a。 在烃溶剂和有机氯化物的存在下混合氯化铝，以制备包含结合聚合物的酸催化剂相; b。 在酸催化剂相中加入氯化氢。

    Process for hydrocarbon conversion using, a method to make, and compositions of, an acid catalyst
    2.
    发明授权
    Process for hydrocarbon conversion using, a method to make, and compositions of, an acid catalyst 有权
    用于烃转化的方法，酸催化剂的制备方法和组合物

    公开(公告)号：US08889934B2

    公开(公告)日：2014-11-18

    申请号：US12335476

    申请日：2008-12-15

    申请人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    发明人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： C07C5/03 ,  B01J31/06 ,  C07C2/58 ,  B01J31/02

    CPC分类号： B01J31/06 ,  B01J31/0284 ,  B01J31/0298 ,  B01J2231/32 ,  C07C2/58 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/06

    摘要： A process for hydrocarbon conversion, comprising: contacting a hydrocarbon with an acid catalyst containing greater than 15 wt % conjunct polymer. The acid catalyst has a molar ratio of Al to a heteroatom selected from the group of N, P, O, S, and combinations thereof greater than 2.0. The hydrocarbon is converted during the contacting. Also a method to make a catalyst having greater than 15 wt % conjunct polymer and a high molar ratio of Al to the heteroatom, wherein an acidic ionic liquid catalyst is made that is effective for catalyzing a reaction. There are also provided catalyst compositions having greater than 15 wt % conjunct polymer.

    摘要翻译： 烃转化方法，包括：使烃与含有大于15重量％结合聚合物的酸催化剂接触。 酸催化剂具有Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 在接触期间碳氢化合物被转化。 还有一种制备具有大于15重量％结合聚合物和高摩尔比Al与杂原子的催化剂的方法，其中制备有效催化反应的酸性离子液体催化剂。 还提供了具有大于15重量％结合聚合物的催化剂组合物。

    ACID CATALYST COMPOSITION HAVING A HIGH LEVEL OF CONJUNCT POLYMER.
    3.
    发明申请
    ACID CATALYST COMPOSITION HAVING A HIGH LEVEL OF CONJUNCT POLYMER. 审中-公开
    酸性催化剂组合物具有高水平的共聚聚合物。

    公开(公告)号：US20120004095A1

    公开(公告)日：2012-01-05

    申请号：US13228171

    申请日：2011-09-08

    申请人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    发明人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： B01J31/06 ,  C08F4/00

    CPC分类号： B01J31/06 ,  B01J31/0284 ,  B01J31/0298 ,  B01J2231/32 ,  C07C2/58 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/06

    摘要： An acid catalyst effective for a conversion of a hydrocarbon, comprising greater than 20 wt % of a conjunct polymer, and an ionic liquid catalyst; wherein the acid catalyst has a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0; and wherein the conversion is alkylation, isomerization, hydrocracking, polymerization, dimerization, oligomerization, acylation, acetylation, metathesis, copolymerization, dehalogenation, dehydration, olefin hydrogenation, or combinations thereof. Also, an acid catalyst effective for a conversion of a hydrocarbon, comprising greater than 15 wt % halide-containing conjunct polymer, and a Lewis acid; wherein less than 0.1 wt % solid precipitates from the catalyst when it is held for three hours or longer at 25° C. or below.

    摘要翻译： 一种有效用于转化烃的酸催化剂，其包含大于20重量％的结合聚合物和离子液体催化剂; 其中所述酸催化剂具有Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0; 并且其中转化为烷基化，异构化，加氢裂化，聚合，二聚，低聚，酰化，乙酰化，复分解，共聚，脱卤，脱水，烯烃氢化或其组合。 另外，一种有效用于转化烃的酸催化剂，其包含大于15重量％的含卤化物的结合聚合物和路易斯酸; 其中当在25℃或更低温度下保持3小时或更长时间时，小于0.1重量％的固体从催化剂中沉淀出来。

    Process for making a high viscosity base oil with an improved viscosity index
    4.
    发明授权
    Process for making a high viscosity base oil with an improved viscosity index 有权
    制备具有改进的粘度指数的高粘度基础油的方法

    公开(公告)号：US08222471B2

    公开(公告)日：2012-07-17

    申请号：US12966738

    申请日：2010-12-13

    申请人： Saleh Elomari ,  Stephen J. Miller ,  Sven Ivar Hommeltoft ,  Hye-Kyung C. Timken

    发明人： Saleh Elomari ,  Stephen J. Miller ,  Sven Ivar Hommeltoft ,  Hye-Kyung C. Timken

    IPC分类号： C07C2/22 ,  C07C2/08

    CPC分类号： C10G50/00 ,  B01J31/0284 ,  B01J31/40 ,  B01J2231/20 ,  C10G1/002 ,  C10G3/00 ,  C10G57/02 ,  C10G2300/1022 ,  C10G2300/1088 ,  C10G2300/301 ,  C10G2300/302 ,  C10G2300/304 ,  C10G2300/4025 ,  C10G2400/10 ,  Y02P30/20

    摘要： We provide a process, comprising oligomerizing one or more olefins having a boiling point less than 82° C. in a presence of an ionic liquid catalyst and one or more C5+ alpha olefins in a reactor to produce a base oil having a kinematic viscosity at 100° C. of 36 mm2/s or higher and a VI greater than 55; and wherein the one or more olefins having the boiling point less than 82° C. comprise greater than 50 wt % of a total mixture of olefins fed to the reactor. We provide a process, comprising oligomerizing olefins having a low boiling point in a presence of an ionic liquid catalyst and a mixture of C5+ alpha olefins derived from waste plastic to produce a base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a VI greater than 55. We also provide a base oil made by the process.

    摘要翻译： 我们提供了一种方法，其包括在反应器中在离子液体催化剂和一种或多种C 5+α-烯烃的存在下使沸点低于82℃的一种或多种烯烃低聚以产生运动粘度为100的基础油 ℃，36mm 2 / s以上，VI大于55; 并且其中沸点小于82℃的一种或多种烯烃占供给反应器的烯烃的总混合物的大于50重量％。 我们提供一种方法，其包括在离子液体催化剂存在下使具有低沸点的烯烃和衍生自废塑料的C5 +α烯烃的混合物低聚以产生在40℃下具有大于1100mm 2的运动粘度的基础油 / s，VI大于55.我们还提供了一个由该过程制成的基础油。

    PROCESS TO MAKE BASE OIL BY OLIGOMERIZING LOW BOILING OLEFINS
    5.
    发明申请
    PROCESS TO MAKE BASE OIL BY OLIGOMERIZING LOW BOILING OLEFINS 有权
    通过低沸点烯烃低沸点制备基础油的方法

    公开(公告)号：US20120149612A1

    公开(公告)日：2012-06-14

    申请号：US12966638

    申请日：2010-12-13

    申请人： Saleh Elomari ,  Stephen J. Miller ,  Sven Ivar Hommeltoft

    发明人： Saleh Elomari ,  Stephen J. Miller ,  Sven Ivar Hommeltoft

    IPC分类号： C10M169/04 ,  C07C2/02

    CPC分类号： C10M107/02 ,  C10G50/02 ,  C10G2400/10 ,  C10M107/06 ,  C10M2205/024 ,  C10M2205/0245 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2240/04 ,  C10M2205/028 ,  C10M2205/0285

    摘要： A process for making base oil, comprising: oligomerizing one or more olefins having a boiling point less than 82° C. in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 1100 mm2/s or higher. Also, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. of 300 mm2/s or higher and a low cloud point, wherein a wt % yield of products boiling at 482° C.+ (900° F.+) is at least 65 wt % of a total yield of products from the oligomerizing. Additionally, a process, comprising: oligomerizing the olefins in the presence of an ionic liquid catalyst to produce the base oil having a kinematic viscosity at 40° C. greater than 1100 mm2/s and a low cloud point.

    摘要翻译： 一种制备基础油的方法，包括：在离子液体催化剂存在下，使沸点小于82℃的一种或多种烯烃低聚，生成在40℃下的运动粘度为1100mm 2 / s以上。 而且，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生在40℃下的运动粘度为300mm 2 / s或更高和低浊点的基础油，其中wt％产率 的沸点为482℃的产物+（900°F +）是来自低聚产物的总产率的至少65重量％。 另外，一种方法包括：在离子液体催化剂的存在下使烯烃低聚以产生具有大于1100mm 2 / s和低浊点的40℃下的运动粘度的基础油。

    IONIC LIQUID SYSTEM FOR AN ISOPARAFFIN/OLEFIN ALKYLATION
    6.
    发明申请
    IONIC LIQUID SYSTEM FOR AN ISOPARAFFIN/OLEFIN ALKYLATION 审中-公开
    离子液体系统用于异烟碱/烯烃烷基化

    公开(公告)号：US20100158762A1

    公开(公告)日：2010-06-24

    申请号：US12646425

    申请日：2009-12-23

    申请人： Howard S. Lacheen ,  Saleh Elomari

    发明人： Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： B01J8/00 ,  B01J31/06

    CPC分类号： B01J31/0278 ,  B01J31/0284 ,  B01J31/26 ,  B01J31/40 ,  B01J2231/32 ,  C07C2/60 ,  C07C2531/14 ,  C10G29/205 ,  C10G2300/1081 ,  C10G2300/1088 ,  C10G2300/305 ,  Y02P20/584 ,  C07C9/00

    摘要： There is provided an ionic liquid system for isoparaffin/olefin alkylation, comprising a quaternary ammonium chloroaluminate, a conjunct polymer, and a hydrogen chloride. The ionic liquid system has a molar ratio of Al to N from 2.1 to 8.0. Less than 0.1 wt % AlCl3 precipitates from the ionic liquid system when it is held for three hours or longer at or below 25° C. There is also provided an alkylation reactor comprising an ionic liquid catalyst comprising an ammonium chloroaluminate salt, and having a molar ratio of Al to N greater than 2.0, when the ionic liquid catalyst is held at a temperature at or below 25° C. for at least two hours. There is also provided an alkylation reactor comprising an ionic liquid catalyst comprising an alkyl-pyridinium haloaluminate and an impurity.

    摘要翻译： 提供了用于异链烷烃/烯烃烷基化的离子液体体系，其包括氯铝酸季铵，结合聚合物和氯化氢。 离子液体体系的Al与N的摩尔比为2.1〜8.0。 当其在25℃或更低温度下保持3小时或更长时间时，小于0.1重量％的AlCl 3从离子液体体系析出。还提供了一种烷基化反应器，其包括含有氯铝酸铵盐的离子液体催化剂， 当离子液体催化剂保持在25℃或低于25℃的温度下至少2小时时，Al与N之比大于2.0。 还提供了一种烷基化反应器，其包括含有烷基 - 卤化吡啶鎓卤化物和杂质的离子液体催化剂。

    PROCESS TO MAKE A LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN
    10.
    发明申请
    PROCESS TO MAKE A LIQUID CATALYST HAVING A HIGH MOLAR RATIO OF ALUMINUM TO NITROGEN 审中-公开
    制备具有高铝比的氮气的液体催化剂

    公开(公告)号：US20100152518A1

    公开(公告)日：2010-06-17

    申请号：US12335494

    申请日：2008-12-15

    申请人： Howard S. Lacheen ,  Saleh Elomari

    发明人： Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： C07C2/58 ,  B01J31/26

    CPC分类号： C10G45/04 ,  B01J31/0284 ,  B01J31/0298 ,  B01J31/06 ,  B01J2231/32 ,  C07C2/58 ,  C10G29/205 ,  C10G45/00 ,  C10G45/46 ,  C10G47/02 ,  C10G50/00 ,  C10G2300/305 ,  C10G2400/02 ,  C07C9/16

    摘要： A process to make a liquid catalyst having a molar ratio of Al to N greater than 2.0, comprising: a) using an ammonium-based ionic liquid catalyst to catalyze a reaction, wherein the ammonium-based ionic liquid catalyst builds up an impurity during the reaction; and b) mixing the ammonium-based ionic liquid catalyst, having an impurity, with aluminum. There is also provided a process for isoparaffin/olefin alkylation, wherein the ionic liquid catalyst comprises a quaternary ammonium ionic liquid salt; and wherein the ionic liquid catalyst has a molar ratio of Al to N greater than 2.0 when held at a temperature at or below 25° C. for at least two hours. There is also provided a method for making a catalyst having a molar ratio of Al to N greater than 2.0, and a process for hydroconversion comprising maintaining a level of conjunct polymer in an ionic liquid catalyst.

    摘要翻译： 一种制备Al与N的摩尔比大于2.0的液体催化剂的方法，包括：a）使用铵基离子液体催化剂催化反应，其中所述铵基离子液体催化剂在 反应; 和b）将具有杂质的铵基离子液体催化剂与铝混合。 还提供了异链烷烃/烯烃烷基化方法，其中离子液体催化剂包含季铵离子液体盐; 并且其中当所述离子液体催化剂在等于或低于25℃的温度保持至少2小时时，Al与N的摩尔比大于2.0。 还提供了制备Al与N摩尔比大于2.0的催化剂的方法，以及加氢转化方法，包括保持离子液体催化剂中的结合聚合物的含量。