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    High internal phase emulsions (HIPEs) and foams made therefrom
    3.
    发明授权
    High internal phase emulsions (HIPEs) and foams made therefrom 失效
    高内相乳液（HIPE）和由其制成的泡沫

    公开(公告)号：US06303834B1

    公开(公告)日：2001-10-16

    申请号：US09645837

    申请日：2000-08-25

    申请人： Steven W. Mork ,  Gene D. Rose ,  Daniel Patrick Green

    发明人： Steven W. Mork ,  Gene D. Rose ,  Daniel Patrick Green

    IPC分类号： C07C4320

    CPC分类号： B01F17/0028 ,  A61L15/425 ,  A61L15/48 ,  B01F17/005 ,  B01F17/0057 ,  B01F17/0064 ,  C08F2/32 ,  C08G65/2612 ,  C08G65/3344 ,  C08J9/283 ,  C11D1/29

    摘要： High internal phase emulsions (HIPEs), porous polymeric materials made therefrom, and methods for making and using the same. Specific embodiments of the invention include water-in-oil high internal phase emulsions having at least 70 volume percent of an internal aqueous phase and less than 30 volume percent of an external oil phase wherein the oil phase comprises a vinyl polymerizable monomer and a surfactant effective to stabilize the emulsion. The subject surfactants are oil soluble and preferably include an oxyalkylene component.

    摘要翻译： 高内相乳液（HIPE），由其制成的多孔聚合材料及其制备和使用方法。 本发明的具体实施方案包括具有至少70体积％的内部水相和小于30体积％的外部油相的油包水高相位乳液，其中油相包含乙烯基可聚合单体和表面活性剂 以稳定乳液。 主题表面活性剂是油溶性的并且优选包括氧化烯组分。

    High internal phase polyelectrolyte emulsions for the manufacture of superabsorbent polymers and superabsorbent polymers made therefrom
    4.
    发明授权
    High internal phase polyelectrolyte emulsions for the manufacture of superabsorbent polymers and superabsorbent polymers made therefrom 失效
    用于制造由其制备的超吸收聚合物和超吸收聚合物的高内相聚电解质乳液

    公开(公告)号：US06916864B2

    公开(公告)日：2005-07-12

    申请号：US10848314

    申请日：2004-05-18

    申请人： Herbert A. Gartner ,  Steven W. Mork ,  Heike Herr ,  Reed A. Shick ,  John Klier ,  Christopher J. Tucker

    发明人： Herbert A. Gartner ,  Steven W. Mork ,  Heike Herr ,  Reed A. Shick ,  John Klier ,  Christopher J. Tucker

    IPC分类号： A61L15/60 ,  C08F2/32 ,  B01J20/26 ,  B01J20/32 ,  C08J3/24 ,  C08L33/02

    CPC分类号： C08F2/32 ,  A61L15/60 ,  C08L33/02

    摘要： The present invention refers to a high internal phase polyelectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyelectrolyte. The present invention also refers to a process for preparing such emulsions and for inverting these emulsions so as to form films or other patterns of the superabsorbent polymer. Absorbent structures containing SAP films or other patterns prepared by the present invention are also contemplated.

    摘要翻译： 本发明涉及高内相聚电解质乳液，其可用于制造具有两相的超吸收聚合物：i）连续油相，和ii）在聚合之前含有单体水溶液的分散水相和聚电解质 水溶性或水溶胀性或非常轻微的交联形式，其中聚合发生在分散的水相中，并且其中分散的水相含有高浓度的聚电解质。 本发明还涉及一种制备这种乳液并反转这些乳液以形成超吸收性聚合物的膜或其它图案的方法。 也考虑了含有SAP薄膜或本发明制备的其它图案的吸收结构。

    Continuous process for polymerizing, curing and drying high internal phase emulsions
    5.
    发明授权
    Continuous process for polymerizing, curing and drying high internal phase emulsions 有权
    用于聚合，固化和干燥高内相乳液的连续方法

    公开(公告)号：US06299808B1

    公开(公告)日：2001-10-09

    申请号：US09586908

    申请日：2000-06-05

    申请人： Steven W. Mork ,  Bruce A. Malone

    发明人： Steven W. Mork ,  Bruce A. Malone

    IPC分类号： B29D700

    CPC分类号： B29C43/22 ,  B29C44/30 ,  B29C67/202 ,  C08J9/28 ,  C08J2201/028 ,  C08J2201/0504

    摘要： The invention comprises a fully continuous process for shaping a high internal phase emulsion (HIPE) with a polymerizable continuous phase into dry foam, comprising 1) providing a high internal phase emulsion (HIPE) comprising (a) at least 70 percent by volume of an eternal phase comprising one or more polymerizable monomer; (b) a surfactant in an amount effective to produce a high internal phase emulsion; and (c) an internal phase; 20 depositing the emulsion onto a lower moving support substrate; 3) leveling the emulsion to a desired thickness above the support substrate; 4) polymerizing the monomers by running the emulsion and the lower moving support substrate through a heating zone for a time sufficient to polymerize at least 75% of the monomer in the HIPE by the end of the heating zone; and 5) drying the polymerized HIPE in a drying zone for a time sufficient to produce a foam having greater than 50% of the internal phase removed.

    摘要翻译： 本发明包括用于将具有可聚合连续相成型为干泡沫的高内相乳液（HIPE）成型为完全连续的方法，其包括1）提供高内相乳液（HIPE），其包含（a）至少70体积％ 永久相包含一种或多种可聚合单体; （b）有效产生高内相乳液的表面活性剂; 和（c）内相; 20将乳液沉积到下移动的支撑基底上; 3）将乳液调平至支撑衬底上方所需的厚度; 4）通过使加热区域使乳液和下部移动的载体基材通过加热区域的末端使得至少75％的HIPE中的单体聚合足够的时间来聚合单体; 和5）在干燥区中干燥聚合的HIPE一段足以产生具有除去内相的50％以上的泡沫的时间。

    Durable, absorbent latex foam composition having high vertical wicking
    6.
    发明授权
    Durable, absorbent latex foam composition having high vertical wicking 有权
    具有高垂直芯吸性能的耐用吸水胶乳泡沫组合物

    公开(公告)号：US06900249B2

    公开(公告)日：2005-05-31

    申请号：US10412922

    申请日：2003-04-14

    申请人： Steven W. Mork ,  Andrew T. Graham

    发明人： Steven W. Mork ,  Andrew T. Graham

    IPC分类号： A41B17/00 ,  A61F5/44 ,  A61F13/49 ,  A61F13/53 ,  A61L20060101 ,  A61L15/00 ,  A61L15/24 ,  A61L15/42 ,  A61L15/44 ,  B65D81/26 ,  C08J9/30

    CPC分类号： A61L15/425 ,  A61L15/24 ,  C08L25/04

    摘要： A durable, conformable, absorbent, hydrophilic, polymeric latex foam composition having a free absorbent capacity of at least 5 grams of a 0.9 weight percent aqueous saline solution per gram of foam and capable of vertically wicking said aqueous saline solution to a height of greater than about 5 cm. In a preferred embodiment, after compression, the latex foam composition remains thin until wet, whereupon it expands and exhibits a high free absorbent capacity and high vertical wicking height.

    摘要翻译： 一种耐久，适应性，吸收性，亲水性的聚合物胶乳泡沫组合物，其具有至少5克0.9重量％的每克泡沫体的盐水溶液的游离吸收能力，并且能够将所述盐水溶液垂直吸湿至高于 约5厘米。 在优选的实施方案中，在压缩之后，胶乳泡沫组合物保持薄至直至湿润，于是其膨胀并表现出高的游离吸收能力和高垂直芯吸高度。

    Manufacture of superabsorbents in high internal phase emulsions
    7.
    发明授权
    Manufacture of superabsorbents in high internal phase emulsions 失效
    高内相乳液中超吸收剂的制造

    公开(公告)号：US06835783B1

    公开(公告)日：2004-12-28

    申请号：US09913621

    申请日：2001-08-15

    申请人： Herbert A. Gartner ,  Steven W. Mork ,  Heike Herr ,  Reed A. Shick ,  John Klier ,  Christopher J. Tucker

    发明人： Herbert A. Gartner ,  Steven W. Mork ,  Heike Herr ,  Reed A. Shick ,  John Klier ,  Christopher J. Tucker

    IPC分类号： A61L1524

    CPC分类号： C08F2/32 ,  A61L15/60 ,  C08L33/02

    摘要： The present invention refers to a high internal phase polyclectrolyte emulsions which are useful for the manufacture of superabsorbent polymers having two phases: i) a continuous oil phase and the ii) a dispersed aqueous phase containing the aqueous monomer solution prior to polymerization and the polyelectrolyte in water-soluble, or water-swellable or very slightly crosslinked form after polymerization, wherein the polymerization occurs in the dispersed aqueous phase and wherein the dispersed aqueous phase contains a high concentration of polyclectrolyte. The present invention also refers to a process for preparing such emulsions and for inverting these emulsions so as to form films or other patterns of the superabsorbent polymer. Absorbent structures containing SAP films or other patterns prepared by the present invention are also contemplated.

    摘要翻译： 本发明涉及一种高内相聚电解质乳液，其可用于制造具有两相的超吸收聚合物：i）连续油相和ii）在聚合之前含有单体水溶液的分散水相和聚合电解质 水溶性或水溶胀性或非常轻微交联的形式，其中聚合发生在分散的水相中，并且其中分散的水相含有高浓度的聚电解质。 本发明还涉及一种制备这种乳液并反转这些乳液以形成超吸收性聚合物的膜或其它图案的方法。 也考虑了含有SAP薄膜或本发明制备的其它图案的吸收结构。