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公开(公告)号：US07049389B2
公开(公告)日：2006-05-23
申请号：US10496139
申请日：2002-12-26
申请人： Toshihide Senzaki , Takahiro Imamura , Kazuyoshi Horibe , Tomoaki Yoshida , Atsuhiko Katayama , Yasuo Wada , Katsuhide Noguchi
发明人： Toshihide Senzaki , Takahiro Imamura , Kazuyoshi Horibe , Tomoaki Yoshida , Atsuhiko Katayama , Yasuo Wada , Katsuhide Noguchi
CPC分类号： C08G10/02
摘要： This invention relates to a process for preparing high-purity aromatic oligomers by effectively separating an organic layer containing aromatic oligomers or the reaction products of a polycyclic aromatic compound with formaldehyde from an aqueous layer containing an acid catalyst in a simplified manner, hitherto regarded difficult to accomplish, and obtaining high-purity aromatic oligomers from the organic layer containing a reduced amount of impurities. In separating the aqueous layer containing the acid catalyst and the organic layer containing the oligomers from the reaction mixture formed by the condensation of a polycyclic aromatic compound and formaldehyde, the emulsion phase is broken by adding a nonionic or cationic surfactant in an effective amount and an alkali in an amount sufficient to neutralize 1–70% of the acid in the acid catalyst, the organic and aqueous layers are separated and the aromatic oligomers are recovered from the organic layer.
摘要翻译： 本发明涉及一种制备高纯度芳族低聚物的方法，该方法通过以简单的方式从含有酸催化剂的水层中有效地分离含有芳族低聚物的有机层或多环芳族化合物与甲醛的反应产物，至今被认为难以 从含有少量杂质的有机层中获得高纯度芳族低聚物。 在将含有酸催化剂的水层和含有低聚物的有机层从由多环芳族化合物和甲醛缩合形成的反应混合物中分离时，通过加入有效量的非离子或阳离子表面活性剂和 碱的量足以中和酸催化剂中的1-70％的酸，分离有机层和水层，并从有机层中回收芳族低聚物。
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2.发明授权公开(公告)号：US06664433B1
公开(公告)日：2003-12-16
申请号：US09958817
申请日：2001-10-15
IPC分类号： C07C705
CPC分类号： C10G29/24 , A01N27/00 , C07C7/005 , C07C7/14875 , C07C7/177 , C10G2400/30 , C07C15/00 , C07C15/24
摘要： This invention provides a process for purifying to a high degree of purity aromatic hydrocarbons containing impurities which are difficult to separate by distillation such as sulfur compounds and nitrogen compounds. The process of this invention for purifying aromatic hydrocarbons comprises treating crude aromatic hydrocarbons with a formaldehyde or with a formaldehyde and a phenol in the presence of an acid catalyst to form oligomers, distilling or evaporating the reaction mixture thereby separating the unreacted aromatic hydrocarbons from the oligomers, and crystallizing or washing with an organic solvent the separated aromatic hydrocarbons. In case the target hydrocarbon is naphthalene, it is possible to prepare naphthalene which has a purity of 99.9999 wt % or more, emits little odor, and can be readily flavored by perfumes. Naphthalene of this quality is used to prepare an insecticide of excellent fragrance.
摘要翻译： 本发明提供了一种纯化到高纯度芳族烃的方法，该方法难以通过蒸馏分离出杂质，例如硫化合物和氮化合物。 用于纯化芳族烃的本发明的方法包括在酸催化剂存在下用甲醛或与甲醛和苯酚处理粗芳烃以形成低聚物，蒸馏或蒸发反应混合物，从而将未反应的芳烃与低聚物分离 ，并用有机溶剂结晶或洗涤分离的芳族烃。 在目标烃为萘的情况下，可以制备纯度为99.9999重量％以上的萘，少量气味，并且可以容易地用香料调理。 这种质量的萘用于制备优良香味的杀虫剂。
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公开(公告)号：US09051422B2
公开(公告)日：2015-06-09
申请号：US12310522
申请日：2007-09-13
CPC分类号： C08G65/18 , C08G65/22 , C08G65/2666 , C08L71/02
摘要： A water-soluble thermally polymerizable oxetane resin composition comprises (A) a water-soluble oxetane compound and (B) at least one heteropolyacid compound selected from heteropolyacids and heteropolyacid salts. The water-soluble oxetane compound may contain one or more oxetane functional groups in the molecule and one or more alcoholic OH groups in the molecule. The heteropolyacids include phosphotungstic acid, phosphomolybdic acid, silicotungstic acid, silicomolybdic acid or mixtures thereof. The heteropolyacid salts include phosphotungstic acid salts, phosphomolybdic acid salts, silicotungstic acid salts, silicomolybdic acid salts or mixtures thereof.
摘要翻译： 水溶性热聚合氧杂环丁烷树脂组合物包含（A）水溶性氧杂环丁烷化合物和（B）至少一种选自杂多酸和杂多酸盐的杂多酸化合物。 水溶性氧杂环丁烷化合物在分子中可以含有一个以上的氧杂环丁烷官能团，在分子中可以含有一个以上的醇类OH基。 杂多酸包括磷钨酸，磷钼酸，硅钨酸，硅钼酸或其混合物。 杂多酸盐包括磷钨酸盐，磷钼酸盐，硅钨酸盐，硅钼酸盐或其混合物。
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公开(公告)号：US20100273941A1
公开(公告)日：2010-10-28
申请号：US12310522
申请日：2007-09-13
IPC分类号： C08F2/18
CPC分类号： C08G65/18 , C08G65/22 , C08G65/2666 , C08L71/02
摘要： Disclosed is a water-soluble, thermally polymerizable oxetane composition essentially comprising a water-soluble oxetane compound and a heteropolyacid. The water-soluble thermally polymerizable oxetane resin composition essentially comprises (A) a water-soluble oxetane compound and (B) at least one heteropolyacid compound selected from heteropolyacids and heteropolyacid salts. The water-soluble oxetane compound may contain one or more oxetane functional groups in the molecule and one or more alcoholic OH groups in the molecule. The heteropolyacids include phosphotungstic acid, phosphomolybdic acid, silicotungstic acid, and silicomolybdic acid and mixtures thereof. The heteropolyacid salts include phosphotungstic acid salts, phosphomolybdic acid salts, silicotungstic acid salts, and silicomolybdic acid salts and mixtures thereof.
摘要翻译： 公开了基本上包含水溶性氧杂环丁烷化合物和杂多酸的水溶性可热聚合的氧杂环丁烷组合物。 水溶性热聚合氧杂环丁烷树脂组合物基本上包含（A）水溶性氧杂环丁烷化合物和（B）至少一种选自杂多酸和杂多酸盐的杂多酸化合物。 水溶性氧杂环丁烷化合物在分子中可以含有一个以上的氧杂环丁烷官能团，在分子中可以含有一个以上的醇类OH基。 杂多酸包括磷钨酸，磷钼酸，硅钨酸和硅钼酸及其混合物。 杂多酸盐包括磷钨酸盐，磷钼酸盐，硅钨酸盐和硅钼酸盐及其混合物。
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5.发明申请公开(公告)号：US20100081785A1
公开(公告)日：2010-04-01
申请号：US12308073
申请日：2007-06-12
CPC分类号： C08F4/06 , C08K3/24 , C08K5/0091 , G03F7/038
摘要： Disclosed is a cationically polymerizable composition which shows improved storage stability and whose polymerization initiation temperature or curing temperature is controlled. In the case where the composition is thermosetting, it yields a cured product of three-dimensional structure excellent in mechanical properties, electrical properties, adhesive properties, heat resistance, moisture resistance, chemical resistance, and the like. The cationically polymerizable composition comprises a cationically polymerizable compound selected from vinyl compounds, lactones, cyclic ethers, and the like, a heteropolyacid selected from phosphotungstic acid, phosphomolybdic acid, silicotungstic acid, silicomolybdic acid, and the like as a cationic polymerization initiator, and a stabilizer selected from heteropolyacid salts as an inhibitor of cationic polymerization.
摘要翻译： 公开了一种显示改进的储存稳定性并且其聚合开始温度或固化温度得到控制的阳离子聚合性组合物。 在组合物为热固性的情况下，得到机械性能，电特性，粘合性，耐热性，耐湿性，耐化学性等优异的三维结构的固化物。 阳离子聚合性组合物包含选自乙烯基化合物，内酯，环状醚等的阳离子聚合性化合物，作为阳离子聚合引发剂的选自磷钨酸，磷钼酸，硅钨酸，硅钼酸等的杂多酸， 选自杂多酸盐的稳定剂作为阳离子聚合的抑制剂。
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6.发明授权公开(公告)号：US08344097B2
公开(公告)日：2013-01-01
申请号：US12308073
申请日：2007-06-12
IPC分类号： C08G59/00
CPC分类号： C08F4/06 , C08K3/24 , C08K5/0091 , G03F7/038
摘要： Disclosed is a cationically polymerizable composition which shows improved storage stability and whose polymerization initiation temperature or curing temperature is controlled. In the case where the composition is thermosetting, it yields a cured product of three-dimensional structure excellent in mechanical properties, electrical properties, adhesive properties, heat resistance, moisture resistance, chemical resistance, and the like. The cationically polymerizable composition comprises a cationically polymerizable compound selected from vinyl compounds, lactones, cyclic ethers, and the like, a heteropolyacid selected from phosphotungstic acid, phosphomolybdic acid, silicotungstic acid, silicomolybdic acid, and the like as a cationic polymerization initiator, and a stabilizer selected from heteropolyacid salts as an inhibitor of cationic polymerization.
摘要翻译： 公开了一种显示改进的储存稳定性并且其聚合开始温度或固化温度得到控制的阳离子聚合性组合物。 在组合物为热固性的情况下，得到机械性能，电特性，粘合性，耐热性，耐湿性，耐化学性等优异的三维结构的固化物。 阳离子聚合性组合物包含选自乙烯基化合物，内酯，环状醚等的阳离子聚合性化合物，作为阳离子聚合引发剂的选自磷钨酸，磷钼酸，硅钨酸，硅钼酸等的杂多酸， 选自杂多酸盐的稳定剂作为阳离子聚合的抑制剂。
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公开(公告)号：US06921842B2
公开(公告)日：2005-07-26
申请号：US10332575
申请日：2001-07-11
摘要： The hydrogenated aromatic oligomer of this invention is represented by the following formula (1) (A-F)n-A (1) (wherein A is a segment comprising mainly a polycyclic aromatic compound, a phenol and at least partly hydrogenated products of these two, F is methylene or dimethylene ether and n is a number in the range of 1-100) and obtained by the reaction of a polycyclic aromatic compound such as naphthalene with formaldehyde or a derivative thereof and a phenol in the presence of an acid catalyst followed by hydrogenation of the product aromatic oligomer. This oligomer is odorless, highly transparent and useful as an improver of the adhesiveness and vibration damping properties when incorporated in resins and rubbers and performs excellently as a vibration damping agent in a wide temperature range.
摘要翻译： 本发明的氢化芳族低聚物由下式（1）表示<？in-line-formula description =“In-line Formulas”end =“lead”？>（AF）n < A（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>（其中A是主要包含多环芳香族化合物，苯酚和这两种化合物的至少部分氢化产物的链段 ，F是亚甲基或二亚甲基醚，n是1-100的数），并且通过在酸催化剂存在下，通过萘与萘甲醛或其衍生物和苯酚之类的多环芳族化合物的反应获得，随后是 通过产物芳族低聚物的氢化。 该低聚物无臭，高度透明，作为粘合性和振动阻尼性能的改进剂并入树脂和橡胶中并且作为减振剂在宽温度范围内表现优异。
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公开(公告)号：US06713591B1
公开(公告)日：2004-03-30
申请号：US10049517
申请日：2002-03-05
IPC分类号： C08G1402
摘要： This invention relates to an aromatic oligomer represented by the following formula (1): (A—F)n—A (1) wherein A is a unit comprising (a) 30-90 wt % of a bicyclic or tricyclic aromatic compound and (b) 10-70 wt % of a phenol, F is methylene or a mixture of methylene and —CH2OCH2— and n is a number of 1-100. The aromatic oligomer is obtained by and reaction of a polycyclic aromatic compound such as naphthalene and benzothiophene, a phenol and formaldehyde compound in the presence of an acid catalyst. The aromatic oligomer is odorless and useful for various applications. In particular, when incorporated in rubber or resin, the aromatic oligomer can perform execellently as a tackifier in a wide temperature range or perform excellently as a vibration damping agent.
摘要翻译： 本发明涉及由下式（1）表示的芳族低聚物：其中A是包含（a）30-90重量％的双环或三环芳族化合物和（b）10-70重量％的苯酚的单元， F是亚甲基或亚甲基和-CH 2 OCH 2 - 的混合物，n是1-100的数。 芳族低聚物通过萘和苯并噻吩等多环芳香族化合物，苯酚和甲醛化合物在酸催化剂的存在下反应而得到。 芳族低聚物无臭，适用于各种应用。 特别是，当结合到橡胶或树脂中时，芳族低聚物可以作为增粘剂在宽温度范围内进行，或作为减震剂表现优异。
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公开(公告)号：US07098268B2
公开(公告)日：2006-08-29
申请号：US10485531
申请日：2002-08-01
CPC分类号： F16F15/08 , C08K5/13 , C08L61/18 , C08L61/34 , F16F1/3605
摘要： This invention relates to a resin composition useful as a vibration-damping agent and the like. The resin composition is formulated by adding 1 wt % or more of styrenated phenol obtained by the reaction of a phenol with styrene to a polycyclic aromatic oligomer obtained by condensing a polycyclic aromatic compound containing 2 to 3 rings and formaldehyde. The polycyclic aromatic oligomer is obtained by the reaction of a polycyclic aromatic compound with formaldehyde and, if necessary, further with a phenol in the presence of an acid catalyst and has a number average molecular weight of 300–1000. The styrenated phenol is obtained by the reaction of 1 mole of a phenol with 1–2.5 moles of styrene in the presence of an acid catalyst.
摘要翻译： 本发明涉及可用作减振剂等的树脂组合物。 通过将通过苯酚与苯乙烯反应得到的苯乙烯苯酚1重量％以上加入到通过使含有2〜3个环和甲醛的多环芳族化合物缩合得到的多环芳族低聚物而配制。 多环芳族低聚物是通过多环芳香族化合物与甲醛的反应而得到的，如果需要，还可以在酸催化剂的存在下与苯酚反应，数均分子量为300〜1000。 苯乙烯苯酚通过在酸催化剂的存在下与1摩尔苯酚与1-2.5摩尔苯乙烯反应获得。
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