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    Use of nuclear aromatic sulfonic acid esters for stabilizing thermoplastic polycarbonates against the effect of gamma-rays
    1.
    发明授权
    Use of nuclear aromatic sulfonic acid esters for stabilizing thermoplastic polycarbonates against the effect of gamma-rays 失效
    使用核芳族磺酸酯来稳定热塑性聚碳酸酯以抵抗伽马射线的影响

    公开(公告)号：US5274009A

    公开(公告)日：1993-12-28

    申请号：US951445

    申请日：1992-09-25

    申请人： Ulrich Grigo ,  Jurgen Kirsch ,  Karsten-Josef Idel ,  Charles Lundy

    发明人： Ulrich Grigo ,  Jurgen Kirsch ,  Karsten-Josef Idel ,  Charles Lundy

    IPC分类号： C08K5/06 ,  C08K5/36 ,  C08K5/42 ,  C08L69/00 ,  C08K5/46

    CPC分类号： C08K5/06 ,  C08K5/42 ,  C08L69/00

    摘要： A thermoplastic molding composition is disclosed containing a polycarbonate resin and(i) 0.1 to 10.0 percent of a polyalkylene oxide corresponding to formula (I) ##STR1## in which R represents H, C.sub.1-6 alkyl, tetrahydropyranyl or a silyl radical,R' represents H or C.sub.1-6 alkyl andx is an integer of 1 to 100, and(ii) 0.1 to 10 percent of an aromatic compound which contains at least one sulfonic acid ester substituent, said percent being relative to the weight of said polycarbonate. The composition which is resistant to the effects of gamma radiation is suitable for the preparation of sterilizable medical instruments.

    摘要翻译： 公开了一种热塑性模塑组合物，其包含聚碳酸酯树脂和（i）0.1-10.0％的对应于式（I）的聚氧化烯，其中R表示H，C 1-6烷基，四氢吡喃基或甲硅烷基 ，R'表示H或C 1-6烷基，x为1〜100的整数，（ii）含有至少一个磺酸酯取代基的芳香族化合物的0.1〜10％，相对于 说聚碳酸酯。 耐γ辐射效果的组合物适用于制备可灭菌医疗器械。

    Polycarbonates of substituted cyclohexylindenebisphenols
    4.
    发明授权
    Polycarbonates of substituted cyclohexylindenebisphenols 失效
    取代环己二烯双酚的聚碳酸酯

    公开(公告)号：US5034458A

    公开(公告)日：1991-07-23

    申请号：US565290

    申请日：1990-08-09

    申请人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Ulrich Grigo

    发明人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Ulrich Grigo

    IPC分类号： C08G64/00 ,  C08G64/06 ,  C08G64/10 ,  C08L69/00

    CPC分类号： C08G64/06 ,  C08L69/00

    摘要： Aromatic polycarbonates having weight average molecular weight M.sub.w of at least 10,000 which contain bifunctional carbonate structural units corresponding to general formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently represent hydrogen, C.sub.1 -C.sub.12 hdyrocarbon or halogen radicals; andR.sup.5, R.sup.6, R.sup.7, R.sup.8 and R.sup.9 independently represent hydrogen or C.sub.1 -C.sub.12 hydrocarbon radicals, one or R.sup.5 and R.sup.9 representing hydrogen and the other C.sub.1 -C.sub.12 hydrocarbon radical;in amounts of from 100 to 1 mole % based on the total amount of difunctional carbonate structural units in the polycarbonate were found to be useful for thermoplast processing of compositions which are characterized by their improved toughness and high heat deflection temperature.

    摘要翻译： 重均分子量＆gt; Mw至少为10,000的芳族聚碳酸酯含有对应于通式（I）的双官能碳酸酯结构单元：其中R 1，R 2，R 3，R 4独立地表示氢，C 1 -C 12羟基或 卤素自由基 R5，R6，R7，R8和R9独立地表示氢或C1-C12烃基，一个或R5和R9代表氢和另一个C1-C12烃基; 发现聚碳酸酯中双官能碳酸酯结构单元的总量为100至1摩尔％可用于组合物的热塑性加工，其特征在于其改进的韧性和高的热变形温度。

    Polycarbonate of polysubstituted cyclohexylidene bisphenols
    5.
    发明授权
    Polycarbonate of polysubstituted cyclohexylidene bisphenols 失效
    多取代亚环己基双酚的聚碳酸酯

    公开(公告)号：US5021542A

    公开(公告)日：1991-06-04

    申请号：US450655

    申请日：1989-12-13

    申请人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Ulrich Grigo ,  Klaus-Christian Paetz

    发明人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Ulrich Grigo ,  Klaus-Christian Paetz

    IPC分类号： C08G64/00 ,  C08G64/06

    CPC分类号： C08G64/06

    摘要： Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently of one another represent hydrogen, a C.sub.1-12 hydrocarbon, halogen,Y.sup.1, Y.sup.2, Y.sup.3 independently of one another represent hydrogen,C.sub.1-5 alkyl, a C.sub.6-12 hydrocarbon radical,at least two of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 not being hydrogen and at least one of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 being C.sub.1-5 alkyl,in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.

    摘要翻译： 平均分子量＆upbar＆Mw至少为10,000的热塑性芳族聚碳酸酯含有对应式（I）的双官能碳酸酯结构单元，其中R 1，R 2，R 3，R 4彼此独立地表示氢，C1-12 烃，卤素，Y 1，Y 2，Y 3彼此独立地表示氢，C 1-5烷基，C 6-12烃基，至少两个取代基Y1，Y2和Y3不为氢，并且至少一个取代基Y1 ，Y2和Y3为C1-5烷基，其量为100至1mol％，基于聚碳酸酯中双官能碳酸酯结构单元的总量。

    Polysiloxane-polycarbonate block copolymers based on certain dihydroxydiphenylcycloalkanes
    7.
    发明授权
    Polysiloxane-polycarbonate block copolymers based on certain dihydroxydiphenylcycloalkanes 失效
    基于某些二羟基二苯基环烷烃的聚硅氧烷 - 聚碳酸酯嵌段共聚物

    公开(公告)号：US5068302A

    公开(公告)日：1991-11-26

    申请号：US564473

    申请日：1990-08-08

    申请人： Peter Horlacher ,  Volker Serini ,  Dieter Freitag ,  Ulrich Grigo ,  Karsten-Josef Idel ,  Uwe Westeppe

    发明人： Peter Horlacher ,  Volker Serini ,  Dieter Freitag ,  Ulrich Grigo ,  Karsten-Josef Idel ,  Uwe Westeppe

    IPC分类号： C08G64/00 ,  C08G64/18 ,  C08G77/42 ,  C08G77/448

    CPC分类号： C08G64/186 ,  C08G77/448

    摘要： Polydiorganosiloxane-polycarbonate block copolymers based on dihydrodiphenylcycloalkanes corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl, preferably phenyl-C.sub.1-4 -alkyl, more especially benzyl,n=2 or 3 andthe substituents R.sup.5 independently of one another are hydrogen or C.sub.1-12 alkyl, with the proviso that at least one of the substituents R.sup.5 is not hydrogen,having an average molecular weight M.sub.w (weight average) in the range from 10,000 to 300,000 (as measured by ultracentrifugation or scattered light measurement) and a content of carbonate containing dihydroxydiphenylcycloalkanes of formula I and, optionally, other diphenols in co-condensed form of from 75% by weight of 99.0% by weight and a content of polydiorganosiloxane having a degree of polymerization Pn of 5 to 300 of from 25% by weight of 1% by weight.

    摘要翻译： 对应于式（I）的二氢二苯基环烷烃的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物其中R 1，R 2彼此独立地表示氢，卤素，优选氯或溴，C 1-8烷基，C 5-6环烷基，C 6 -10芳基和C7-12芳烷基，优选苯基-C1-4 - 烷基，更特别是苄基，n = 2或3，取代基R5彼此独立地为氢或C 1-12烷基，条件是至少一个 的取代基R5不是氢，平均分子量Mw（重均分子量）为10,000〜300,000（通过超速离心或散射光测定测定）和含有式I的二羟基二苯基环烷烃的碳酸酯的含量，以及任选的其它 共缩合形式的双酚75重量％为99.0重量％，聚二有机硅氧烷的聚合度Pn为5〜300的25重量％的1重量％的含量。

    Process for the production of aromatic polyesters
    10.
    发明授权
    Process for the production of aromatic polyesters 失效
    生产芳香族聚酯的方法

    公开(公告)号：US4923957A

    公开(公告)日：1990-05-08

    申请号：US292917

    申请日：1989-01-03

    申请人： Peter Tacke ,  Ulrich Grigo ,  Karsten-Josef Idel

    发明人： Peter Tacke ,  Ulrich Grigo ,  Karsten-Josef Idel

    IPC分类号： C08G63/19 ,  C08G63/195 ,  C08G63/78

    CPC分类号： C08G63/78 ,  C08G63/195

    摘要： Aromatic polyesters based on diphenols and iso- and/or terephthalic acid are produced by transesterification of esters of the diphenols with the aromatic dicarboxylic acids in the melt by first reacting the aromatic dicarboxylic acids with a stoichiometric excess of the diphenol esters to form oligomers and then condensing the resulting oligomers to the aromatic polyesters with elimination and removal by distillation of diphenol ester.

    摘要翻译： 基于二酚和异 - 和/或对苯二甲酸的芳族聚酯通过首先使芳族二羧酸与化学计量过量的二酚酯反应形成低聚物，然后通过二元酚的酯与芳族二羧酸在熔体中的酯交换而产生，然后 通过蒸馏二酚酯消除和除去，将所得的低聚物缩合成芳族聚酯。