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    Polysiloxane-polycarbonate block copolymers based on certain dihydroxydiphenylcycloalkanes
    1.
    发明授权
    Polysiloxane-polycarbonate block copolymers based on certain dihydroxydiphenylcycloalkanes 失效
    基于某些二羟基二苯基环烷烃的聚硅氧烷 - 聚碳酸酯嵌段共聚物

    公开(公告)号：US5068302A

    公开(公告)日：1991-11-26

    申请号：US564473

    申请日：1990-08-08

    申请人： Peter Horlacher ,  Volker Serini ,  Dieter Freitag ,  Ulrich Grigo ,  Karsten-Josef Idel ,  Uwe Westeppe

    发明人： Peter Horlacher ,  Volker Serini ,  Dieter Freitag ,  Ulrich Grigo ,  Karsten-Josef Idel ,  Uwe Westeppe

    IPC分类号： C08G64/00 ,  C08G64/18 ,  C08G77/42 ,  C08G77/448

    CPC分类号： C08G64/186 ,  C08G77/448

    摘要： Polydiorganosiloxane-polycarbonate block copolymers based on dihydrodiphenylcycloalkanes corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1-8 alkyl, C.sub.5-6 cycloalkyl, C.sub.6-10 aryl and C.sub.7-12 aralkyl, preferably phenyl-C.sub.1-4 -alkyl, more especially benzyl,n=2 or 3 andthe substituents R.sup.5 independently of one another are hydrogen or C.sub.1-12 alkyl, with the proviso that at least one of the substituents R.sup.5 is not hydrogen,having an average molecular weight M.sub.w (weight average) in the range from 10,000 to 300,000 (as measured by ultracentrifugation or scattered light measurement) and a content of carbonate containing dihydroxydiphenylcycloalkanes of formula I and, optionally, other diphenols in co-condensed form of from 75% by weight of 99.0% by weight and a content of polydiorganosiloxane having a degree of polymerization Pn of 5 to 300 of from 25% by weight of 1% by weight.

    摘要翻译： 对应于式（I）的二氢二苯基环烷烃的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物其中R 1，R 2彼此独立地表示氢，卤素，优选氯或溴，C 1-8烷基，C 5-6环烷基，C 6 -10芳基和C7-12芳烷基，优选苯基-C1-4 - 烷基，更特别是苄基，n = 2或3，取代基R5彼此独立地为氢或C 1-12烷基，条件是至少一个 的取代基R5不是氢，平均分子量Mw（重均分子量）为10,000〜300,000（通过超速离心或散射光测定测定）和含有式I的二羟基二苯基环烷烃的碳酸酯的含量，以及任选的其它 共缩合形式的双酚75重量％为99.0重量％，聚二有机硅氧烷的聚合度Pn为5〜300的25重量％的1重量％的含量。

    Polycarbonate of polysubstituted cyclohexylidene bisphenols
    2.
    发明授权
    Polycarbonate of polysubstituted cyclohexylidene bisphenols 失效
    多取代亚环己基双酚的聚碳酸酯

    公开(公告)号：US5021542A

    公开(公告)日：1991-06-04

    申请号：US450655

    申请日：1989-12-13

    申请人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Ulrich Grigo ,  Klaus-Christian Paetz

    发明人： Volker Serini ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Ulrich Grigo ,  Klaus-Christian Paetz

    IPC分类号： C08G64/00 ,  C08G64/06

    CPC分类号： C08G64/06

    摘要： Thermoplastic aromatic polycarbonates having average molecular weights Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3, R.sup.4 independently of one another represent hydrogen, a C.sub.1-12 hydrocarbon, halogen,Y.sup.1, Y.sup.2, Y.sup.3 independently of one another represent hydrogen,C.sub.1-5 alkyl, a C.sub.6-12 hydrocarbon radical,at least two of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 not being hydrogen and at least one of the substituents Y.sup.1, Y.sup.2 and Y.sup.3 being C.sub.1-5 alkyl,in quantities of from 100 to 1 mol-%, based on the total quantity of difunctional carbonate structural units in the polycarbonate.

    摘要翻译： 平均分子量＆upbar＆Mw至少为10,000的热塑性芳族聚碳酸酯含有对应式（I）的双官能碳酸酯结构单元，其中R 1，R 2，R 3，R 4彼此独立地表示氢，C1-12 烃，卤素，Y 1，Y 2，Y 3彼此独立地表示氢，C 1-5烷基，C 6-12烃基，至少两个取代基Y1，Y2和Y3不为氢，并且至少一个取代基Y1 ，Y2和Y3为C1-5烷基，其量为100至1mol％，基于聚碳酸酯中双官能碳酸酯结构单元的总量。

    Thermoplastic molding compositions of a polysiloxane block copolycarbonate and a polycarbonate based on certain dihydroxydiphenylcycloalkanes
    4.
    发明授权
    Thermoplastic molding compositions of a polysiloxane block copolycarbonate and a polycarbonate based on certain dihydroxydiphenylcycloalkanes 失效
    基于某些二羟基二苯基甲烷的聚硅氧烷嵌段共聚碳酸酯和聚碳酸酯的热塑性成型组合物

    公开(公告)号：US5100960A

    公开(公告)日：1992-03-31

    申请号：US493036

    申请日：1990-03-12

    申请人： Ulrich Grigo ,  Peter Horlacher ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Wolfgang Beer ,  Werner Nouvertne

    发明人： Ulrich Grigo ,  Peter Horlacher ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe ,  Wolfgang Beer ,  Werner Nouvertne

    IPC分类号： C08L69/00 ,  C08L83/10

    CPC分类号： C08L69/00 ,  C08L83/10

    摘要： The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.4 both represent alkyl; and(C) from 0.5 to 30 parts by weight of a rubber having a glass transition temperature of less than -20.degree. C.The composition of the invention is useful for the preparation of injection molded articles having an excellent surface and a particularly good toughness at low temperatures.

    摘要翻译： 本发明涉及一种热塑性模塑组合物，其包含（A）10至98重量份的重均分子量为10,000至200,000的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物，并且含有75至97.5重量％ ％的芳族碳酸酯结构单元和25〜2.5wt。 ％的聚二有机硅氧烷结构单元; （B）2至90重量份的重均分子量为至少10,000的热塑性芳族聚碳酸酯，并且含有对应于（Ia）的双官能碳酸酯结构单元，其中R 1和R 2独立地表示氢，卤素 C 1 -C 8烷基，C 5 -C 6环烷基，C 6 -C 10芳基或C 7 -C 12芳烷基; m表示4至7的整数，可以为每个X单独选择的R 3和R 4独立地表示氢或C 1 -C 6烷基; 并且x表示碳，条件是在至少一个原子X，R 3和R 4都表示烷基; 和（C）0.5〜30重量份玻璃化转变温度低于-20℃的橡胶。本发明的组合物可用于制备具有优异表面和特别良好韧性的注塑制品 在低温下。

    Fire-retardant polycarbonates and polyesters
    7.
    发明授权
    Fire-retardant polycarbonates and polyesters 失效
    阻燃聚碳酸酯和聚酯

    公开(公告)号：US5025065A

    公开(公告)日：1991-06-18

    申请号：US504487

    申请日：1990-04-04

    申请人： Peter Tacke ,  Ulrich Grigo ,  Werner Nouvertne ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe

    发明人： Peter Tacke ,  Ulrich Grigo ,  Werner Nouvertne ,  Dieter Freitag ,  Karsten-Josef Idel ,  Uwe Westeppe

    IPC分类号： C08K13/00 ,  C08G63/19 ,  C08G63/193 ,  C08G63/199 ,  C08G63/64 ,  C08G64/00 ,  C08G64/06 ,  C08G64/10 ,  C08L67/00 ,  C08L69/00

    CPC分类号： C08G64/06 ,  C08G63/193 ,  C08G63/64

    摘要： Fire-retardant polycarbonates, polyester carbonates and polyesters based on dihydroxydiphenyl cycloalkanes ##STR1## in which R.sup.1 and R.sup.2 independently of one another represent hydrogen, halogen, preferably chlorine or bromine, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl, preferably phenyl and C.sub.7 -C.sub.12 aralkyl, preferably phenyl-C.sub.1 -C.sub.4 -alkyl, more especially benzyl,m is an integer of 4 to 7, preferably 4 or 5, R.sup.3 and R.sup.4 may be individually selected for each X and, independently of one another, represent hydrogen or C.sub.1 -C.sub.6 alkyl andX is carbon,with the proviso that, at at least one atom X, R.sup.3 and R.sup.4 are both alkyl,the fire-retardant finish being provided by additives and/or comonomers.

    摘要翻译： 基于二羟基二苯基环烷烃的阻燃聚碳酸酯，聚酯碳酸酯和聚酯其中R1和R2彼此独立地代表氢，卤素，优选氯或溴，C1-C8烷基，C5-C6环烷基，C6- C10芳基，优选苯基和C7-C12芳烷基，优选苯基-C1-C4-烷基，更特别是苄基，m是4至7，优选4或5的整数，R 3和R 4可以各自独立地选自X， 彼此独立地表示氢或C1-C6烷基，X是碳，条件是在至少一个原子X，R 3和R 4均为烷基时，阻燃剂由添加剂和/或共聚单体提供。

    Polycarbonate of cycloalkylidene bisphenol
    8.
    发明授权
    Polycarbonate of cycloalkylidene bisphenol 失效
    环亚烷基双酚的聚碳酸酯

    公开(公告)号：US5010163A

    公开(公告)日：1991-04-23

    申请号：US450604

    申请日：1989-12-13

    申请人： Volker Serini ,  Dieter Freitag ,  Uwe Westeppe ,  Karsten Idel ,  Ulrich Grigo ,  Carl Casser ,  Klaus-Christian Paetz ,  Manfred Hajek

    发明人： Volker Serini ,  Dieter Freitag ,  Uwe Westeppe ,  Karsten Idel ,  Ulrich Grigo ,  Carl Casser ,  Klaus-Christian Paetz ,  Manfred Hajek

    IPC分类号： C08G64/00 ,  C08G64/06

    CPC分类号： C08G64/06

    摘要： Thermoplastic aromatic polycarbonates having average molecular weight Mw of at least 10,000 which contain bifunctional carbonate structural units corresponding to formula (I) ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another represent hydrogen, a C.sub.1 -C.sub.12 -hydrocarbon, halogen,m is 2 or 3 andX represents hydrogen or a C.sub.6 -C.sub.12 hydrocarbon, at least one substituent X being a C.sub.6 -C.sub.12 hydrocarbon radical,in quantities of from 100 to 1 mol-% based on the total quantity of difunctional carbonate structural units in the polycarbonate.

    摘要翻译： 具有至少10,000的平均分子量＆amp; Mw和Mw的热塑性芳族聚碳酸酯，其含有对应于式（I）的双官能碳酸酯结构单元，其中R 1，R 2，R 3和R 4彼此独立地表示氢，C1- C 12烃，卤素，m为2或3，X表示氢或C 6 -C 12烃，至少一个取代基X为C 6 -C 12烃基，其量为100至1摩尔％，基于总量 的聚碳酸酯中的双官能碳酸酯结构单元。