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    Adhesion promoters for thiolene adhesive formulations
    3.
    发明授权
    Adhesion promoters for thiolene adhesive formulations 失效
    硫醇粘合剂配方的粘合促进剂

    公开(公告)号：US5028661A

    公开(公告)日：1991-07-02

    申请号：US443046

    申请日：1989-11-27

    申请人： Paul J. Clark ,  Anthony F. Jacobine ,  David M. Glaser

    发明人： Paul J. Clark ,  Anthony F. Jacobine ,  David M. Glaser

    IPC分类号： C08G75/04

    CPC分类号： C08G75/045

    摘要： Compounds useful as adhesion promoters for thermally cured thiolene adhesives include a) acrylic or norbornene acid phosphate esters such as ##STR1## b) maleic, acrylic, methacrylic, norbornene dicarboxylic, and fumaric acids and half acid esters and peresters of maleic fumaric and norbornene dicarboxylic acids; and c) norbornene, acrylic or methacrylic silanes having two or three hydrolyzable groups bound to the silicon atom thereof, such as 5-(triacetoxysilyl) norbornene.The adhesion promoters may be employed as surface primers for conventional thiolene compositions. Alternatively the thiolene compositions themselves may be modified by addition of 0.1 to 10% by weight of the adhesion promoter. Preferred thiolene compositions employ norbornene functional ene ingredients.

    摘要翻译： 可用作热固化硫醇粘合剂的粘合促进剂的化合物包括：a）丙烯酸或降冰片烯酸性磷酸酯，例如马来酸，丙烯酸，甲基丙烯酸，降冰片烯二羧酸和富马酸，马来酸的半酸酯和过酸酯 富马酸和降冰片烯二羧酸; 和c）具有两个或三个与其硅原子结合的可水解基团的降冰片烯，丙烯酸或甲基丙烯酸硅烷如5-（三乙酰氧基甲硅烷基）降冰片烯。 粘合促进剂可用作常规硫羟组合物的表面引物。 或者，硫醇组合物本身可以通过加入0.1至10重量％的粘合促进剂来改性。 优选的硫醇组合物使用降冰片烯功能烯成分。

    High purity resins for thiol-ene polymerizations and method for producing same
    5.
    发明授权
    High purity resins for thiol-ene polymerizations and method for producing same 失效
    用于硫醇烯聚合的高纯度树脂及其制备方法

    公开(公告)号：US5399624A

    公开(公告)日：1995-03-21

    申请号：US56128

    申请日：1993-04-30

    申请人： David M. Glaser ,  Anthony F. Jacobine ,  Paul J. Grabek

    发明人： David M. Glaser ,  Anthony F. Jacobine ,  Paul J. Grabek

    IPC分类号： B29C67/00 ,  C08F6/02 ,  C08F8/34 ,  C08F8/42 ,  C08G75/02 ,  C08G75/04 ,  G03F7/00 ,  G03F7/027 ,  C08F279/00

    CPC分类号： B29C67/0066 ,  C08F6/02 ,  C08G75/045 ,  G03F7/0037 ,  G03F7/0275

    摘要： A treatment method for polyene resins used in thiol-ene formulations, especially norbornene resins, significantly stabilizes thiol-ene compositions made from batches of polyene resin which otherwise give compositions with poor dark stability. The treatment comprises contacting the polyene with an amphoteric treating agent selected from the group consisting of silicated magnesium oxide, basic aluminum oxide, silica gel, magnesium oxide, magnesium hydroxide, calcium oxide, calcium hydroxide, barium oxide, and barium hydroxide, and then separating the resin from the treating agent prior to mixture with a polythiol to form a thiol-ene composition. The treatment method significantly reduces ionic content in polyene resins, particularly chloride ion but also sodium and potassium ions. Consequently, treatment is also beneficial with polyene resins which do not produce substantial dark stability problems. Reduction of the ionic content of the resin is desirable to produce cured thiolene polymers with low electrical conductivity and low corrosiveness.

    摘要翻译： 用于硫醇烯制剂，特别是降冰片烯树脂中的多烯树脂的处理方法显着地稳定了一批由多烯树脂制成的硫醇烯组合物，否则会产生具有差的黑色稳定性的组合物。 处理包括使多烯与选自硅酸镁，碱性氧化铝，硅胶，氧化镁，氢氧化镁，氧化钙，氢氧化钙，氧化钡和氢氧化钡的两性处理剂接触，然后分离 在与多硫醇混合之前来自处理剂的树脂形成硫醇 - 烯组合物。 处理方法显着降低了多烯树脂中的离子含量，特别是氯离子，而且钠离子和钾离子。 因此，对于不产生实质的黑暗稳定性问题的多烯树脂，处理也是有益的。 需要降低树脂的离子含量以生产具有低导电性和低腐蚀性的固化硫醇聚合物。

    Selective monohydrosilation of vinyl and ethynyl functional norbornenes and curable products produced thereby
    6.
    发明授权
    Selective monohydrosilation of vinyl and ethynyl functional norbornenes and curable products produced thereby 失效
    乙烯基和乙炔基功能降冰片烯的选择性单氢化和由此生产的可固化产物

    公开(公告)号：US5266670A

    公开(公告)日：1993-11-30

    申请号：US315737

    申请日：1989-02-24

    申请人： Steven T. Nakos ,  Anthony F. Jacobine ,  David M. Glaser

    发明人： Steven T. Nakos ,  Anthony F. Jacobine ,  David M. Glaser

    IPC分类号： C07F7/14 ,  C08G75/04 ,  C08G77/20 ,  C08G77/38 ,  C08L83/07 ,  C07F7/08

    CPC分类号： C08G75/045 ,  C07F7/14 ,  C08G77/20 ,  C08G77/38

    摘要： A process comprising the steps of:1) reacting a norbornene compound of the formula: ##STR1## where R is H or methyl, R.sup.1 is a direct bond or --C(.dbd.O)O-- and R.sup.2 is vinyl, ethynyl, allyl or propargyl, with a silicon hydride functional compound in the presence of hydrosilation catalyst at a temperature of at least 60 degrees; and2) recovering a product which consists essentially of the addition products of the silicon hydride functional compound to the R.sup.2 group of the norbornene compound and which is substantially free of addition products of the silicon hydride functional compound to the internal ring double bond of the norbornene compound.The products of this process can be used to produce norbornene functional prepolymers which are useful in cureable silicone formulations based on thiolene or hydrosilation cure chemistry.

    摘要翻译： 一种方法，包括以下步骤：1）使下式的降冰片烯化合物：其中R是H或甲基，R1是直接键或-C（= O）O-，R2是乙烯基，乙炔基，烯丙基或 炔丙基与硅氢化物官能化合物在硅氢化催化剂存在下在至少60度的温度下反应; 和2）回收基本上由氢化硅官能化合物的加成产物与降冰片烯化合物的R2基团组成的产物，其基本上不含氢化硅官能化合物与降冰片烯的内环双键的加成产物 复合。 该方法的产物可用于制备降冰片烯官能预聚物，其可用于基于硫醇或氢化硅烷化固化化学的可固化硅氧烷配方。

    Polyol terminated silicones and derivatives thereof
    7.
    发明授权
    Polyol terminated silicones and derivatives thereof 失效
    多元醇封端的硅氧烷及其衍生物

    公开(公告)号：US4640940A

    公开(公告)日：1987-02-03

    申请号：US765292

    申请日：1985-08-13

    申请人： Anthony F. Jacobine ,  David M. Glaser

    发明人： Anthony F. Jacobine ,  David M. Glaser

    IPC分类号： C08F2/46 ,  C08F30/08 ,  C08G77/38 ,  C08G77/382

    CPC分类号： C08G77/382 ,  C08F30/08 ,  C08G77/38

    摘要： Polyorganosiloxane polymers which include at least one group of the formula: ##STR1## where R.sup.1 is an organo group; R.sup.2 is alkylene or alkenylene; G is a n+1 valent hydrocarbon, oxyhydrocarbon or poly(oxyhydrocarbon) radical in which some or all of the hydrogen atoms may optionally be substituted by halogen atoms; R.sup.3 is H or an organic functional group, particularly polymerizable groups, polymerization accelerating groups or polymerization initiating groups; n is an integer of 2 or more provided that when n is 2 and one of R.sup.3 is H, the other R.sup.3 group is also H; and a is 0, 1 or 2.Additional polyorganosiloxane polymers include at least one group of the formula: ##STR2## where R.sup.4 R.sup.5 are H or a mono valent hydrocarbon group.

    摘要翻译： 包含至少一个下式的基团的聚有机硅氧烷聚合物：其中R 1是有机基团; R2是亚烷基或亚烯基; G是n + 1价烃，羟基烃或聚（氧代烃）基团，其中一些或全部氢原子可以任选被卤素原子取代; R3是H或有机官能团，特别是可聚合基团，聚合促进基团或聚合引发基团; n是2或更大的整数，条件是当n是2且R3中的一个是H时，另一个R3基也是H; 和a为0,1或2.另外的聚有机硅氧烷聚合物包括至少一个下式的基团：其中R 4 R 5是H或一价烃基。

    Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same
    8.
    发明授权
    Photosensitive compounds, photopolymerizable compositions including the same, and methods of making and using the same 有权
    感光性化合物，包含其的光聚合性组合物及其制备和使用方法

    公开(公告)号：US07705064B2

    公开(公告)日：2010-04-27

    申请号：US11781317

    申请日：2007-07-23

    申请人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    发明人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    IPC分类号： C08F2/50 ,  C08F222/10 ,  C07C69/587 ,  C08G16/00

    CPC分类号： C08F2/50 ,  C07C67/347 ,  C07C255/22 ,  C08G18/10 ,  C08G18/672 ,  C07C69/716 ,  C08G18/3206 ,  C08G18/3838 ,  C08G18/42

    摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.

    摘要翻译： 本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基， 和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。

    Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same
    10.
    发明申请
    Photosensitive Compounds, Photopolymerizable Compositions Including the Same, and Methods of Making and Using the Same 有权
    光敏化合物，包括其的可光聚合组合物及其制备和使用方法

    公开(公告)号：US20090030106A1

    公开(公告)日：2009-01-29

    申请号：US11781317

    申请日：2007-07-23

    申请人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    发明人： Anthony F. Jacobine ,  John G. Woods ,  Joel D. Schall ,  Steven T. Nakos ,  Andrew D. Messana ,  David M. Glaser

    IPC分类号： C08F2/48 ,  C07C45/00

    CPC分类号： C08F2/50 ,  C07C67/347 ,  C07C255/22 ,  C08G18/10 ,  C08G18/672 ,  C07C69/716 ,  C08G18/3206 ,  C08G18/3838 ,  C08G18/42

    摘要： The present invention is directed to reaction products prepared from at least one Michael addition donor material including two or more active methylene hydrogens; and at least one material capable of reacting with a Michael addition donor, the material having one Michael addition acceptor and at least one functional group selected from the group consisting of hydroxy, hydroxyalkyl, vinyl ether, amino, aminoalkyl, carboxy, carboxyalkyl, cyano, and cyanoalkyl groups; or reaction products prepared from (a) at least one Michael addition donor material comprising at least one Michael Addition donor group selected from the group consisting of cyano functional groups and phosphono functional groups; and (b) at least one material capable of reacting with the at least one Michael addition donor group, the material having at least one Michael addition acceptor, wherein the above reaction products are capable of forming free radicals upon exposure to actinic radiation; as well as compositions, and processes for making and using the same.

    摘要翻译： 本发明涉及由至少一种包含两种或更多种活性亚甲基氢的迈克尔加成供体材料制备的反应产物; 和至少一种能够与迈克尔加成供体反应的材料，所述材料具有一个迈克尔加成受体和至少一种选自羟基，羟基烷基，乙烯基醚，氨基，氨基烷基，羧基，羧基烷基，氰基， 和氰基烷基; 或由（a）包含至少一种选自氰基官能团和膦酰基官能团的迈克尔加成供体基团的至少一种迈克尔加成供体材料制备的反应产物; 和（b）至少一种能够与至少一种迈克尔加成供体基团反应的材料，该材料具有至少一种迈克尔加成受体，其中上述反应产物能够在暴露于光化辐射下形成自由基; 以及组合物和制备和使用它们的方法。