摘要:
Heat-resistant resin composition comprising (A) 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure containing 50% by weight or higher of recurring units of the formula ##STR1## and a logarithmic viscosity number of 0.1 to 1.0 dl/g; (B) from 0.01 to less than 25 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR2## wherein the --CO-- and --S-- are in the para position to each other, and having a melting point of 310.degree.-380.degree. C., a residual melt crystallization enthalpy of at least 10 J/g, a melt crystallization temperature of at least 210.degree. C. and a reduced viscosity of 0.2 to 2 dl/g; and (C) at least one of fibrous fibers and/or at least one of inorganic fillers in a proportion of 0 to 400 parts by weight per 100 parts by weight of the resin component comprising said poly(arylene sulfide) and said poly(arylene thioether-ketone). Heat-resistant articles obtained by melt-molding or forming said resin compositions and a method for the production of such articles are also described.
摘要:
Heat-resistant resin composition including (A) 100 parts by weight of a poly(arylene sulfide) of a substantially linear structure containing 50% by weight or higher or recurring units of the formula ##STR1## and a logarithmic viscosity number of 0.1 to 1.0 dl/g; (B) from 0.01 to less than 25 parts by weight of a melt-stable poly(arylene thioether-ketone) having predominant recurring units of the formula ##STR2## wherein the --CO-- and --S-- are in the para position to each other, and having a melting point of 310.degree.-380.degree. C., a residual melt crystallization enthalpy of at least 10 J/g, a melt crystallization temperature of at least 210.degree. C. and a reduced viscosity of 0.2 to 2 dl/g; and (C) at least one of fibrous fibers and/or at least one of inorganic fillers in a proportion of 0 to 400 parts by weight per 100 parts by weight of the resin component including said poly(arylene sulfide) and said poly(arylene thioether-ketone). Heat-resistant articles obtained by melt-molding or forming said resin compositions and a method for the production of such articles are also described.
摘要:
Disclosed herein is a crystallized, thin-wall container which is excellent in heat-resistance, oil-resistance, chemical stability under high temperature and high humidity and gas impermeability, is particularly suitable for heating foodstuffs packaged in it in electronic range, electric oven, etc. and is obtained by thermoforming a substantially amorphous sheet which has a crystallinity index of below 15% and an elongation of not less than 100% at room temperature and is obtained from a poly(arylene sulfide) which has a substantially linear structure, has not less thant 70 wt % of a repeating unit of ##STR1## and a logarithmic viscosity number of 0.2 to 1.0 in a solution of 1-chloronaphthalene (concentration of 0.4 g/dl at a temperature of 208.degree. C.) and a process for producing the container.
摘要:
Disclosed herein is a poly(arylene thioether) resin composition comprising 100 parts by weight of a poly(arylene thioether) (A) having a shear rate dependence value of melt viscosity at 310.degree. C. of 2.2-3.0 and a crystallization temperature of 175.degree.-210.degree. C., and 20-400 parts by weight of a poly(arylene thioether) (B) having a shear rate dependence value of melt viscosity at 310.degree. C. of 1.0-2.0 and a crystallization temperature of 220.degree.-260.degree. C. The resin portion consisting of the poly(arylene thioethers) (A) and (B) in the resin composition has a melt viscosity of 1,400-3,500 poises as measured at 310.degree. C. and a shear rate of 1,200 sec.sup.-1, a shear rate dependence value of melt viscosity at 310.degree. C. of 1.5-2.3, and a crystallization temperature of 205.degree.-230.degree. C. Extruded products such as a tubular extruded article obtained from the resin composition are also disclosed.
摘要:
Disclosed herein are electronic device sealing resin compositions containing (A) 40-25 parts by weight of a thermoplastic resin composed of 100-10 wt. % of a poly(arylene thioether-ketone) and 0-90 wt. % of a poly(arylene sulfide), (B) 60-75 parts by weight of an inorganic filler, and per 100 parts by weight of the sum of the thermoplastic resin (A) and inorganic filler (B), (C) 1.5-5 parts by weight of a silicone oil, (D) 10-15 parts by weight of a silicone rubber or (C) 0.5-3 parts by weight of a silicone oil and (D) 5-13 parts by weight of a silicone rubber. Electronic devices sealed using such resin compositions are also disclosed.
摘要:
Disclosed herein are electronic device sealing resin compositions containing (A) 40-25 parts by weight of a thermoplastic resin composed of 100-10 wt. % of a poly(arylene thioether-ketone) and 0-90 wt. % of a poly(arylene sulfide), (B) 60-75 parts by weight of an inorganic filler, and per 100 parts by weight of the sum of the thermoplastic resin (A) and inorganic filler (B), (C) 1.5-5 parts by weight of a silicone oil, (D) 10-15 parts by weight of a silicone rubber or (C) 0.5-3 parts by weight of a silicone oil and (D) 5-13 parts by weight of a silicone rubber. Electronic devices sealed using such resin compositions are also disclosed.
摘要:
A cement material containing polyarylene thioether fibers and carbon fibers as reinforcing fiber and molded articles comprising hardened products thereof are disclosed.The fiber reinforced cement material is curable in an autoclave and the molded articles comprising the hardened products thereof are excellent in deflection property, impact strength, tensile strength and bending strength.
摘要:
This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is separated from its neighboring chamber by means of an anodic ion exchange membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radical, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10 - 20 wt. % while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt. %.
摘要:
This invention relates to an apparatus for the electrolytic treatment of alkali halide solution in a three chamber type electrolytic bath assembly comprising an anodic chamber, an intermediate chamber and a cathodic chamber arranged one after another in series. Each chamber is from its neighboring chamber by means of a cationic permselective membrane. The apparatus is characterized, according to this invention, in that the first one of the membranes separating the intermediate and anodic chambers is made of a fluorine-containing resin, while the second membrane separating the intermediate and cathodic chambers includes, as its main ion exchange radial, a pendant type phenolic radical or derivative thereof. The inventive process, which utilizes the above-described apparatus is characterized in that it utilizes a caustic alkali concentration in the intermediate chamber which ranges from about 10-20 wt.% while the output caustic alkali developed at and delivered from the cathodic chamber amounts to a concentration ranging from about 30 to 50 wt.%.