公开(公告)号：US06833430B2

公开(公告)日：2004-12-21

申请号：US10257145

申请日：2002-10-09

申请人： Eiji Yashima ,  Katsuhiro Maeda

发明人： Eiji Yashima ,  Katsuhiro Maeda

IPC分类号： C08G6100

CPC分类号： C08F4/80 ,  C08F38/00 ,  C08F138/02

摘要： A process for the production of polyacetylene derivatives by which polyacetylene derivatives having an ability to discriminate asymmetry can be easily obtained in a few steps and in high yield and which is also advantageous in respects of economical efficiency, environmental problems, and so on. This process is characterized by polymerizing an acetylene derivative having a hydrophilic functional group in an aqueous solvent in the presence of a water-soluble transition metal complex catalyst and a base.

摘要翻译： 制造聚乙炔衍生物的方法可以容易地以几个步骤和高产率获得具有鉴别不对称性的聚乙炔衍生物，并且在经济效率，环境问题等方面也是有利的。 该方法的特征在于在水溶性过渡金属络合物催化剂和碱的存在下，在水性溶剂中聚合具有亲水性官能团的乙炔衍生物。

公开(公告)号：US06372881B1

公开(公告)日：2002-04-16

申请号：US09912927

申请日：2001-07-24

申请人： Qibing Pei

发明人： Qibing Pei

IPC分类号： C08G6100

摘要： The invention provides novel conjugated polymers comprised of arylamine-substituted poly(arylene vinylenes). The polymers have the general structure (I) wherein: Ar is arylene, heteroarylene, substituted arylene or substituted heteroarylene containing one to three aromatic rings; R1 is an arylamine substituent having the formula —Ar1—N(R4R5) wherein Ar1 is as defined for Ar and R4 and R5 are independently hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, or substituted heteroatom-containing hydrocarbyl, or together form a cyclic group; and R2 and R3 are independently selected from the group consisting of hydrido, halo and cyano, or may be as defined for R4 and R5, or may together form a triple bond. Monomeric precursors and methods of synthesizing the precursors are also provided, as are electroluminescence and other devices containing a polymer of the invention.

公开(公告)号：US06309763B1

公开(公告)日：2001-10-30

申请号：US09063615

申请日：1998-04-21

申请人： Edmund P. Woo ,  Mark T. Bernius ,  Michael Inbasekaran ,  Weishi Wu

发明人： Edmund P. Woo ,  Mark T. Bernius ,  Michael Inbasekaran ,  Weishi Wu

IPC分类号： C08G6100

CPC分类号： H05B33/14 ,  C07C25/22 ,  C08G61/00 ,  C08G61/02 ,  C08G61/12 ,  C08G73/02 ,  C08G73/026 ,  C09K11/06 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0059 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/31678

摘要： A copolymer comprising 10-90 percent by weight of groups of Formula (I): and from 10-90 percent by weight of groups selected from Formulas (II), (III), and (IV): and mixtures thereof; wherein R1 is independently in each occurrence H, C1-C20 hydrocarbyl or C1-C20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-C16 hydrocarbyl carbonyloxy, C4-C16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-C20 cycloaliphatic structure or a C4-C20 cycloaliphatic structure containing one or more heteroatoms of S, N, or O; R2 is independently in each occurrence C1-C20 hydrocarbyl, C1-C20 hydrocarbyloxy, C1-C20 thioether, C1-C20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence carboxyl, C1-C20 alkyl, C1-C20 alkoxy or a group of the formula —CO2R4 wherein R4 is a C1-C20 alkyl; and a and b are independently in each occurrence an integer from 0 to 3.

摘要翻译： 包含10-90重量％的式（I）的基团和10-90重量％的选自式（II），（III）和（IV）的基团的共聚物及其混合物; 其中R 1在每次出现时独立地为H，C 1 -C 20烃基或含有一个或多个S，N，O，P或Si原子的C 1 -C 20烃基，C 4 -C 16烃基羰氧基，C 4 -C 16芳基（三烷基甲硅烷氧基）或两个R 1 与芴环上的9-碳形成C5-C20脂环族结构或含有一个或多个S，N或O的杂原子的C 4 -C 20脂环族结构; R2各自独立地为C1-C20烃基，C1-C20烃氧基，C1-C20硫醚，C1-C20烃基羰基氧基或氰基; R3各自独立地为羧基，C 1 -C 20烷基，C 1 -C 20烷氧基或式-CO 2 R 4基团，其中R 4为C 1 -C 20烷基; 并且a和b各自独立地为0至3的整数。

公开(公告)号：US06706821B1

公开(公告)日：2004-03-16

申请号：US09908485

申请日：2001-07-18

申请人： Robert J. Letchford

发明人： Robert J. Letchford

IPC分类号： C08G6100

CPC分类号： C08G18/672 ,  C08C19/02 ,  C08C19/28 ,  C08F222/1006 ,  C08F255/00 ,  C08F285/00 ,  C08F290/00 ,  C08F290/06 ,  C08F290/14 ,  C08L71/02 ,  C08L2205/05 ,  C08L2666/04

摘要： Adducts of polyfunctional acrylates and amine terminated polyolefins are provided. The adducts are prepared via a Michael addition reaction of the acrylate and the amine terminated polyolefin. The resultant adducts can be further polymerized with acrylic monomers via free radical or radiation curing mechanisms or quaternized to improve dispersion in aqueous systems.

摘要翻译： 提供多官能丙烯酸酯和胺封端的聚烯烃的加合物。 通过丙烯酸酯和胺封端的聚烯烃的迈克尔加成反应制备加合物。 所得到的加合物可以通过自由基或辐射固化机理与丙烯酸单体进一步聚合或季铵化以改进含水体系中的分散体。

公开(公告)号：US06593450B2

公开(公告)日：2003-07-15

申请号：US09755507

申请日：2001-01-05

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof

IPC分类号： C08G6100

CPC分类号： H01L51/0052 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28035 ,  H01L21/28167 ,  H01L22/20 ,  H01L29/42364 ,  H01L29/42376 ,  H01L29/66575 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0058 ,  H01L51/0094 ,  H01L51/42 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/3154

摘要： The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C5-20 ring structure formed with the 9-carbon on the fluorene ring or a C4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7′-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7′-positions. The 2,7′-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7′-aryl moieties, which are capable of crosslinking or chain extension, to undergo chain extension or crosslinking. Also disclosed are processes for preparing the disclosed compounds.

摘要翻译： 本发明涉及2,7-取代的9-取代的芴和9-取代的芴低聚物和聚合物。 芴，低聚物和聚合物在9位被两个烃基部分取代，该烃基部分可任选地含有一个或多个硫，氮，氧，磷或硅杂原子; 由芴环上的9-碳形成的C5-20环结构或由含有一个或多个硫，氮或氧杂原子的9-碳形成的C 4-20环结构; 或亚烃基部分。 在一个实施方案中，芴在2-和7-位被芳基部分取代，芳基部分可进一步被能够交联或延伸的部分或三烷基甲硅烷氧基部分取代。 芴聚合物和低聚物可以在2-和7-位取代。 芴低聚物和聚合物的单体单元在2和7'位置彼此结合。 2,7'-芳基-9-取代的芴低聚物和聚合物可以进一步彼此反应以通过在端基2,7'-芳基部分上引入任选的部分来形成较高分子量的聚合物，其能够交联或 链延伸，进行链延长或交联。 还公开了制备所公开的化合物的方法。

公开(公告)号：US06512083B1

公开(公告)日：2003-01-28

申请号：US09661237

申请日：2000-09-13

申请人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

发明人： Edmund P. Woo ,  William R. Shiang ,  Michael Inbasekaran ,  Gordon R. Roof ,  Mark T. Bernius ,  Weishi Wu

IPC分类号： C08G6100

CPC分类号： H01L51/0043 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2602/44 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09B69/105 ,  C09B69/109 ,  C09K11/06 ,  C09K2211/1408 ,  C09K2211/1416 ,  H01L51/0036 ,  H01L51/0037 ,  H01L51/0038 ,  H01L51/0039 ,  H01L51/0042 ,  H01L51/0052 ,  H01L51/0059 ,  H01L51/0062 ,  H01L51/007 ,  H01L51/0081 ,  H01L51/42 ,  H01L51/5012 ,  H01L2251/308 ,  Y10S428/917

摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or  wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurrence a C2-10 alkylene group.

摘要翻译： 下式的化合物及下式的化合物：其中R1各自独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基， 16芳基（三烷基甲硅烷氧基）或两者可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O的杂原子的C 4-20环结构; R 2在每次出现时独立地 C 1-20烃基，C 1-20烃基氧基，C 1-20硫醚，C 1-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基， 20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2或其中R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时独立地为C 2-10亚烷基。

公开(公告)号：US06835803B1

公开(公告)日：2004-12-28

申请号：US09958257

申请日：2002-02-19

申请人： Peter Kian-Hoon Ho ,  Ji-Seon Kim ,  Richard Henry Friend

发明人： Peter Kian-Hoon Ho ,  Ji-Seon Kim ,  Richard Henry Friend

IPC分类号： C08G6100

CPC分类号： C08L65/00 ,  B82Y20/00 ,  C08K5/5317 ,  G02B1/10 ,  G02B6/1221 ,  G02B2006/12069 ,  G02B2006/12104 ,  H01B1/12 ,  H01L51/002 ,  H01L51/0026 ,  H01L51/0038 ,  H01L51/5012 ,  H01L51/5052 ,  H01L51/5262 ,  H01L51/5265 ,  H01S3/168 ,  H01S5/36 ,  C08L2666/06

摘要： A method for forming a conjugated polymer which is doped by a dopant includes the steps of (a) adding a doping agent comprising a dopant moiety to a solution containing the conjugated polymer or a precursor thereof and, optionally, a second polymer, the dopant moiety being capable of bonding to the conjugated polymer, precursor thereof or the second polymer; (b) allowing the dopant moiety to bond to the conjugated polymer, precursor thereof or the second polymer to perform doping of the conjugated polymer, wherein the amount of doping agent added in step (a) is less than the amount required to form a fully doped conjugated polymer.

摘要翻译： 形成由掺杂剂掺杂的共轭聚合物的方法包括以下步骤：（a）将包含掺杂剂部分的掺杂剂加入到含有共轭聚合物或其前体和任选的第二聚合物的溶液中，掺杂剂部分 能够与共轭聚合物，其前体或第二聚合物键合; （b）允许掺杂剂部分与共轭聚合物，其前体或第二聚合物键合以进行共轭聚合物的掺杂，其中在步骤（a）中添加的掺杂剂的量小于形成完全的量所需的量 掺杂共轭聚合物。

公开(公告)号：US06583260B2

公开(公告)日：2003-06-24

申请号：US10004802

申请日：2001-12-07

申请人： Valerie V. Sheares

发明人： Valerie V. Sheares

IPC分类号： C08G6100

CPC分类号： C08F36/14

摘要： Functionalized monomers and polymerized functionalized monomers selected from the group consisting of 2-(N,N-dimethylaminomethyl)-1,3-butadiene, 2-(N,N-diethylaminomethyl)-1,3-butadiene, 2-(N,N-di-n-propylaminomethyl)-1,3-butadiene, 2-(cyanomethyl)-1,3-butadiene, 2-(aminomethyl)-1,3-butadiene, 2-(hydroxymethyl)-1,3-butadiene, 2-(carboxymethy)-1,3-butadiene, 2-(acetoxymethyl)-1,3-butadiene, 2-(2-alkoxy-2-oxoethyl)-1,3-butadiene, 2,3-bis(cyanomethyl)-1,3-butadiene, 2,3-bis(dialkylaminomethyl)-1,3-butadiene, 2,3-bis(4-ethoxy-4-4-oxobutyl)-1,3-butadiene and 2,3-bis(3-cyanopropyl)-1,3-butadiene, and methods for preparing such functionalized diene monomers and polymers.

公开(公告)号：US06569953B1

公开(公告)日：2003-05-27

申请号：US09318738

申请日：1999-05-26

申请人： David C. Dehm ,  David A. Hutchings ,  Alan K. Randall ,  Mark A. Peters

发明人： David C. Dehm ,  David A. Hutchings ,  Alan K. Randall ,  Mark A. Peters

IPC分类号： C08G6100

CPC分类号： C08L65/00 ,  C08G18/4879 ,  C08G61/02 ,  C08L61/28 ,  C08L63/00 ,  C08L2666/22 ,  C08L61/20

摘要： Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.

摘要翻译： 公开了酚醛树脂多元醇。 含有脂族或混合酚和脂族羟基的多元醇是芳烷基化酚或苯酚芳烷基化聚合物与选自环氧烷烃和碳酸亚烷基酯的烷氧基化剂的反应产物。 酚醛树脂多元醇是许多聚合物体系的通用中间体，包括聚氨酯，环氧树脂，醇酸树脂，丙烯酸酯和聚酯。

公开(公告)号：US06255447B1

公开(公告)日：2001-07-03

申请号：US09316435

申请日：1999-05-21

申请人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof

发明人： Edmund P. Woo ,  Michael Inbasekaran ,  William R. Shiang ,  Gordon R. Roof

IPC分类号： C08G6100

CPC分类号： H01L51/0052 ,  C07C17/2637 ,  C07C17/266 ,  C07C25/22 ,  C07C25/24 ,  C07C211/48 ,  C07C2603/18 ,  C08G61/00 ,  C08G61/02 ,  C08G61/10 ,  C09K11/06 ,  H01L21/28035 ,  H01L21/28167 ,  H01L22/20 ,  H01L29/42364 ,  H01L29/42376 ,  H01L29/66575 ,  H01L51/0039 ,  H01L51/0043 ,  H01L51/0058 ,  H01L51/0094 ,  H01L51/42 ,  H01L51/5012 ,  Y10S428/917 ,  Y10T428/3154

摘要： The invention relates to 2,7-substituted-9-substituted fluorenes and 9-substituted fluorene oligomers and polymers. The fluorenes, oligomers and polymers are substituted at the 9-position with two hydrocarbyl moieties which may optionally contain one or more of sulfur, nitrogen, oxygen, phosphorous or silicon heteroatoms; a C5-20 ring structure formed with the 9-carbon on the fluorene ring or a C4-20 ring structure formed with the 9-carbon containing one or more heteroatoms of sulfur, nitrogen or oxygen; or a hydrocarbylidene moiety. In one embodiment, the fluorenes are substituted at the 2- and 7-positions with aryl moieties which may further be substituted with moieties which are capable of crosslinking or chain extension or a trialkylsiloxy moiety. The fluorene polymers and oligomers may be substituted at the 2- and 7′-positions. The monomer units of the fluorene oligomers and polymers are bound to one another at the 2- and 7′-positions. The 2,7′-aryl-9-substituted fluorene oligomers and polymers may be further reacted with one another to form higher molecular weight polymers by causing the optional moieties on the terminal 2,7′-aryl moieties, which are capable of crosslinking or chain extension, to undergo chain extension or crosslinking. Also disclosed are processes for preparing the disclosed compounds.

摘要翻译： 本发明涉及2,7-取代的9-取代的芴和9-取代的芴低聚物和聚合物。 芴，低聚物和聚合物在9位被两个烃基部分取代，该烃基部分可任选地含有一个或多个硫，氮，氧，磷或硅杂原子; 由芴环上的9-碳形成的C5-20环结构或由含有一个或多个硫，氮或氧杂原子的9-碳形成的C 4-20环结构; 或亚烃基部分。 在一个实施方案中，芴在2-和7-位被芳基部分取代，芳基部分可进一步被能够交联或延伸的部分或三烷基甲硅烷氧基部分取代。 芴聚合物和低聚物可以在2-和7-位取代。 芴低聚物和聚合物的单体单元在2和7'位置彼此结合。 2,7'-芳基-9-取代的芴低聚物和聚合物可以进一步彼此反应以通过在端基2,7'-芳基部分上引入任选的部分来形成较高分子量的聚合物，其能够交联或 链延伸，进行链延长或交联。还公开了制备所公开的化合物的方法。