公开(公告)号：US20160170301A1

公开(公告)日：2016-06-16

申请号：US14571462

申请日：2014-12-16

Applicant: Deepak Shukla

Inventor： Deepak Shukla

IPC: G03F7/06

CPC classification number: G03F7/06 ,  G03F7/063

Abstract: A non-aqueous metal catalytic composition includes (a) a complex of silver and a hindered aromatic N-heterocycle comprising reducible silver ions in an amount of at least 2 weight %, (b) a silver ion photoreducing composition in an amount of at least 1 weight %, and (c) a photocurable component, a non-curable polymer, or a combination of a photocurable component and a non-curable polymer. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.

Abstract translation: 非水性金属催化剂组合物包括（a）银和受阻芳族N-杂环的配合物，其包含至少2重量％的可还原银离子，（b）银离子光还原组合物的量至少 1重量％，（c）光固化性成分，非固化性聚合物，光固化性成分和非固化性聚合物的组合。 该非水金属催化剂组合物可用于在合适的还原条件下原位形成银金属颗粒。 银金属可以以合适的层或图案提供在基底上，然后可随后对其进行化学镀以形成用于各种制品的导电层或图案或用作电子设备中的触摸屏显示器。

公开(公告)号：US20160167036A1

公开(公告)日：2016-06-16

申请号：US14571354

申请日：2014-12-16

Applicant: Deepak Shukla ,  Kevin M. Donovan

Inventor： Deepak Shukla ,  Kevin M. Donovan

IPC: B01J37/34 ,  B01J37/02 ,  C23C18/40 ,  B01J37/16 ,  C23C18/18 ,  B01J23/50 ,  B01J31/06

CPC classification number: B01J37/344 ,  B01J23/50 ,  B01J31/06 ,  B01J37/0219 ,  B01J37/16 ,  B01J37/348 ,  C23C18/1637 ,  C23C18/1834 ,  C23C18/34 ,  C23C18/40 ,  C23C18/405

Abstract: A non-aqueous metal catalytic composition includes (a) a silver complex comprising reducible silver ions, (b) an organic phosphite, (c) an oxyazinium salt silver ion photoreducing agent, (d) a hindered pyridine, (e) a photocurable component, a non-curable polymer, or combination of a photocurable component and a non-curable polymer, and (f) a photosensitizer different from all components (a) through (e) in the non-aqueous metal catalytic composition, in an amount of at least 1 weight %. This non-aqueous metal catalytic composition can be used to form silver metal particles in situ during suitable reducing conditions. The silver metal can be provided in a suitable layer or pattern on a substrate, which can then be subsequently subjected to electroless plating to form electrically-conductive layers or patterns for use in various articles or as touch screen displays in electronic devices.

Abstract translation: 非水性金属催化剂组合物包括（a）包含可还原银离子的银络合物，（b）有机亚磷酸酯，（c）氮杂鎓盐银离子光还原剂，（d）受阻吡啶，（e）光固化性组分 ，非可固化聚合物或光固化性组分和不可固化聚合物的组合，和（f）不同于非水性金属催化剂组合物中所有组分（a）至（e）的光敏剂，其量为 至少1重量％。 该非水金属催化剂组合物可用于在合适的还原条件下原位形成银金属颗粒。 银金属可以以合适的层或图案提供在基底上，然后可随后对其进行化学镀以形成用于各种制品的导电层或图案或用作电子设备中的触摸屏显示器。

公开(公告)号：US09360427B2

公开(公告)日：2016-06-07

申请号：US14526930

申请日：2014-10-29

Applicant: Deepak Shukla

Inventor： Deepak Shukla

IPC: B29C35/02 ,  G01N21/64

CPC classification number: G01N21/643 ,  C08J3/248 ,  C08J3/28 ,  C08J2363/00 ,  G01N21/8422 ,  G01N2021/8427

Abstract: Pyrene can be used as a fluorescent probe for various industrial purposes. For example, it can be included in photocurable or thermally curable compositions and monitoring the fluorescence emission spectra before and after some curing will provide an indication of how much curing has occurred. Such monitoring can be carried out multiple times during a manufacturing process. Monitoring can also be done at different locations of a composition such as at inner and outer surfaces of a photocured or thermally cured layer.

Abstract translation: 芘可用作各种工业用途的荧光探针。 例如，它可以包括在可光固化或可热固化的组合物中，并且在一些固化之前和之后监测荧光发射光谱将提供发生多少固化的指示。 这样的监视可以在制造过程中进行多次。 还可以在诸如在光固化或热固化层的内表面和外表面的组合物的不同位置进行监测。

公开(公告)号：US20150364688A1

公开(公告)日：2015-12-17

申请号：US14301385

申请日：2014-06-11

Applicant: Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

Inventor： Deepak Shukla ,  Kevin M. Donovan ,  Mark R. Mis

IPC: H01L51/00

CPC classification number: H01L51/052 ,  C08F12/30 ,  C08F220/14 ,  C08F220/18 ,  C08G18/0819 ,  C08G18/381 ,  C08G18/44 ,  C08G18/6633 ,  C08G18/755 ,  C08G18/83 ,  H01L51/0053 ,  H01L51/0541 ,  H01L51/0545 ,  C08F212/14 ,  C08F2220/1858

Abstract: A precursor dielectric composition comprises: (1) a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and organic charge balancing cations, (2) optionally, an electron-accepting photosensitizer component, and (3) one or more organic solvents in which the photocurable or thermally curable thiosulfate-containing polymer is dissolved or dispersed. These precursor dielectric compositions can be applied to various substrates and eventually cured to form dielectric compositions or layers for various types of electronic devices.

Abstract translation: 前体电介质组合物包含：（1）Tg至少为50℃的可光固化或可热固化的含硫代硫酸盐的聚合物，包括：有机聚合物主链，其包含（a）包含硫代硫酸盐基团的重复单元; 和有机电荷平衡阳离子，（2）任选的电子接受光敏剂组分，和（3）其中溶解或分散有可光固化或可热固化的含硫代硫酸盐的聚合物的一种或多种有机溶剂。 这些前体介电组合物可以施加到各种基底上，并且最终固化以形成用于各种类型的电子器件的电介质组合物或层。

公开(公告)号：US20150361201A1

公开(公告)日：2015-12-17

申请号：US14301375

申请日：2014-06-11

Applicant: Deepak Shukla ,  Kevin Donovan

Inventor： Deepak Shukla ,  Kevin Donovan

IPC: C08F220/10 ,  H01L51/00

CPC classification number: C08F220/10 ,  C08F220/14 ,  H01L51/0035 ,  H01L51/052 ,  H01L51/0541 ,  H01L51/0545 ,  C08F212/14 ,  C08F2220/1858 ,  C08F2220/303 ,  C08F220/36

Abstract: Photocurable or thermally curable thiosulfate-containing polymers have a Tg of at least 50° C. and (a) recurring units comprising pendant thiosulfate groups, and (b) recurring units comprising organic charge balancing cations that are associated with the (a) recurring units sufficiently to provide a net neutral charge with the pendant thiosulfate groups. These polymers can be represented by the following Structure (III): wherein R represents the organic polymer backbone, G is a single bond or a divalent linking group, M+ represents the organic charge balancing cation, and “a” represents at least 0.5 mol % and up to and including 50 mol % of (a) recurring units, and “b” represents the (b) recurring units and is at least equal to the “a” mol %, based on the total recurring units. These thiosulfate-containing polymers can be used to made dielectric compositions and gate dielectric layers in various devices.

Abstract translation: 可光固化或可热固化的含硫代硫酸盐的聚合物的Tg至少为50℃，（a）包含硫代硫酸盐基团的重复单元，和（b）包含与（a）重复单元相关联的有机电荷平衡阳离子的重复单元 足以提供与硫代硫酸盐侧基团的净中性电荷。 这些聚合物可以由以下结构（III）表示：其中R表示有机聚合物主链，G是单键或二价连接基团，M +表示有机电荷平衡阳离子，“a”表示至少0.5mol％ 并且包括（a）重复单元的50mol％，并且“b”表示（b）重复单元，并且基于总重复单元至少等于“a”mol％。 这些含硫代硫酸盐的聚合物可以用于制备各种装置中的电介质组合物和栅极电介质层。

公开(公告)号：US20150126637A1

公开(公告)日：2015-05-07

申请号：US14591199

申请日：2015-01-07

Applicant: Deepak Shukla

Inventor： Deepak Shukla

IPC: C08F2/50

CPC classification number: C08F2/50 ,  C08F2222/1013 ,  C08F2222/1053

Abstract: The photocuring efficiency of an N-oxyazinium salt photo initiator is increased by mixing it with an organic phosphine as a photoinitiator efficiency amplifier, and with an aryl aldehyde or alkyl aldehyde having a molecular weight of less than 1000. This mixture or photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment.

Abstract translation: 通过将其与作为光引发剂效率放大器的有机膦和分子量小于1000的芳基醛或烷基醛混合，可以提高N-氧嗪鎓盐引发剂的光固化效率。该混合物或光引发剂组合物可以是 用于固化丙烯酸酯或其它可光固化的化合物，特别是在含氧环境中。

公开(公告)号：US20140288253A1

公开(公告)日：2014-09-25

申请号：US14158897

申请日：2014-01-20

Applicant: Mark R. Mis ,  Deepak Shukla

Inventor： Mark R. Mis ,  Deepak Shukla

IPC: C08F20/70

CPC classification number: C08F228/02 ,  C08F20/70 ,  C08F212/14 ,  C08F220/66 ,  C08F222/04 ,  C08F222/40 ,  C08F226/12 ,  C08F232/08 ,  C08F2220/385 ,  C08F2222/402 ,  C08F2222/404 ,  C08F2222/406 ,  C08F2222/408 ,  C09D4/00 ,  C08F220/14 ,  C08F220/34

Abstract: A thiosulfate polymer includes both an electron-accepting photosensitizer component and thiosulfate groups in the same molecule, arranged in random order along the backbone. The thiosulfate polymer composition can be formulated into compositions and applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.

Abstract translation: 硫代硫酸盐聚合物包括同一分子中的电子接受光敏剂组分和硫代硫酸盐基团，其沿主链以随机顺序排列。 硫代硫酸盐聚合物组合物可以配制成组合物并施加到各种制品上，或者用于在光热反应后形成预定的聚合物图案以形成交联的二硫键，除去非交联的聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属，并且作为在理发操作中塑造人的头发的方法。

公开(公告)号：US20140287366A1

公开(公告)日：2014-09-25

申请号：US14158890

申请日：2014-01-20

Applicant: Deepak Shukla ,  Kevin M. Donovan

Inventor： Deepak Shukla ,  Kevin M. Donovan

IPC: G03F7/26

CPC classification number: G03F7/265 ,  G03F7/038 ,  G03F7/32 ,  G03F7/405 ,  H01L21/00

Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequestering metals.

Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品，或者用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键，除去非交联聚合物和与二硫化物反应性材料的反应。 这种硫代硫酸盐聚合物组合物也可用于螯合金属。

公开(公告)号：US20140287349A1

公开(公告)日：2014-09-25

申请号：US14158883

申请日：2014-01-20

Applicant: Deepak Shukla ,  Mark R. Mis ,  Dianne Marie Meyer

Inventor： Deepak Shukla ,  Mark R. Mis ,  Dianne Marie Meyer

IPC: G03F7/038

CPC classification number: G03F7/038 ,  A61K8/81 ,  A61K8/8147 ,  A61Q5/04 ,  A61Q5/06 ,  C08F2/50 ,  C08F20/70 ,  C08F212/04 ,  C08F212/14 ,  C08F220/66 ,  C08F222/04 ,  C08F222/40 ,  C08F226/12 ,  C08F228/02 ,  C08F232/08 ,  C08F2222/402 ,  C08F2222/404 ,  C08F2222/406 ,  C08F2222/408 ,  C09D4/00 ,  G03F7/0045 ,  Y02P20/582 ,  C08F8/34 ,  C08F220/14 ,  C08F2220/365

Abstract: A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.

Abstract translation: 硫代硫酸盐聚合物组合物包括电子接受光敏剂组分，作为单独的化合物或作为与硫代硫酸盐聚合物的连接。 硫代硫酸盐聚合物组合物可以应用于各种制品，或者用于在光热反应之后形成预定的聚合物图案以形成交联的二硫键，除去非交联聚合物和与二硫化物反应性材料的反应。 这样的硫代硫酸盐聚合物组合物也可以用于螯合纳米颗粒形式的金属，并且作为在理发操作中塑造人的头发的方法。

公开(公告)号：US08664287B2

公开(公告)日：2014-03-04

申请号：US13108273

申请日：2011-05-16

Applicant: Deepak Shukla

Inventor： Deepak Shukla

IPC: C08F2/50 ,  C08F2/46 ,  B29C71/04 ,  A61L2/08 ,  A61L24/00 ,  C08G61/04

CPC classification number: C08F2/50

Abstract: Photocuring methods are made more efficient by using an N-oxyazinium salt photoinitiator with an organic phosphine as a photoinitiator efficiency amplifier. This photoinitiator composition can be used to cure acrylates or other photocurable compounds, particularly in an oxygen-containing environment. The method can be used to prepare various articles, fibers, or devices with photocured compositions.

Abstract translation: 通过使用N-氧杂氮鎓盐引发剂与有机膦作为光引发剂效率放大器，使光固化方法更有效。 该光引发剂组合物可用于固化丙烯酸酯或其它可光固化的化合物，特别是在含氧环境中。 该方法可用于制备具有光固化组合物的各种制品，纤维或装置。