Alkaline earth metal salts, transition metal salts and transition metal
complexes of ketocarboxylic acids as corrosion inhibitors
    91.
    发明授权
    Alkaline earth metal salts, transition metal salts and transition metal complexes of ketocarboxylic acids as corrosion inhibitors 失效
    碱土金属盐,过渡金属盐和酮羧酸的过渡金属络合物作为腐蚀抑制剂

    公开(公告)号:US5458678A

    公开(公告)日:1995-10-17

    申请号:US222766

    申请日:1994-04-04

    摘要: There are described novel alkaline earth metal salts, transition metal salts and transition metal complexes of compounds of the formula I ##STR1## in which R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are, independently of one another, hydrogen, halogen, nitro, cyano, CF.sub.3, C.sub.1 -C.sub.15 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.2 -C.sub.15 alkenyl, C.sub.1 -C.sub.12 haloalkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, C.sub.6 -C.sub.10 aryl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl; C.sub.6 -C.sub.10 aryloxy which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl; C.sub.7 -C.sub.12 arylalkyl which is unsubstituted or substituted on the aryl radical by from 1 to 3 C.sub.1 -C.sub.4 alkyl groups; --CO.sub.2 R.sub.6, --COR.sub.6 or ##STR2## where at least one of the radicals R.sub.1 to R.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.15 alkyl, in addition the radicals R.sub.1 and R.sub.2, R2 and R.sub.3, R.sub.3 and R.sub.4 or R.sub.4 and R.sub.5 form, together with the carbon atoms to which they are bound, a benzo or cyclohexenyl ring,R.sub.6 is C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkyl interrupted by oxygen, sulfur or >N--R.sub.9 ; C.sub.7 -C.sub.12 arylalkyl which is unsubstituted or substituted on the aryl radical by from 1 to 3 C.sub.1 -C.sub.4 alkyl groups, R.sub.7 and R.sub.8 are, independently of one another, hydrogen, C.sub.1 -C.sub.24 alkyl or C.sub.2 -C.sub.24 alkyl interrupted by oxygen, sulfur or >N--R.sub.9,R.sub.9 is hydrogen or C.sub.1 -C.sub.8 alkyl, andn is an integer in the range from 1 to 10 for use, as corrosion inhibitors in coating compositions for protecting metal surfaces.

    摘要翻译: 描述了式I(I)化合物的新型碱土金属盐,过渡金属盐和过渡金属络合物,其中R 1,R 2,R 3,R 4和R 5彼此独立地为氢,卤素, 硝基,氰基,CF 3,C 1 -C 15烷基,C 5 -C 12环烷基,C 2 -C 15烯基,C 1 -C 12卤代烷基,C 1 -C 12烷氧基,C 1 -C 12烷硫基,未被C 1 -C 4烷基取代的C 6 -C 10芳基; 未取代或被C 1 -C 4烷基取代的C 6 -C 10芳氧基; 未取代或在芳基上被1至3个C 1 -C 4烷基取代的C 7 -C 12芳基烷基; -CO 2 R 6,-COR 6或其中基团R 1至R 5中的至少一个为氢,卤素或C 1 -C 15烷基,此外基团R 1和R 2,R 2和R 3,R 3和R 4或R 4和R 5一起形成 与其结合的碳原子,苯并或环己烯基环,R 6是C 1 -C 20烷基,被氧,硫或> N-R 9中断的C 2 -C 20烷基; 未取代或在芳基上被1至3个C 1 -C 4烷基取代的C 7 -C 12芳基烷基,R 7和R 8彼此独立地为氢,C 1 -C 24烷基或C 2 -C 24烷基,其被氧,硫或> N- R9,R9为氢或C1-C8烷基,n为1〜10的整数,用作保护金属表面的涂料组合物中的腐蚀抑制剂。

    Mixture containing dicyanate or polycyanate compound, substituted
bicyclo[2.]hept-5-ene-2,3-dicarboximide and thermoplastic
    93.
    发明授权
    Mixture containing dicyanate or polycyanate compound, substituted bicyclo[2.]hept-5-ene-2,3-dicarboximide and thermoplastic 失效
    含有二氰酸酯或聚氰酸酯化合物的混合物,取代的双环[2.2.1]庚-5-烯-2,3-二甲酰亚胺和热塑性

    公开(公告)号:US4885346A

    公开(公告)日:1989-12-05

    申请号:US279883

    申请日:1988-12-05

    CPC分类号: C08G73/12 C08F212/32

    摘要: Heat curable mixtures comprising(a) 5 to 95% by weight of at least one aromatic dicyanate or polycyanate compound or a prepolymer thereof,(b) 95 to 5% by weight of at least one compound of formula I or II ##STR1## or of a prepolymer of a compound of formula I or II, (c) 0 to 50% by weight, based on the sum of (a)+(b), of at least one compound of formula III ##STR2## (d) 0.1 to 50% by weight, based on the sum of (a)+(b), of at least one thermoplastic having a glass transition temperature of at least 120.degree. C., in which formulae aboveR.sub.1, R.sub.2 and R.sub.3 are each independently of one another a hydrogen atom or methyl,n is 1 or 2 and m is 2 or 3,R is hydrogen or an aliphatic, cycloaliphatic or aromatic radical, R' is an aliphatic radical, m- or p-phenylene or m- or p-phenyleneoxy, and R" is an organic radical or valency m containing 2 to 30 carbon atoms, are suitable for the production of mouldings such as prepregs or composites, coatings and bonds.

    摘要翻译: 包含(a)5至95重量%的至少一种芳族二氰酸酯或聚氰酸酯化合物或其预聚物,(b)95至5重量%的至少一种式I或II化合物(IMAGE) (II)或式I或II化合物的预聚物,(c)0至50重量%,基于(a)+(b)的总和,至少一种化合物 式(III)(d)(d)0.1至50重量%,基于(a)+(b)的总和,至少一种玻璃化转变温度为至少120℃的热塑性塑料, R 1,R 2和R 3各自独立地为氢原子或甲基,n为1或2,m为2或3,R为氢或脂族,脂环族或芳族基团,R'为脂族基团 对 - 亚苯基或对 - 亚苯基氧基,R“是含有2-30个碳原子的有机基团或价态m,适用于制备诸如预浸料或复合材料,涂层和粘结的模制品。

    Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures
    95.
    发明授权
    Thermally hardenable epoxy resin composition having an improved impact resistance at low temperatures 有权
    在低温下具有改善的耐冲击性的热固化性环氧树脂组合物

    公开(公告)号:US09221969B2

    公开(公告)日:2015-12-29

    申请号:US10538877

    申请日:2003-12-17

    摘要: The invention relates to compositions containing at least one epoxide adduct A that comprises an average of more than one epoxide group per molecule, at least one polymer B of formula (I), at least one thixotropic agent C based on a urea derivative in a non-diffusing carrier material, and at least one hardener D for epoxy resins, which is activated at an increased temperature. Said composition is used especially as an adhesive and is provided with an extraordinarily high impact peel working value, especially at low temperatures. The invention further relates to epoxide group-terminal impact strength modifiers of formula (I), which significantly increase the impact resistance in epoxy resin compositions, particularly two-component epoxy resin compositions.

    摘要翻译: 本发明涉及至少一种包含至少一种环氧化物加合物A的组合物,其每分子平均含有多于一个环氧基团,至少一种式(I)的聚合物B,至少一种基于非衍生物的脲衍生物的触变剂C, 以及至少一种用于环氧树脂的硬化剂D,其在升高的温度下被活化。 所述组合物特别用作粘合剂,并且具有特别高的冲击剥离工作值,特别是在低温下。 本发明还涉及式(I)的环氧基团 - 末端冲击强度改性剂,其显着提高了环氧树脂组合物,特别是双组分环氧树脂组合物的耐冲击性。

    Process for removing carbonaceous deposits on surfaces of catalysts and plant parts
    98.
    发明授权
    Process for removing carbonaceous deposits on surfaces of catalysts and plant parts 有权
    用于去除催化剂和植物部件表面上的碳质沉积物的方法

    公开(公告)号:US08349090B2

    公开(公告)日:2013-01-08

    申请号:US13124281

    申请日:2009-10-09

    IPC分类号: B08B3/00

    摘要: A process for removing carbonaceous deposits on surfaces of catalysts and plant parts by treating the deposits with a superheated stream of steam admixed at least temporarily with an oxygenous gas is provided, which involves, in each case monitoring the offgas CO2 content after condensation of the steam, at a temperature of at least 300° C.: (a) treating the carbonaceous deposits with superheated steam at a temperature of at least 300° C. until the CO2 content of the offgas has exceeded a maximum; (b) then, with further supply of superheated steam, commencing oxygen supply, the amount of oxygen supplied being adjusted such that the CO2 content in the offgas decreases further until it has fallen to a value of

    摘要翻译: 提供了一种通过用至少暂时与氧气混合的过热蒸汽流处理沉积物来除去催化剂和植物部件表面上的碳质沉积物的方法,其包括在各种情况下监测蒸汽冷凝后的废气CO 2含量 ,在至少300℃的温度下:(a)在至少300℃的温度下用过热蒸汽处理碳质沉积物,直到废气的CO 2含量超过最大值; (b)然后,进一步供应过热蒸汽,开始供氧,调整供氧量,使得废气中的二氧化碳含量进一步下降,直到其下降到<1%体积的数值; 然后(c)结束过热蒸汽的供应并将氧气通过剩余量的碳质沉积物,直到沉积物被真实地除去。